IP Library Granted Patent US 7,553,691
Granted Patent B2
US 7,553,691 · App. 11/114,454 · Granted Jun 30, 2009

Method and apparatus of multiplejunction solar cell structure with high band gap heterojunction middle cell

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Quick Facts
Patent No.
US 7,553,691
App. No.
11/114,454
Granted
Jun 30, 2009
Kind
B2
Abstract

A method and a multijunction solar device having a high band gap heterojunction middle solar cell are disclosed. In one embodiment, a triple-junction solar device includes bottom, middle, and top cells. The bottom cell has a germanium (Ge) substrate and a buffer layer, wherein the buffer layer is disposed over the Ge substrate. The middle cell contains a heterojunction structure, which further includes an emitter layer and a base layer that are disposed over the bottom cell. The top cell contains an emitter layer and a base layer disposed over the middle cell.

Claims (45)

1. A method for manufacturing a triple-junction solar cell comprising:

providing a germanium substrate; forming a bottom cell in the substrate;

forming a heterojunction middle cell over the bottom cell; and

forming a homojunction top cell over the heterojunction middle cell.

2. The method of claim 1 , further comprising:

forming a first tunnel junction layer over the bottom cell;

depositing an indium gallium arsenide (InGaAs) base layer over the first tunnel junction layer; and

depositing a first indium gallium phosphide (InGaP) emitter layer over the InGaAs base layer.

3. The method of claim 2 , wherein the step of forming a first tunnel junction layer comprises:

depositing a gallium arsenide (GaAs) layer on the bottom cell; and

depositing an aluminum gallium arsenide (AlGaAs) layer over the GaAs layer.

4. The method of claim 2 , wherein the step of forming a heterojunction middle cell comprises:

depositing an aluminum gallium arsenide (AlGaAs) back surface field (BSF) layer on the first tunnel junction layer;

depositing an indium gallium arsenide (InGaAs) set back (SB) layer over the InGaAs base layer; and

depositing a first indium aluminum phosphide (InAlP) window layer over the InGaP emitter layer.

5. The method of claim 2 , wherein the step of forming a homojunction top cell over the heterojunction middle cell comprises:

forming a second tunnel junction layer over the middle cell;

depositing an indium gallium phosphide (InGaP) base layer over the second tunnel junction layer; and

depositing a second indium gallium phosphide (InGaP) emitter layer over the InGaP base layer.

6. The method of claim 5 , wherein the step of forming a second tunnel junction layer further comprises:

depositing an indium phosphide (InGaP) layer on the middle cell; and

depositing an aluminum gallium arsenide (AlGaAs) layer over the InGaP layer.

7. The method of claim 5 , wherein the step of forming a homojunction top cell over the heterojunction middle cell comprises:

depositing an indium gallium aluminum phosphide (InGaAlP) back surface field (BSF) layer on the second tunnel junction layer; and

depositing an indium gallium phosphide (InGaP) set back (SB) layer between the InGaP base layer and the InGaP emitter layer.

8. The method of claim 7 , wherein the step of forming a homojunction top cell further comprises:

depositing a second indium aluminum phosphide (InAlP) window layer on the InGaP emitter layer; and

depositing a gallium arsenide (GaAs) contact layer on the second InAlP window layer.

9. A method for forming a multijunction solar cell comprising:

forming a first cell including a germanium (Ge) substrate;

forming a second cell disposed over the first cell having a heterojunction solar cell structure including a first emitter layer and a first base layer; and

forming a homojunction third cell disposed over the second cell.

10. The method of claim 9 , further comprising:

forming a first tunnel junction layer disposed between the first and second cells;

forming a second tunnel junction layer disposed between the second and third cells; and

forming a contact layer including gallium arsenide (GaAs) disposed over the third cell.

11. The method of claim 9 , wherein the first cell is the bottom cell of the multijunction solar cell and further comprising a nucleation layer disposed over the Ge substrate.

12. The method of claim 9 , further comprising:

forming a buffer layer that includes GaAs deposited over the Ge substrate.

13. The method of claim 9 , wherein the second cell is a middle cell that includes a window layer that includes indium aluminum phosphide (InAlP) disposed over the first emitter layer.

14. The method of claim 9 , wherein the first base layer includes indium gallium arsenide (InGaAs) and the first emitter layer includes indium gallium phosphide (InGaP).

15. The method of claim 9 , wherein the third cell is a top cell having a second emitter layer and a second base layer, and further comprising a window layer that includes indium aluminum phosphide (InAlP) disposed over the second emitter layer.

16. The method of claim 15 , wherein the second base layer includes indium gallium arsenide (InGaAs).

17. The method of claim 15 , wherein the second emitter layer includes InGaAs.

18. The method of claim 9 , wherein the third cell has a homojunction structure including second base and emitter layers that have substantially the same material composition.

Assignments (11)
SECURITY INTEREST Recorded Apr 17, 2019
From: SOLAERO TECHNOLOGIES CORP.
To: CITIZENS BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 048930/0952 →
NOTICE OF RELEASE OF SECURITY INTEREST IN PATENTS Recorded Apr 12, 2019
From: CITIZENS BANK, N.A. (SUCCESSOR BY MERGER TO CITIZENS BANK OF PENNSYLVANIA), AS ADMINISTRATIVE AGENT
To: SOLAERO SOLAR POWER INC. (F/K/A EMCORE SOLAR POWER, INC)
Reel/Frame 049455/0179 →
NOTICE OF RELEASE OF SECURITY INTEREST IN PATENTS Recorded Apr 12, 2019
From: CITIZENS BANK, N.A. (SUCCESSOR BY MERGER TO CITIZENS BANK OF PENNSYLVANIA), AS ADMINISTRATIVE AGENT
To: SOLAERO TECHNOLOGIES CORP.
Reel/Frame 048877/0802 →
SECURITY INTEREST Recorded Oct 17, 2018
From: SOLAERO TECHNOLOGIES CORP.
To: CITIZENS BANK OF PENNSYLVANIA, AS ADMINISTRATIVE AGENT FOR THE SECURED PARTIES
Reel/Frame 047246/0418 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 12, 2015
From: EMCORE SOLAR POWER, INC.
To: SOLAERO TECHNOLOGIES CORP.
Reel/Frame 034750/0211 →
SECURITY INTEREST Recorded Dec 12, 2014
From: EMCORE SOLAR POWER, INC.
To: CITIZENS BANK OF PENNSYLVANIA, AS ADMINISTRATIVE AGENT
Reel/Frame 034612/0961 →
RELEASE OF SECURITY INTEREST Recorded Dec 10, 2014
From: WELLS FARGO BANK, N.A.
To: EMCORE SOLAR POWER, INC.
Reel/Frame 034590/0761 →
RELEASE OF SECURITY INTEREST Recorded Oct 12, 2011
From: BANK OF AMERICA, N.A.
To: EMCORE CORPORATION; EMCORE SOLAR POWER, INC.
Reel/Frame 027050/0880 →
SECURITY AGREEMENT Recorded May 18, 2011
From: EMCORE CORPORATION; EMCORE SOLAR POWER, INC.
To: WELLS FARGO BANK, NATIONAL ASSOCIATION
Reel/Frame 026304/0142 →
SECURITY AGREEMENT Recorded Nov 12, 2008
From: EMCORE CORPORATION
To: BANK OF AMERICA, N.A.
Reel/Frame 021824/0019 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 12, 2008
From: EMCORE CORPORATION
To: EMCORE SOLAR POWER, INC.
Reel/Frame 021817/0929 →