Structural reinforcement article and process for preparation thereof
The invention is a process for the preparation of article comprising placing a film on each inner surface of each part of a two part mold; placing an article in the mold with film located between the surface of the mold and the article such that there is a small space between the article and the surface of the mold; closing the mold about the article; injecting between the film and the article an expandable plastic material under conditions that the article is coated with the expandable material and the expandable material does not expand; removing the plastic article with the expandable material coated thereon with the two films attached to the expandable plastic material. In another embodiment the invention is an article comprising a shaped plastic article; an expandable material coated in the shaped plastic article; and a film covering the material coated shaped plastic article. In another embodiment the invention is a method of reinforcing a structural member which comprises inserting an article according to this invention into a cavity of the structural member and heating the structural member and the article to a temperature at which the expandable plastic material expands and the film or the expandable material bonds to the inner surface of the structural member so as to fix the location of the article in the structural member.
1. A process for the preparation of an article comprising
a) placing a film on the inner surface of each part of a two part mold;
b) placing an article in the mold with film located between the surface of the mold and the article;
c) closing the mold about the article such that there is a small space between the article and the surface of the mold;
d) injecting between the film and the article an expandable material under conditions that the article is coated with the expandable material and the expandable material does not expand;
e) removing the article with the expandable material coated thereon with the film attached to the expandable material wherein the film is removed from the exuandable material coated plastic article.
2. The process of claim 1 wherein rho expandable material exhibits adhesive properties under conditions at which the expandable material is expanded.
3. The process of claim 1 wherein the article is a shaped foam article.
4. The process of claim 1 wherein the article is a structural reinforcement member adapted to reinforce a cavity in a structure.
5. A process for the preparation of an article comprising
a) placing a film on the inner surface of each part oC a two part mold;
b) placing an article in the mold with film located between the surface of the mold and the article:
c) closing the mold about the article such that there is a small space between the article and the surface of the mold;
d) injecting between the film and the article an expandable material under conditions that the article Is coated with the expandable material and the expandable material does not expand, wherein the expandable material is comprised of a heat activated blowing agent;
e) removing die article with the expandable material coated thereon with the film attached in the expandable material.
6. The process of claim 5 , wherein the heat activated blowing agent is activated at a temperature of about 100° C. or greater.
7. The process of claim 6 , wherein the temperature is about 120° C. or greater.
8. The process of claim 7 , wherein the temperature is not greater than about 200° C.
9. The process of claim 5 , wherein the expandable material is a polymeric material.
10. The process of claim 9 , wherein the polymeric material is polyvinyl chloride, methacrylate, phenoxy thermoplastics or combination thereof.
11. The process of claim 9 , wherein the expandable material is an expandable adhesive.
12. The process of claim 11 , wherein the expandable adhesive is comprised of an epoxy resin.
13. The process of claim 12 , wherein the epoxy resin a one part epoxy resin.
14. process of claim 12 , wherein the expandable adhesive has a viscosity increasing agent.
15. process of claim 12 , wherein the expandable adhesive has a curing agent.
16. The process of claim 9 , wherein expandable material is a polyolefin, copolymers and terpolymers with at least one monomer type an alpha-olefin, phenollfonnaldehyde material, phenoxy material, or polyurethane material.