In-situ BWR and PWR CRUD flake analysis method and tool
The invention provides a method and tool to perform an analysis of CRUD on a nuclear fuel rod. The method recites providing a nuclear fuel rod with a layer of CRUD on an exterior of the fuel rod, scraping the CRUD from the fuel rod with a CRUD scraping tool and collecting CRUD flakes from the CRUD scraping tool. The method also provides for sorting the CRUD flakes into particle fractions, and analyzing the CRUD with a scanning electron microscope, wherein the scraping tool has a blade with a rigidity that is matched to an anticipated CRUD deposit shear strength.
1. A method for analysis of a CRUD flake cross section on a nuclear fuel rod, comprising:
determining a morphology of crystals of the flake;
determining a size of the crystals of the flake;
correlating elemental distributions of the flake at various locations on the flake, wherein the distributions are obtained with a scanning electron microscope with attached energy dispersive spectrometer;
determining chemical elements including depletion of iron and/or an enrichment in zinc and silicon in the crystals by the elemental distributions; and
correlating the depletion of iron and the enrichment in zinc and silicon with the size and the morphology of the crystals.
2. The method according to claim 1 , further comprising:
tilting the flake with respect to a beam from the scanning electron microscope.
3. The method according to claim 1 , further comprising:
obtaining EDXS spectra of individual crystals; and
tilting the crystals relative to a beam of the SEM to investigate crystal morphology.
4. The method according to claim 3 , wherein the tilting is done using one of many possible props and/or glue.
5. The method according to claim 1 , further comprising:
performing a small area electron diffraction on the crystals.
6. The method to perform an analysis of CRUD on a nuclear fuel rod according to claim 1 , wherein the step of analyzing the CRUD comprises:
cropping a scanning electron microscope image;
adjusting a contrast of the image such that darkest points of the image are pure black and lightest points are pure white;
determining a density of at least one flake reference sample;
determining a percent of pixels that have a grayscale value equivalent to porosity determined from the density;
applying a grayscale equivalent to a remainder of flake samples;
determining a percentage of pixels that are one of darker and equal to the grayscale value to determine a porosity; and
determining a density of the remainder of the flake sample based on the porosity.