Hydrolysis of chlorosilanes
View Patent ↗Chlorosilanes are hydrolyzed to a hydrolysate in a looped system containing a hydrolysis reactor, an HCl purifier, a wash means, and a separator. The steps of the method comprise: (i) feeding chlorosilanes from an external source to the hydrolysis reactor, (ii) feeding water from an external source to the wash means, (iii) feeding a high concentration aqueous HCl of at least 10 percent by weight HCl from an external source to the hydrolysis reactor between the wash means and the hydrolysis reactor, (iv) removing anhydrous hydrogen chloride from the HCl purifier, (v) removing hydrolysate from the wash means, and (vi) removing a low concentration aqueous hydrogen chloride of 0.1 to less than 10 percent by weight HCl from the looped system.
1. A method of hydrolyzing chlorosilanes to produce a hydrolysate in a looped system containing a hydrolysis reactor, an HCl purifier, a wash means, and a separator. the method comprising:
(i) feeding chiorosilanes from an external source to a hydrolysis reactor where a hydrolysis reaction occurs and produces a mixture containing a liquid hydrolysate, aqueous HCl, and HCl vapor;
(ii) passing liquid hydrolysate, aqueous HCl, and HCl vapor produced in (i) through an HCl purifier where anhydrous hydrogen chloride is removed from the mixture and the looped system;
(iii) passing liquid hydrolysate and aqueous HCl from the HCl purifier into a separator where liquid hydrolysate is separated from aqueous HCl;
(iv) returning aqueous HCl from (iii) to the hydrolysis reactor;
(v) feeding liquid hydrolyzate from (iii) into a wash means;
(vi) feeding water from an external source into the wash means to purify the liquid hydrolyzate;
(vii) removing purified liquid hydrolysate from the wash means and the looped system;
(viii) returning low concentration aqueous HCl from the wash means to the hydrolysis reactor;
(ix) removing low concentration aqueous HCl from the wash means and the looped system, wherein the low concentration aqueous HCl is at a concentration of 0.1 to less than 10 percent by weight; and
(x) feeding high concentration aqueous HCl of at least 10 percent by weight HCl from an external source to the hydrolysis reactor.
2. A method according to claim 1 in which the high concentration aqueous HCl in (iii) is at least greater than 20 percent by weight HCl and less than 42 percent by weight HCl.
3. A method according to claim 2 in which the high concentration aqueous HCl in (iii) is 32–36 percent by weight HCl.
4. A method according to claim 1 in which the low concentration aqueous HCl in (vi) is 0.1 to less than 5 percent by weight HCl.
5. A method according to claim 4 in which the low concentration aqueous HCl in (vi) is 0.1 to less than 1 percent by weight HCl.
6. A method according to claim 1 in which the chlorosilanes are selected from the group consisting of dimethyldichlorosilane, diethyldchlorosilane, di-n-propyldichlorosilane, di-i-propyldichlorosilane, di-n-butyldichlorosilane, di-i-butyldichlorosilane, di-t-butyldichlorosilane, n-butylmethyldichlorosilane, octadecylmethyldichlorosilane, diphenyldichlorosilane, phenylmethyldichlorosilane, dicyclohexyldichlorosilane, methyldichlorosilane, and trimethylchlorosilane.