Removal of fluorinated surfactants from waste water

1. Method of removing a fluorinated surfactant from waste water comprising fluoropolymer particles, said method comprising (i) adding a non-fluorinated surfactant to said waste water (ii) contacting the thus obtained waste water with adsorbent particles to adsorb at least part of the fluorinated surfactant to said adsorbent particles and (iii) separating the waste water and the adsorbent particles.

2. Method according to claim 1 wherein said adsorbent particles comprise carbon black.

3. Method according to claim 1 wherein said non-fluorinated surfactant comprises a non-ionic surfactant.

4. Method according to claim 1 wherein said fluorinated surfactant comprises a fluorinated acid or salt thereof.

5. Method according to claim 4 wherein said fluorinated surfactant comprises a perfluoroaliphatic acid or salt thereof.

6. Method according to claim 1 wherein the amount of non-fluorinated surfactant is between 1 and 1000 ppm based on the amount of fluoropolymer particles in the waste water.

7. Method according to claim 1 further comprising regenerating the adsorbent particles.

8. Method according to claim 7 wherein said fluorinated surfactant comprises a perfluoroaliphatic acid or salt thereof and wherein the regenerating comprises mixing the adsorbent particles with an alcohol and an acid and heating the thus obtained mixture to cause esterification of said perfluoroaliphatic acid or salt thereof with said alcohol so as to produce an ester derivative of said perfluoroaliphatic acid.

9. Method according to claim 8 further comprising distilling the mixture, thereby forming a distillate containing said ester derivative, and separating said ester derivative from the distillate thereby yielding said ester derivative of said perfluoroaliphatic acid and a remainder of the distillate.

10. Method according to claim 9 wherein the remainder of the distillate is re-introduced in said mixture.