Longitudinal shrink films
A heat-shrinkable film and a method of its manufacture are provided. In an exemplary embodiment, a polystyrene film exhibits heat-induced growth in the cross direction of great than or equal to 5% with greater than or equal to 30% concomitant shrinkage in the machine direction. The films may comprise crystal polystyrene, high impact polystyrene, and/or elastomers. A method of manufacture is disclosed which includes a post-extrusion temperature conditioning step.
1. A method of increasing the viscosity of a polystyrene polymer blend suitable for shrink films, comprising (a) providing pellets of a polystyrene polymer blend, (b) melting the pellets to form a molten mass at a first viscosity value or range of values, and (c) cooling the molten mass to a second viscosity value or range of values in a polymer cooling unit.
2. The method of claim 1 in which the second viscosity value falls in the range of about two times to about ten times the first viscosity value.
3. The method of claim 1 in which the second viscosity value falls in the range of about four times to about eight times the first viscosity value.
4. The method of claim 1 in which the second viscosity value falls about six times the first viscosity value.