Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers
Polymer blends that exhibit good impact resistance comprise a crystalline polypropylene matrix and a partly crystalline copolymer impact modifier with a molecular weight lower than that of the matrix polymer. The matrix polymer can comprise any crystalline propylene homo- or copolymer. The impact modifying copolymers are characterized as comprising at least about 60 weight percent (wt %) of units derived from propylene and, in certain embodiments, as having at least one, preferably two or more, of the following properties: (i) 13 C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity, (ii) a B-value greater than about 1.4 when the comonomer content of the copolymer is at least about 3 wt %, (iii) a skewness index, S ix , greater than about −1.20, (iv) a DSC curve with a T me that remains essentially the same and a T max that decreases as the amount of comonomer in the copolymer is increased, and (v) an X-ray diffraction pattern that reports more gamma-form crystals than a comparable copolymer prepared with a Ziegler-Natta (Z-N) catalyst.
1. An impact-resistant polymer blend comprising (i) a crystalline polypropylene matrix having a weight average molecular weight, and (ii) a copolymer impact modifier having (a) a percent crystallinity of about 40 to >0, and (b) a weight average molecular weight lower than the weight average molecular weight of the crystalline polypropylene matrix the impact modifier prepared using a metallocene catalyst and comprising propylene and ethylene and/or one or more unsaturated comonomers, the matrix and the modifier each having an MFR and the MFR of the modifier at least 10 times larger than the MFR of the matrix.
2. The polymer blend of claim 1 in which the crystalline polypropylene matrix is a homopolymer.
3. The polymer blend of claim 1 in which the crystalline polypropylene matrix is a copolymer.
4. The polymer blend of claim 1 in which the unsaturated comonomer is a C 4-20 α-olefin or diene.
5. The polymer blend of claim 1 in which the impact modifier is at least one of a copolymer of propylene and ethylene or a terpolymer of propylene, ethylene and a C 4-20 α-olefin or diene.
6. The polymer blend of claim 1 in which the impact modifier is characterized as (A) comprising at least about 60 weight percent (wt %) of units derived from propylene, about 0.1–35 wt % of units derived from ethylene, and 0 to about 35 wt % of units derived from one or more unsaturated comonomers, with the proviso that the combined weight percent of units derived from ethylene and the unsaturated comonomer does not exceed about 40 wt. % of the polymer.
7. The polymer blend of claim 1 in which the impact modifier is characterized as comprising at least about 60 weight percent (wt %) of units derived from propylene and about 0.1–40 wt % of units derived from an unsaturated comonomer other than ethylene.
8. The polymer blend of claim 1 in which the impact modifier has a melt flow rate of about 0.02 to 100 g/10 min.
9. The polymer blend of claim 8 in which the crystalline polypropylene matrix comprises at least about 80 percent by weight based upon the total weight of the blend.
10. The polymer blend of either claim 6 in which one or both of the crystalline polypropylene and impact modifier is in combination with one or more other polymers.
11. The polymer blend of claim 7 in which one or both of the crystalline polypropylene and impact modifier is in combination with one or more other polymers.
12. An article comprising the polymer blend of claim 1 .
13. An article comprising the polymer blend of claim 6 .
14. An article comprising the polymer blend of claim 7 .
15. A blow molded article comprising the polymer blend of claim 6 .
16. A blow molded article comprising the polymer blend of claim 7 .
17. The blend of claim 1 in which the MFR of the at least partially crystalline copolymer impact modifier is at least 30 times larger than the MFR of the crystalline polypropylene matrix.
18. The blend of claim 7 in which the MFR of the at least partially crystalline copolymer impact modifier is at least 30 times larger than the MFR of the crystalline polypropylene matrix.