Thermoplastic olefin compositions and injection molded articles made thereof
View Patent ↗A thermoplastic polymer composition that exhibits substantially isotropic post injection molding shrinkage. The thermoplastic polymer composition includes a blend of highly crystalline polypropylene homopolymer, an ethylene-C 4-8 α-olefin plastomer and talc having a D 50 of about 2.0 μm or less. The thermoplastic polymer composition exhibits post injection molding shrinkage, low temperature impact strength and tensile strength that is similar to or better than relatively expensive engineering resins and blends. The thermoplastic polymer composition according to the invention is particularly useful for forming injection molded parts for motor vehicles.
1. A thermoplastic polymer composition comprising:
from about 25% to about 45% by weight of highly crystalline polypropylene homopolymer having a melt flow greater than 40 g/10 min as measured in accordance with ASTM D1238-04;
from about 15% to about 30% by weight of an ethylene-octene plastomer;
from about 10% to about 20% by weight of a propylene-ethylene impact copolymer;
less than about 1% by weight of rubber; and
from about 15% to about 35% by weight of talc having a D 50 of about 2.0 μm or less;
wherein the thermoplastic polymer composition exhibits post injection molding shrinkage in both a longitudinal flow direction and a transverse flow direction of less than 1.0%, the ratio of the percentage of post injection molding shrinkage in the longitudinal flow direction to the percentage of post injection molding shrinkage in the transverse flow direction is from about 0.8 to about 1.3, and the thermoplastic polymer composition exhibits a flexural modulus of 275,000 psi or greater as measured in accordance with ASTM D790-03.
2. An injection molded part for a motor vehicle formed of the thermoplastic polymer composition according to claim 1 .
3. A thermoplastic polymer composition consisting essentially of:
from about 10% to about 75% by weight of a highly crystalline polypropylene homopolymer having a melt flow greater than 40 g/10 min as measured in accordance with ASTM D1238-04;
from about 15% to about 30% by weight of an ethylene-C 4-8 α-olefin plastomer;
less than about 30% by weight of a propylene-ethylene impact copolymer;
less than about 1% by weight of rubber;
a nucleating agent derived from sorbitol, provided the content of the nucleating agent does not exceed about 0.5% by weight of the thermoplastic polymer composition; and
from about 10% to about 40% by weight of talc having a D 50 of about 2.0 μm or less;
wherein the thermoplastic polymer composition exhibits post injection molding shrinkage in both a longitudinal flow direction and a transverse flow direction of less than 1.0%, and wherein the ratio of the percentage of post injection molding shrinkage in the longitudinal flow direction to the percentage of post injection molding shrinkage in the transverse flow direction is from about 0.6 to about 1.5.
4. The thermoplastic polymer composition according to claim 3 wherein the thermoplastic polymer composition exhibits a flexural modulus of 275,000 psi or greater as measured in accordance with ASTM D790-03.
5. The thermoplastic polymer composition according to claim 3 wherein the ethylene-C 4-8 α-olefin plastomer is an ethylene-octene plastomer.
6. The thermoplastic polymer composition according to claim 3 wherein the ratio of the percentage of post injection molding shrinkage in the longitudinal flow direction to the percentage of post injection molding shrinkage in the transverse flow direction is from about 0.7 to about 1.4.
7. The thermoplastic polymer composition according to claim 3 wherein the ratio of the percentage of post injection molding shrinkage in the longitudinal flow direction to the percentage of post injection molding shrinkage in the transverse flow direction is from about 0.8 to about 1.3.
8. A thermoplastic polymer composition consisting essentially of:
from about 10% to about 75% by weight of a highly crystalline polypropylene homopolymer havirnz a melt flow greater than 40 g/10 min as measured in accordance with ASTM D1238-04;
from about 15% to about 30% by weight of an ethylene-C 4-8 α-olefin plastomer;
less than about 30% by weight of a propylene-ethylene impact copolymer;
less than about 1% by weight of rubber;
a nucleating agent derived from sorbitol, provided the content of the nucleating agent does not exceed about 0.5% by weight of the thermoplastic polymer composition;
from about 0.1% to about 0.5% by weight of ethylene bis-stearamide wax;
from about 0.1% to about 0.5% by weight calcium stearate; and
from about 10% to about 40% by weight of talc having a D 50 of about 2.0 μm or less;
wherein the thermoplastic polymer composition exhibits post injection molding shrinkage in both a longitudinal flow direction and a transverse flow direction of less than 1.0%, and wherein the ratio of the percentage of post injection molding shrinkage in the longitudinal flow direction to the percentage of post injection molding shrinkage in the transverse flow direction is from about 0.6 to about 1.5.