Silver powder and method for producing same
View Patent ↗There is provided a method for producing a silver powder having excellent dispersibility and capable of forming a paste which do not form suspended matters by phase separation and which is printed on a substrate to form a film having a uniform thickness. In this method, an alkali or a complexing agent is added to an aqueous silver salt containing solution to form a silver oxide containing slurry or an aqueous silver complex salt containing solution. After or before silver particles are deposited by reduction by adding a reducing agent to the silver oxide containing slurry or aqueous silver complex salt containing solution while stirring it, at least one chelating agent selected from the group consisting of compounds having an azole structure, dicarboxylic acids, hydroxy carboxylic acids and salts thereof is added to a silver power containing slurry solution as a dispersing agent.
1. A method for producing a silver powder, said method comprising the steps of:
adding a reducing agent to an aqueous solution of at least one of a silver salt and silver oxide for depositing silver particles to form a silver containing slurry;
adding a dispersing agent to said aqueous solution for dispersing said silver particles in said silver containing slurry; and
filtering, washing and drying said silver containing slurry to form a silver powder,
wherein said dispersing agent is added before said reducing agent is added to deposit the silver particles, and
said dispersing agent is at least one selected from the group consisting of compounds having an azole structure and salts thereof.
2. A method for producing a silver powder as set forth in claim 1 , wherein said dispersing agent is benzotriazole or benzotriazole sodium.
3. A method for producing a silver powder as set forth in claim 1 , wherein said aqueous solution is an aqueous silver ammine complex salt solution.