Polymers for electrical applications
Electrical insulation compounds are disclosed, the insulation compounds including an ethylene polymer comprising at least 40 wt % ethylene-derived units and having a density of ≦0.91 g/cm 3 and a propylene polymer comprising at least 75 wt % propylene-derived units and having an isotactic propylene triad tacticity of from 65% to 99%. Also disclosed are electrical devices including the electrical insulation compounds.
1. An electrically conductive device comprising:
(a) an electrically conductive portion; and
(b) an electrically insulating portion comprising an electrical insulation compound, the insulation compound comprising a blend of:
(1) at least 10 wt %, based on the total weight of the insulation compound, of an ethylene polymer comprising at least 40 wt % ethylene-derived units and having a density of ≦0.91 g/cm 3 ; and
(2) at least 10 wt %, based on the total weight of the insulation compound, of a propylene polymer comprising at least 75 wt % propylene-derived units having an isotactic propylene triad tacticity of from 65% to 99% and a heat of fusion of 1 J/g to 60 J/g..
2. The electrically conductive device of claim 1 , wherein the ethylene polymer has a density of from 0.85 to 0.91 g/cm 3 .
3. The electrically conductive device of claim 1 , wherein the ethylene polymer has a density of from 0.86 to 0.89 g/cm 3 .
4. The electrically conductive device of claim 1 , wherein the ethylene polymer additionally comprises from 0.1 to 10 wt % diene-derived units.
5. The electrically conductive device of claim 1 , wherein the ethylene polymer is an EP(D)M elastomer having a Mooney viscosity (ML [1+4] 125° C.) of from 10 to 80.
6. The electrically conductive device of claim 1 , wherein the ethylene polymer has an MI of from 0.01 to 100 and an MIR (I 21 /I 2 ) of at least 30.
7. The electrically conductive device of claim 1 , wherein the electrical insulation compound includes less than 25 phr filler.
8. The electrically conductive device of claim 1 , wherein the electrical insulation compound is substantially free of filler.
9. The electrically conductive device of claim 1 , wherein the electrical insulation compound has a 28 day dissipation factor of less than 0.01.
10. An electrically conductive device comprising:
(a) an electrically conductive portion; and
(b) an electrically insulating portion comprising an electrical insulation compound, the insulation compound comprising a blend of:
(1) at least 10 wt%, based on the total weight of the insulation compound, of an ethylene polymer comprising at least 40 wt% ethylene-derived units and having a density of ≦0.91 g/cm 3 ; and
(2) at least 10 wt%, based on the total weight of the insulation compound, of a propylene polymer comprising at least 75 wt% propylene-derived units having an isotactic propylene triad tacticity of from 65% to 99% and a heat of fusion of less than 75 J/g, wherein the propylene polymer of the electrical insulation compound additionally comprises from 0.1 to 10 wt% diene-derived units.
11. The electrically conductive device of claim 1 , wherein the propylene polymer of the electrical insulation compound additionally comprises from 0.1 to 25 wt % ethylene-derived units.
12. The electrically conductive device of claim 1 , wherein the propylene polymer of the electrical insulation compound additionally comprises from 0.1 to 25 wt % ethylene-derived units.
13. The electrically conductive device of claim 1 , wherein the propylene polymer is present in the electrical insulation compound in an amount of at least 15 wt %, based on the total weight of the insulation compound.
14. The electrically conductive device of claim 1 , wherein the ethylene polymer is present in the electrical insulation compound in an amount of at least 15 wt %, based on the total weight of the insulation compound.
15. The electrically conductive device of claim 1 , wherein the ethylene polymer and propylene polymer constitute together at least 70 wt % of the electrical insulation compound.
16. The electrically conductive device of claim 1 , wherein the ethylene polymer and propylene polymer constitute together at least 80 wt % of the electrical insulation compound.
17. An electrically conductive device comprising:
(a) an electrically conductive portion; and
(b) an electrically insulating portion comprising an electrical insulation compound, the insulation compound comprising a blend of:
(1) at least 10 wt%, based on the total weight of the insulation compound, of an ethylene polymer comprising at least 40 wt% ethylene-derived units and having a density of ≦0.91 g/cm 3 ; and
(2) at least 10 wt%, based on the total weight of the insulation compound, of a propylene polymer comprising at least 75 wt% propylene-derived units having an isotactic propylene triad tacticity of from 65% to 99% and a heat of fusion of less than 75 J/g, wherein the electrical insulation compound additionally comprises an LDPE.
18. The electrically conductive device of claim 17 , wherein the LDPE is present in the electrical insulation compound in an amount of at least 10 wt %, based on the total weight of the insulation compound.