Inkjet ink composition
View Patent ↗An inkjet ink composition having a binder including an aqueous dispersion of polymer particles, the polymer comprising as polymerized units from 3 to 20 wt. % monoethylenically unsaturated acid monomer, based on polymer weight, and having a glass transition temperature (Tg) in the range of from −40° C. to 120° C., and the polymer particles having a volume average particle diameter as measured by dynamic light scattering of at least 35 nanometers greater than the weight average particle diameter as measured by capillary hydrodynamic fractionation is provided. An inkjet ink composition including the inkjet ink binder is also provided.
1. An inkjet ink composition comprising a colorant, a liquid medium, and an inkjet ink binder, said binder comprising an aqueous dispersion of polymer particles, said polymer comprising as polymerized units from 3 to 20 wt. % monoethylenically unsaturated acid monomer, based on polymer weight, and having a glass transition temperature (Tg) in the range of from −40° C. to 120° C., and said polymer particles having a volume average particle diameter as measured by dynamic light scattering of at least 35 nanometers greater than the weight average particle diameter as measured by capillary hydrodynamic fractionation; and
wherein said polymer particles have been formed by emulsion polymerization in the presence of a neutralizer in the amount of from 20 to 75%, on an equivalents basis, based on said monoethylenically unsaturated acid monomer.
2. The inkjet ink composition of claim 1 wherein said polymer particles have a volume average particle diameter as measured by dynamic light scattering of at least 45 nanometers greater than the weight average particle diameter as measured by capillary hydrodynamic fractionation.
3. The inkjet ink composition of claim 1 wherein said polymer particles have a volume average particle diameter as measured by dynamic light scattering of at least 55 nanometers greater than the weight average particle diameter as measured by capillary hydrodynamic fractionation.
4. The inkjet ink composition of claim 1 wherein the neutralizer is a hard base.
5. The inkjet ink composition of claim 1 wherein said polymer particles have a weight average particle diameter of from 100 to 450 nanometers.
6. The inkjet ink composition of claim 1 wherein said colorant comprises a pigment.
7. The inkjet ink composition of claim 6 , wherein said pigment is surface-modified to be self dispersing.
8. The inkjet ink composition of claim 6 , wherein said Tg is in the range of from about −300° C. to about 100° C.
9. The inkjet ink composition of claim 7 , wherein the glass transition temperature ranges from about −20° C. to about +25° C.
10. The inkjet ink composition of claim 7 wherein said acid monomer comprises methacrylic acid.
11. The inkjet ink composition of claim 7 wherein said acid monomer comprises acrylic acid.
12. The inkjet ink composition of claim 7 wherein said acid monomer ranges from about 3% to about 6% by weight of said polymer.
13. The inkjet ink composition of claim 7 wherein said ink composition comprises from about 0.5% to about 10% colorant, by weight of said ink composition, and from about 0.1% to about 10% polymer by weight of said ink composition.
14. The inkjet ink composition of claim 7 wherein said ink composition comprises from about 0.5% to about 7% colorant by weight of the ink composition; and from about 2% to about 3% polymer by weight of the ink composition.
15. The inkjet ink composition of claim 7 wherein said ink composition comprises from about 1% to about 6% colorant by weight of the ink composition and said polymer is present at about 2% by weight of the ink composition.
16. The inkjet ink composition of claim 7 wherein the glass transition temperature of said polymer is about −2.5° C. and the weight average molecular weight of said polymer is about 450,000.
17. The inkjet ink composition of claim 7 wherein said colorant comprises a self-dispersed pigment and a dispersed pigment mixture.
18. The inkjet ink composition of claim 7 wherein said inkjet ink binder further comprises a surfactant.
19. The inkjet ink composition of claim 12 wherein said binder comprises one or more surfactants selected from the group consisting of sodium lauryl sulfate, sodium allyl dodecyl sulfosuccinate, sodium linear-dodecyl benzenesulfonate, allylammonium nonphenol-(EO)10-phosphate, ammonium lauryl sulfate, linear (C12-14 alkyl)-(EO)4-sodium sulfate, potassium linear-dodecyl benzenesulfonate, and combinations thereof.
20. The inkjet ink composition of claim 7 wherein the Tg of said polymer ranges from −20° C. to about 0° C. and the weight average molecular weight of the polymeric binder ranges from about 300,000 to about 450,000.
21. The inkjet ink composition of claim 7 further comprising a surfactant.
22. The inkjet ink composition of claim 7 wherein said polymer comprises one or more monomers selected from the group consisting of acrylates, methacrylates, substituted styrenes, styrenes, fluoromethacrylates, vinyl acetate, acrylamides, substituted acrylamides, methacrylamides and substituted methacrylamides; and said acid monomer selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, maleic acids, vinylsulfonic acids and acids derived from methacrylic anhydride, maleic anhydride, sodium vinylsulfonate or acrylamido propane sulfonate, and combinations thereof.
23. The inkjet ink composition of claim 7 wherein said inkjet ink binder further comprises a mixture of a plurality of larger particles and a plurality of smaller particles, and further wherein the binder mixture is bimodal.
24. The inkjet ink composition of claim 7 further comprising a humectant and a penetrant, wherein said humectant ranges from about 1% to about 30% by weight of the ink composition and said penetrant ranges from about 0.01% to about 10% by weight of said ink composition.
25. The inkjet ink composition of claim 7 wherein the binder mixture is unimodal.