Precursor colorant composition for latex paint
The present invention relates to copolymer surfactants and their use in, e.g., coatings such as latex paint and solvent-based paint, and to a method of dispersing colored pigments using the copolymer surfactant, colorant compositions in which at least one pigment is dispersed by a copolymer surfactant of the invention, a paint which has a colorant composition of the invention, and a method for making a paint having a colorant composition of the invention.
1. A colorant composition suitable as a precursor to an aqueous latex paint, which colorant composition consists essentially of at least one pigment, water, and a copolymer surfactant having a number average molecular weight of from about 400 Daltons to about 200,000 Daltons comprising the following monomers
(a) from about 10% to about 80% by weight of at least one C 3 -C 12 α,β-ethylenically unsaturated carboxylic acid or anhydride,
(b) from about 10% to about 80% by weight of at least one C 2 -C 12 α,β-ethylenically unsaturated vinyl monomer, and
(c) from about 0.01% to about 20% by weight of at least one surfactant monomer, wherein each said surfactant monomer is either an acrylic or methacrylic ester moiety joined with a hydrophobic moiety which is styrylphenyl by a bridging group consisting essentially of a poly(ethyleneoxy) moiety,
which colorant composition is not itself an aqueous latex paint, and which colorant composition is capable of causing the Stormer low-shear viscosity of an aqueous latex paint formed of a mixture comprising said composition and a tint-base to be within about ±10% of the Stormer low-shear viscosity of said tint-base.
2. The colorant composition of claim 1 , which further includes at least one oxygenated solvent.
3. The colorant composition of claim 1 , wherein the copolymer surfactant is formed of the following monomers
(a) from about 10% to about 80% by weight of methacrylic or acrylic acid,
(b) from about 10% to about 80% by weight of ethyl methacrylate, and vinyl acetate, and
(c) from about 0.01% to about 20% by weight tristyrylphenylpoly(ethyleneoxy) methacrylate.
4. The colorant composition of claim 1 , wherein the copolymer surfactant comprises two surfactant monomers which are the same or different.
5. The colorant composition of claim 1 , wherein each said surfactant monomer is either an acrylic or methacrylic ester moiety joined with a hydrophobic moiety selected from the group consisting of monostyrylphenyl, distyrylphenyl and tristyrylphenyl by a bridging group consisting essentially of a poly(ethyleneoxy) moiety.
6. The colorant composition of claim 5 , wherein the poly(ethyleneoxy) moiety has from about 4 to about 200 ethyleneoxy units.
7. A method of making the colorant composition of claim 1 consisting essentially of admixing said copolymer surfactant, water and said at least one pigment, wherein said at least one pigment is one or more organic pigments, one or more inorganic pigments, or a mixture of one or more organic pigments and one or more inorganic pigments.
8. The method of claim 7 , wherein the colorant composition further includes at least one conventional surfactant.
9. The method of claim 8 , wherein the conventional surfactant is an anionic surfactant, a nonionic surfactant, an amphoteric surfactant, or a mixture thereof.
10. The method of claim 7 , wherein the colorant composition further includes a water-soluble polymer selected from a polycarboxylic acid, a copolymer comprising a monomer containing a carboxylic acid, an alkali soluble emulsion polymer, a cellulose derivative, a salt of a polyacrylic acid, a salt of a copolymer comprising a monomer containing an acrylic acid, polyvinylpyrrolidone, a copolymer comprising vinylpyrrolidone monomer, or a mixture thereof.
11. The method of claim 10 , wherein the water-soluble polymer is a salt of a polyacrylic acid, a salt of a copolymer comprising a monomer containing an acrylic acid, or a mixture thereof.
12. The method of claim 7 , wherein the inorganic pigment is titanium dioxide white, carbon black, lampblack, black iron oxide, yellow iron oxide, brown iron oxide, red iron oxide, or a mixture thereof.
13. The method of claim 7 , wherein the organic pigment is phthalocyanine blue, phthalocyanine green, monoarylide yellow, diarylide yellow, benzimidazolone yellow, heterocyclic yellow, DAN orange, quinacridone magenta, quinacridone violet, organic red, or a mixture thereof.
14. The method of claim 13 , wherein the organic red is metallized azo red, a nonmetallized azo red, or a mixture thereof.
15. The colorant composition as defined in claim 1 , wherein the copolymer surfactant is formed of the following monomers
(a) from about 10% to about 80% by weight of methacrylic or acrylic acid,
(b) from about 10% to about 80% by weight of a first vinyl ester which is alkyl methacrylate, the alkyl of which is of from 2 to 12 carbon atoms, and a second vinyl ester of from 2 to 12 carbon atoms, and
(c) from about 0.01% to about 20% by weight of at least one surfactant monomer, wherein each said surfactant monomer is either an acrylic or methacrylic ester moiety joined with a hydrophobic moiety which is tristyrylphenyl by a bridging group consisting essentially of a poly(ethyleneoxy) moiety.
16. A method of making the colorant composition of claim 15 consisting essentially of admixing said copolymer surfactant, water and said at least one pigment, wherein said at least one pigment is one or more organic pigments, one or more inorganic pigments, or a mixture of one or more organic pigments and one or more inorganic pigments.
17. A method of claim 16 , wherein the colorant composition further includes at least one conventional surfactant.
18. The method of claim 17 , wherein the conventional surfactant is an anionic surfactant, a nonionic surfactant, an amphoteric surfactant, or a mixture thereof.
19. The method of claim 16 , wherein the colorant composition further includes a water-soluble polymer selected from a polycarboxylic acid, a copolymer comprising a monomer containing a carboxylic acid, an alkali soluble emulsion polymer, a cellulose derivative, a salt of a polyacrylic acid, a salt of a copolymer comprising a monomer containing an acrylic acid, polyvinylpyrrolidone, a copolymer comprising vinylpyrrolidone monomer, or a mixture thereof.
20. The method of claim 19 , wherein the water-soluble polymer is a salt of a polyacrylic acid, a salt of a copolymer comprising a monomer containing an acrylic acid, or a mixture thereof.
21. The method of claim 16 , wherein the inorganic pigment is titanium dioxide white, carbon black, lampblack, black iron oxide, yellow iron oxide, brown iron oxide, red iron oxide, or a mixture thereof.
22. The method of claim 16 , wherein the organic pigment is phthalocyanine blue, phthalocyanine green, monoarylide yellow, diarylide yellow, benzimidazolone yellow, heterocyclic yellow, DAN orange, quinacridone magenta, quinacridone violet, organic red, or a mixture thereof.
23. The method of claim 22 , wherein the organic red is metallized azo red, a nonmetallized azo red, or a mixture thereof.