Methods of nanotubes films and articles
View Patent ↗Nanotube films and articles and methods of making the same are disclosed. A conductive article includes an aggregate of nanotube segments in which the nanotube segments contact other nanotube segments to define a plurality of conductive pathways along the article. The nanotube segments may be single walled carbon nanotubes, or multi-walled carbon nanotubes. The various segments may have different lengths and may include segments having a length shorter than the length of the article. The articles so formed may be disposed on substrates, and may form an electrical network of nanotubes within the article itself. Conductive articles may be made on a substrate by forming a nanotube fabric on the substrate, and defining a pattern within the fabric in which the pattern corresponds to the conductive article. The nanotube fabric may be formed by growing the nanotube fabric on the substrate using a catalyst, for example, in which the catalyst is a gas phase catalyst, or in which the catalyst is a metallic gas phase catalyst. The nanotube fabric may be formed by depositing a solution of suspended nanotubes on the substrate. The deposited solution may be spun to create a spin-coating of the solution. The solution may be deposited by dipping the substrate into the solution. The nanotube fabric is formed by spraying an aerosol having nanotubes onto a surface of the substrate.
1. A method of making a conductive article on a substrate, comprising:
forming a nanotube film on the substrate, the film having a plurality of nanotubes extending in varying orientations but parallel to a facing surface of the substrate;
depositing a mask layer over the nanotube film;
defining a pattern in the mask layer, the pattern corresponding to the shape of the conductive article;
removing nanotubes in accordance with the pattern of the mask layer so that the remaining nanotube film forms the conductive article, wherein the remaining nanotube film includes at least one conductive pathway along a major axis of the conductive article.
2. The method of claim 1 wherein the nanotube film is formed by depositing a solution of suspended nanotubes on the substrate.
3. The method of claim 2 wherein the deposited solution is spun to create a spin-coating of the solution.
4. A method of making a conductive article on a substrate, comprising:
forming an accumulation of nanotubes on the substrate without forcing the nanotubes in alignment so that the orientation of each nanotube may vary relative to the other nanotubes;
depositing a mask layer over the accumulation of nanotubes;
lithographically patterning the mask layer, the pattern corresponding to the shape of the conductive article;
removing nanotubes in accordance with the pattern of the mask layer so that the remaining nanotubes form the conductive article.
5. The method of claim 4 wherein the accumulation of nanotubes is formed by depositing a solution of suspended nanotubes on the substrate.
6. The method of claim 5 wherein the deposited solution is spun to create a spin-coating of the solution.
7. A method of making a conductive article on a substrate, comprising:
providing a substantially planar fabric of pre-formed nanotubes on the substrate;
depositing a mask layer over the fabric of pre-formed nanotubes;
defining a pattern in the mask layer, the pattern corresponding to the shape of the conductive article;
removing nanotubes in accordance with the pattern of the mask layer to define the conductive article.
8. The method of claim 7 wherein the nanotubes are applied via a spin-coating operation.
9. The method of claim 7 wherein the fabric has controlled density.
10. The method of claim 7 wherein the fabric is substantially a monolayer of nanotubes.
11. The method of claim 8 wherein the thickness of the fabric is controlled via adjusting parameters of the spin coating operation.
12. The method of claim 8 wherein the thickness of the fabric is controlled via adjusting a spin profile of the spin coating operation.
13. The method of claim 8 wherein the thickness of the fabric is controlled via adjusting a spin-coating speed of the spin coating operation.
14. The method of claim 8 wherein the thickness of the fabric is controlled via adjusting a surface functionalization of a surface of the substrate.
15. The method of claim 8 wherein the thickness of the fabric is controlled via adjusting a surface pH of the substrate.
16. The method of claim 8 wherein the thickness of the fabric is controlled via adjusting the temperature of the environment of the spin coating operation.
17. The method of claim 8 wherein the thickness of the fabric is controlled via adjusting the duration of the spin coating operation.
18. A method of making a conductive article having a predefined shape on a substrate, comprising:
providing a plurality of nanotubes on the substrate wherein the nanotubes are in electrical contact;
depositing a mask layer over the plurality of nanotubes;
patterning the mask layer with a predefined shape, the pre-defined shape corresponding to the shape of the conductive article, wherein the predefined shape has a predefined orientation and wherein the nanotubes are not individually constrained to said orientation; and
removing nanotubes in accordance with the pattern of the mask layer to define the conductive article.