IP Library Granted Patent US 7,276,559
Granted Patent B2
US 7,276,559 · App. 11/012,753 · Granted Oct 2, 2007

Soft thermoplastic elastomers

Assignee: Advanced Elastomer Systems, L.P.
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Quick Facts
Patent No.
US 7,276,559
App. No.
11/012,753
Granted
Oct 2, 2007
Kind
B2
Abstract

This invention relates to a soft thermoplastic vulcanizate composition comprising: a) from about 2-10 wt %, based upon total polymer content weight a)+b)+c), of a thermoplastic polyethylene or polypropylene homopolymer, or ethylene-propylene copolymer, or copolymer that includes ethylene or propylene together with one or more C 4 to C 20 α-olefins, said thermoplastic having at least 25% crystallinity by DSC; b) from about 15 to about 36 wt. %, based upon total polymer content weight a)+b)+c), of an ethylene-α-olefin random or block copolymer thermoplastic having less than 5% crystallinity by DSC; c) from about 60 to about 80 wt. %, based upon total polymer content weight a)+b)+c), of a cross-linked elastomer; and d) from about 50 to about 65 wt %, based upon total composition weight a)+b)+c)+d), of a process oil; wherein said thermoplastic vulcanizate composition has a Shore A Hardness of less than 35. The invention compositions may also comprise from about 0 to about 40 wt. %, based upon the total composition weight, of conventional additives.

Claims (12)

1. A thermoplastic vulcanizate composition comprising:

a) from about 2-10 wt %, based upon total polymer content weight a)+b)+c), of a thermoplastic polyethylene or polypropylene homopolymer, or ethylene-propylene copolymer, or copolymer that includes ethylene or propylene together with one or more C 4 to C 20 α-olefins, said thermoplastic having at least 25% crystallinity by DSC;

b) from about 15 to about 36 wt. %, based upon total polymer content weight a)+b)+c), of a thermoplastic ethylene-α-olefin random or block copolymer having less than 5% crystallinity by DSC;

c) from about 60 to about 80 wt. %, based upon total polymer content weight a)+b)+c), of a cross-linked elastomer; and

d) from about 50 to about 65 wt %, based upon total composition weight a)+b)+c)+d), of a process oil;

wherein said thermoplastic vulcanizate composition has a Shore A Hardness of less than 35 and wherein the relative amount of b) to a)+b) is greater than 75 wt % and less than or equal to 90 wt. %.

2. The composition of claim 1 , wherein the thermoplastic ethylene-α-olefin random or block copolymer has a number-average molecular weight (M n ) of at least 25,000.

3. The composition of claim 1 , wherein the cross-linked elastomer is selected from the group of EADM and butyl rubber.

4. The composition of claim 1 , wherein not more than 5% of the cross-linked elastomer is extractable.

5. A molded article comprising the thermoplastic vulcanizate of claim 1 .

6. The composition of claim 1 wherein the relative amount of b) to a) is from about 80 wt. % to less than or equal to 90 wt. %.

7. The composition of claim 1 wherein the relative amount of b) to a) is from about 84 wt. % to less than or equal to 90 wt. %.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 25, 2022
From: EXXONMOBIL CHEMICAL PATENTS INC.
To: SANTOPRENE PRODUCTION PENSACOLA LLC
Reel/Frame 059248/0456 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 25, 2022
From: SANTOPRENE PRODUCTION PENSACOLA LLC
To: CELANESE INTERNATIONAL CORPORATION
Reel/Frame 059248/0673 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 23, 2011
From: ADVANCED ELASTOMER SYSTEMS, L.P.
To: EXXONMOBIL CHEMICAL PATENTS INC.
Reel/Frame 026796/0245 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 1, 2005
From: ABRAHAM, TONSON; SHEN, KUO-SHEIN; BARBER, NORMAN
To: ADVANCED ELASTOMER SYSTEMS, L.P.
Reel/Frame 015806/0299 →
Continuity (2)
Provisional Application 6057857200 · Jun 10, 2004
Related Publication 20050277735A1 · Dec 15, 2005