Reduction of carrot defects in silicon carbide epitaxy
View Patent ↗Single crystal silicon carbide epitaxial layer on an off-axis substrate are manufactured by placing the substrate in an epitaxial growth reactor, growing a first layer of epitaxial silicon carbide on the substrate, interrupting the growth of the first layer of epitaxial silicon carbide, etching the first layer of epitaxial silicon carbide to reduce the thickness of the first layer, and regrowing a second layer of epitaxial silicon carbide on the first layer of epitaxial silicon carbide. Carrot defects may be terminated by the process of interrupting the epitaxial growth process, etching the grown layer and regrowing a second layer of epitaxial silicon carbide. The growth interruption/etching/regrowth may be repeated multiple times. A silicon carbide epitaxial layer has at least one carrot defect that is terminated within the epitaxial layer. A semiconductor structure includes an epitaxial layer of silicon carbide on an off-axis silicon carbide substrate, and a carrot defect having a nucleation point in the vicinity of an interface between the substrate and the epitaxial layer and is terminated within the epitaxial layer.
1. A semiconductor structure comprising a silicon carbide epitaxial layer having a carrot defect which is terminated within the epitaxial layer.
2. A semiconductor structure comprising:
an off-axis silicon carbide substrate;
an epitaxial layer of silicon carbide on the substrate,
a carrot defect having a nucleation point in the vicinity of an interface between the substrate and the epitaxial layer, wherein the carrot defect terminates within the epitaxial layer.
3. A structure according to claim 2 , wherein the substrate comprises silicon carbide having a polytype selected from the group consisting of 2H, 4H, and 6H.
4. A structure according to claim 2 , wherein the silicon carbide substrate is cut off-axis towards the [11 2 0] direction.
5. A structure according to claim 2 , wherein the silicon carbide substrate is cut off-axis towards a crystallographic direction perpendicular to the c-axis.
6. A structure according to claim 2 , wherein the epitaxial layer comprises a buffer layer.
7. A structure according to claim 2 , wherein the epitaxial layer is doped with a dopant at a concentration of 1E18 cm −3 or greater.
8. A structure according to claim 7 , wherein the dopant comprises nitrogen, phosphorus, boron or aluminum.
9. A structure according to claim 7 wherein the epitaxial layer is a first epitaxial layer, the structure further comprising:
a second epitaxial layer on the first epitaxial layer, the second epitaxial layer having fewer carrots defects therein than the first epitaxial layer.