Methods and structures for metal interconnections in integrated circuits
View Patent ↗A typical integrated-circuit fabrication requires interconnecting millions of microscopic transistors and resistors with metal wires. Making the metal wires flush, or coplanar, with underlying insulation requires digging trenches in the insulation, and then filling the trenches with metal to form the wires. The invention provides a new “trench-less” or “self-planarizing” method of making coplanar metal wires. Specifically, one embodiment forms a first layer that includes silicon and germanium; oxidizes a region of the first layer to define an oxidized region and a non-oxidized region; and reacts aluminum or an aluminum alloy with the non-oxidized region. The reaction substitutes, or replaces, the non-oxidized region with aluminum to form a metallic wire coplanar with the first layer. Another step removes germanium oxide from the oxidized region to form a porous insulation having a very low dielectric constant, thereby reducing capacitance.
1. A method of fabricating a conductive structure in an integrated circuit, the method comprising:
forming a silicon-germanium layer;
forming a silicon nitride mask layer over the silicon-germanium layer;
removing a portion of the silicon nitride mask layer to expose a first region of the silicon-germanium layer;
oxidizing the exposed first region of the silicon-germanium layer, wherein a second region of the silicon-germanium layer covered by the silicon nitride layer remains un-oxidized;
after oxidizing, removing remaining portions of the silicon nitride mask layer;
depositing a metallic layer over the first and second regions of the silicon-germanium layer; and
annealing the integrated circuit to substitute metal from the metallic layer for the un-oxidized silicon-germanium of the second region to form the conductive structure.
2. The method of claim 1 wherein the silicon-germanium layer comprises silicon and between 10 and 40 percent germanium.
3. The method of claim 1 wherein the metallic layer comprises an aluminum alloy.
4. The method of claim 3 wherein the aluminum alloy comprises copper.
5. The method of claim 3 wherein the aluminum alloy comprises silicon.
6. The method of claim 1 further comprising forming a layer including titanium, zirconium, or hafnium on the metallic layer prior to annealing.
7. A method of fabricating a conductive structure in an integrated circuit, the method comprising:
forming a silicon-germanium layer;
forming a silicon nitride mask layer over the silicon-germanium layer;
removing a portion of the silicon nitride mask layer to expose a first region of the silicon-germanium layer;
oxidizing the exposed first region of the silicon-germanium layer, wherein a second region of the silicon-germanium layer covered by the silicon nitride layer remains un-oxidized;
after oxidizing, removing remaining portions of the silicon nitride mask layer;
depositing a metallic layer over the first and second regions of the silicon-germanium layer;
annealing the integrated circuit to substitute metal from the metallic layer for the un-oxidized silicon-germanium of the second region to form the conductive structure; and
removing silicon-germanium oxide from the first region to provide a porous oxide region.
8. The method of claim 7 wherein the silicon-germanium layer comprises silicon and between 10 and 40 percent germanium.
9. The method of claim 7 wherein the metallic layer comprises an aluminum alloy.
10. The method of claim 9 wherein the aluminum alloy comprises copper.
11. The method of claim 9 wherein the aluminum alloy comprises silicon.
12. The method of claim 7 further comprising forming a layer including titanium, zirconium, or hafnium on the metallic layer prior to annealing.
13. A method of fabricating a conductive structure in an integrated circuit, the method comprising:
forming a first layer;
selectively oxidizing a first region of the first layer, wherein a second region of the first layer remains un-oxidized;
after selectively oxidizing the first region depositing a metallic layer over the first and second regions of the first layer; and
annealing the integrated circuit to substitute metal from the metallic layer for material of the un-oxidized second region to form the conductive structure.
14. The method of claim 13 wherein the first layer comprises silicon-germanium.
15. The method of claim 14 wherein the silicon-germanium comprises silicon and between 10 and 40 percent germanium.
16. The method of claim 13 wherein the metallic layer comprises an aluminum alloy.
17. A method of fabricating a conductive structure in an integrated circuit, the method comprising:
forming a first layer;
selectively oxidizing a first region of the first layer, wherein a second region of the first layer remains un-oxidized;
after selectively oxidizing the first region depositing a metallic layer over the first and second regions of the first layer;
annealing the integrated circuit to substitute metal from the metallic layer for material of the un-oxidized second region to form the conductive structure; and
removing material from the oxidized first region to provide a porous insulator region.
18. The method of claim 17 wherein the first layer comprises silicon-germanium.
19. The method of claim 18 wherein the silicon-germanium comprises silicon and between 10 and 40 percent germanium.
20. The method of claim 17 wherein the metallic layer comprises an aluminum alloy.