Methods of forming capping layers on reflective materials
View Patent ↗A reflective material is heated to reduce internal stress, and then a capping layer is formed over the reflective material. Heating the reflective material reduces the internal stress of the reflective material. Because the reflective material has reduced internal stress, a more continuous, stable and reliable capping layer is formed that is not subject to stress induced degradation over time due to the relaxing internal stress of the underlying reflective material. Thus, the capping layer remains intact and protects the reflective material residing beneath the capping layer from exposure to contaminants.
1. A method of forming a capping layer over a multi-layer mirror element, the method comprising:
providing the multi-layer mirror element, at least a top portion of the multi-layer mirror element having internal stress;
heating at least the multi-layer mirror element, thereby reducing the internal stress of at least the top portion of the multi-layer mirror element; and
forming the capping layer over the multi-layer mirror element.
2. The method according to claim 1 , wherein providing the multi-layer mirror element comprises providing a multi-layer mirror element that has been formed in a first deposition chamber, wherein without removing the multi-layer mirror element from the first deposition chamber, the multi-layer mirror element is heated and the capping layer is formed over the multi-layer mirror element.
3. The method according to claim 1 , wherein heating at least the multi-layer mirror element reduces the internal stress of at least the top potion of the multi-layer mirror element by about 10% or greater.
4. The method according to claim 1 , wherein forming the capping layer comprises forming a capping layer comprising a noble metal or alloy, a ceramic material, a transition metal, or a metal oxide.
5. The method according to claim 1 , wherein the multi-layer mirror element comprises a reflective lithography mask.
6. The method according to claim 1 , wherein heating at least the multi-layer mirror element comprises heating at least the multi-layer mirror element to a temperature of about 300 degrees C. or less.
7. The method according to claim 1 , wherein the multi-layer mirror element comprises a substrate and a plurality of material layers disposed over the substrate, wherein the substrate and plurality of material layers have internal stress, and wherein heating at least the multi-layer mirror element comprises decreasing the internal stress of the substrate and the plurality of material layers.
8. A method of manufacturing a multi-layer mirror element, the method comprising:
providing a substrate;
forming a plurality of material layers over the substrate, the plurality of material layers comprising a first internal stress;
heating at least the plurality of material layers to reduce the first internal stress; and
forming a capping layer over the plurality of material layers.
9. The method according to claim 8 , further comprising forming a diffusion barrier over the plurality of material layers.
10. The method according to claim 8 , wherein forming the diffusion barrier comprises forming about 10 nm or less of boron carbide (B 4 C), C, B, Si, Be, Mg, or Al.
11. The method according to claim 8 , wherein forming the plurality of material layers is performed in a first deposition chamber, and wherein heating at least the plurality of material layers and forming the capping layer are performed in the first deposition chamber after forming the plurality of material layers without removing the substrate from the first deposition chamber.
12. The method according to claim 8 , wherein forming the plurality of material layers is performed in a first deposition chamber, further comprising moving the substrate to a second deposition chamber while protecting the plurality of material layers from oxidation, and wherein forming the capping layer is performed in the second deposition chamber.
13. The method according to claim 8 , wherein heating at least the plurality of material layers reduces the first internal stress of plurality of material layers by about 10% or greater.
14. The method according to claim 8 , wherein forming the capping layer comprises forming a capping layer comprising a noble metal or alloy, a ceramic material, a transition metal, or a metal oxide.
15. The. method according to claim 14 , wherein forming the capping layer comprises forming about 3 nm or less of Ru, Ru oxide, Zr, Pd, PdAu, SiC, MoSi 2 , or Yttrium Stabilized Zirconium (YSZ).
16. The method according to claim 8 , wherein heating at least the plurality of material layers comprises heating at least the plurality of material layers a temperature of about 300 degrees C. or less.
17. The method according to claim 8 , wherein heating at least the plurality of material layers comprises heating at least the plurality of material layers for a time period of about 30 minutes or greater.
18. The method according to claim 8 , wherein the multi-layer mirror element has an expected lifetime and a predicted stress level at the end of the expected lifetime, wherein heating at least the plurality of material layers comprises reducing the first internal stress to at least the predicted stress level at the end of the expected lifetime of the multi-layer mirror element.
19. The method according to claim 8 , wherein providing the substrate comprises providing a substrate having a second internal stress, wherein heating at least the plurality of material layers further comprises heating the substrate, and wherein heating the substrate comprises reducing the second internal stress.
20. The method according to claim 8 , wherein at least heating at least the plurality of material layers comprises exposing the plurality of material layers to an inert gas.
21. The method according to claim 20 , wherein exposing the plurality of material layers to the inert gas comprises exposing the plurality of material layers to Ar or N.
22. The method according to claim 8 , wherein forming the plurality of material layers comprises forming a diffusion barrier layer between each of the plurality of material layers.
23. A method of manufacturing a multi-layer mirror element of an extreme ultraviolet lithography (EUVL) system, the method comprising:
providing a substrate;
placing the substrate in a deposition chamber;
forming a plurality of material layers over the substrate, the plurality of material layers comprising a first internal stress;
heating at least the plurality of material layers, reducing the first internal stress; and
forming a capping layer over the plurality of material layers, wherein forming the plurality of material layers, heating at least the plurality of material layers, and forming the capping layer are performed in the deposition chamber without removing the substrate from the deposition chamber.
24. The method according to claim 23 , further comprising forming a diffusion barrier over the plurality of material layers, before or after heating at least the plurality of material layers.
25. The method according to claim 23 , wherein providing the substrate comprises providing a substrate with a second internal stress, wherein heating at least the plurality of material layers further comprises heating the substrate, wherein heating the substrate reduces the second internal stress.