IP Library Granted Patent US 7,887,689
Granted Patent B2
US 7,887,689 · App. 10/842,357 · Granted Feb 15, 2011

Method and apparatus for attaching nanostructure-containing material onto a sharp tip of an object and related articles

Assignees: The University of North Carolina at Chapel Hill; Xintek, Inc.
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Quick Facts
Patent No.
US 7,887,689
App. No.
10/842,357
Granted
Feb 15, 2011
Kind
B2
Abstract

A method for attaching nanostructure-containing material onto a sharp tip of an object includes forming a suspension of pre-formed nanostructure-containing material in a liquid medium. An electrode is immersed in the suspension. The sharp tip of the object is arranged to be in contact with the suspension. A voltage is applied to the immersed electrode and to the sharp tip. The nanostructure-containing material attaches to the sharp tip of the object.

Claims (23)

1. A method of attaching carbon nanotubes and/or nanowires onto a sharp tip by an electrophoresis process, the method comprising the successive steps of:

providing an object with a sharp, pointed tip;

forming a suspension containing at least one of a carbon nanotube or nanowire, wherein the suspension has a surface;

immersing an electrode in the suspension;

placing the sharp tip of the object perpendicular to and directly above the surface of the suspension;

applying a voltage between the immersed electrode and the sharp tip;

moving the sharp tip toward the surface of the suspension until electrical contact is established between the immersed electrode and the sharp tip;

allowing current to pass between the immersed electrode and the sharp tip for a predetermined amount of time, wherein the carbon nanotube or nanowire attaches to the sharp tip and remains permanently attached after the application of voltage is discontinued; and

raising the sharp tip above the surface of the suspension after expiration of the predetermined amount of time.

2. The method of claim 1 , comprising:

monitoring the current between the immersed electrode and the sharp tip to determine when electrical contact between the electrode and tip is established.

3. The method of claim 1 , further comprising:

annealing the sharp tip with attached nanotube or nanowire.

4. The method of claim 1 , wherein forming a suspension containing carbon nanotubes or nanowires further comprises selectively adding a charger to the liquid medium.

5. The method of claim 1 , wherein the nanotubes comprise at least one of carbon, BxNy, CxByNz, and MS2, wherein M=tungsten, molybdenum, or vanadium oxide.

6. The method of claim 1 , wherein the nanowires comprise at least one of an elemental metal, an elemental or a compound semiconductor, an oxide, a carbide, a nitride, and a chalcogenide.

7. The method of claim 1 , comprising attaching an individual nanotube, nanotube bundle, or nanowire to the sharp tip at a contact point of the sharp tip with the suspension.

8. The method of claim 1 , wherein the object with a sharp tip comprises a plurality of sharp tips, wherein the plurality of sharp tips are arranged to concurrently be in contact with the suspension, whereby the nanostructure-containing material attaches to each of the sharp tips.

9. The method of claim 1 , wherein the electrophoresis process is a dielectrophoresis method where an alternating-current voltage is applied between the sharp tip and the immersed electrode.

10. The method of claim 1 , wherein either an individual nanotube or a single nanowire is attached to the sharp tip after the electrophoresis process.

11. The method of claim 1 , wherein multiple nanotubes, multiple nanowires, or a mixture of nanotubes and nanowires are attached to the sharp tip after the electrophoresis process.

12. The method of claim 1 , wherein the sharp tip with the attached nanotube or nanowire used as a probe for an atomic force microscope, a probe for a scanning tunneling microscope, or a point electron field emission source.

13. The method of claim 1 , wherein allowing current to pass between the immersed electrode and the sharp tip for a predetermined amount of time comprises the carbon nanotube or nanowire forming a protrusion or bundle on the sharp tip wherein the carbon nanotube or nanowire remains permanently attached even after application of voltage is discontinued.

Assignments (4)
CHANGE OF NAME Recorded Oct 27, 2010
From: APPLIED NANOTECHNOLOGIES, INC.
To: XINTEK, INC.
Reel/Frame 025207/0782 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 27, 2010
From: ZHOU, OTTO Z.; YUE, GUOZHEN; OH, SOOJIN
To: UNIVERSITY OF NORTH CAROLINA AT CHAPEL HILL, THE
Reel/Frame 025207/0833 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 27, 2010
From: GAO, BO
To: APPLIED NANOTECHNOLOGIES, INC.
Reel/Frame 025207/0862 →
CONFIRMATORY LICENSE Recorded Dec 27, 2004
From: NORTH CAROLINA, UNIVERISITY OF
To: NAVY, SECRETARY OF THE, UNITED STATES OF AMERICA
Reel/Frame 016100/0607 →
Continuity (2)
Division 09996695 · Nov 30, 2001
Related Publication 20050133372A1 · Jun 23, 2005