Functionalized polymer composition for grease
A grease composition containing: (a) the reaction product of: (i) a calcium containing overbased organic acid; and (ii) at least one acid producing compound or derivatives thereof selected from the group consisting of: (1) a non-polymeric hydrocarbyl substituted dicarbonyl derivative selected from the group consisting of an acid, an ester, a salt, an anhydride, ester-acid, acid-salt and mixtures thereof; (2) a copolymer derived from monomers containing (1) an olefin; and (2) an unsaturated dicarboxylic acid anhydride or derivatives thereof; and (3) an inorganic acid containing about 2 or more acidic hydrogens; and (b) an oil of lubricating viscosity, wherein the overbased calcium sulphonate contains colloidally dispersed calcium carbonate is selected from the group consisting of calcite, vaterite and mixtures thereof. The invention further relates to the process to make the composition and its use in greases to increase water resistance.
1. A grease composition comprising:
(a) the reaction product of:
(i) a calcium containing overbased organic acid; and
(ii) at least one acid producing compound or derivatives thereof comprising a non-polymeric hydrocarbyl substituted derivative of succinic acid, wherein the hydrocarbyl contains about 4 to about 40 carbon atoms; and
(b) an oil of lubricating viscosity,
wherein the calcium containing overbased organic acid contains colloidally dispersed calcium carbonate calcite.
2. The composition of claim 1 , wherein the hydrocarbyl contains about 6 to about 20 carbon atoms.
3. The composition of claim 1 , wherein the hydrocarbyl contains about 8 to about 20 carbon atoms.
4. The composition of claim 1 , wherein the non-polymeric hydrocarbyl substituted derivative is nonyl succinic acid, decyl succinic acid, undecyl succinic acid, dodecyl succinic acid, tridecyl succinic acid, tetradecyl succinic acid, pentadecyl succinic acid, hexadecyl succinic acid, heptadecyl succinic acid, octadecyl succinic acid, octadecenyl succinic acid, nonadecyl succinic acid, or mixtures thereof.
5. The composition of claim 1 further comprising a thickening agent.