Sol-gel nanocoated particles for magnetic displays
Magnetic display devices include low-density silica coated magnetic and nonmagnetic particles. In a one-particle system, low-density silica coated magnetic particles coated by a sol-gel process are used in combination with non-magnetic particles. In a two-particle system, low-density silica coated magnetic particles coated by a sol-gel process are used in combination with low-density silica coated non-magnetic particles. Display devices employing silica coated magnetic particles minimize the tendency of the magnetic particles to aggregate. Silica coated magnetic particles in a display device results in a magnetic display with improved image stability. Low-density silica coated magnetic particles in a display device allow for particles to move easily through a dispersion fluid in response to a magnetic field.
1. A method of manufacturing a magnetic display device comprising:
mixing a silicate solution with particles having a density of about 3.0 g/cm 3 –6.0 g/cm 3 ;
titrating the mixture with HCl to a pH of about 10;
removing soluble sodium silicates and aggregated particles to obtain the particles which are thinly coated with silica;
dispersing the thinly coated particles in ethanol, ammonia, and tetraethoxysilane (TEOS);
stirring to form silica coated particles having a density of about 1.4 g/cm 3 –3.0 g/cm 3 ; and
inserting the particles in a dispersion medium between two substrates of a display device.
2. The method of claim 1 , further comprising the step of treating the silica coated particles with ((3-methacryloxy)propyl)trimethoxysilane or octadecyl alcohol before inserting the particles into a dispersion medium.
3. The method of claim 1 , wherein silica coated particles have a coating thickness of about 0.5 nm to about 1 μm.
4. The method of claim 1 , wherein the particles are treated with tetramethylammonium in water before mixing with the silicate solution.
5. The method of claim 1 , wherein the stirring is for about 24 hours at about 20° C.
6. The method of claim 1 , wherein the particles are selected from the group consisting of magnetic, non-magnetic, and mixtures thereof.