Molding compositions
View Patent ↗A curable composition exhibiting excellent moldability without mold staining or delamination is provided, including an epoxy resin, a curing agent for the epoxy resin, and a polyphenylene oxide compound having a glass transition temperature between about 165° C. and about 190° C. The polyphenylene oxide compound may be provided as a melt blended mixture of two polyphenylene oxide compounds having distinct glass transition temperatures. The curable compositions may further include a bulk filler, and are therefore particularly useful as molding compounds encapsulation of electrical and/or electronic parts in transfer molding operations.
1. A curable composition comprising:
an epoxy resin;
a curing agent for promoting curing of the epoxy resin; and
a polyphenylene oxide component comprising a melt blended mixture of at least two different polyphenylene oxide compounds having different glass transition temperatures, wherein the at least two different polyphenylene oxide compounds are melt blended in the absence of the epoxy resin,
wherein the glass transition temperature of a first polyphenylene oxide compound is below about 200° C., and the glass transition temperature of a second polyphenylene oxide compound is above about 220° C., and
wherein the ratio of the first polyphenylene oxide compound to the second polyphenylene oxide compound is from about 3:1 to 1:1.
2. The composition of claim 1 , wherein the polyphenylene oxide component comprises from about 0.8 percent to about 2.0 percent by weight of the total composition.
3. The composition of claim 1 , wherein the epoxy resin is selected from the group consisting of novolac type epoxy resins, bisphenol A type epoxy resins, alicyclic epoxy resins, glycidyl type epoxy resins, biphenyl epoxy resins, napthalene-ring containing epoxy resins, cyclopentadiene-containing epoxy resins, polyfunctional epoxy resins, hydroquinone epoxy resins, stilbene epoxy resins, and combinations thereof.
4. The composition of claim 1 , wherein the curing agent is selected from the group consisting of phenol novolac type hardeners, cresol novolac type hardeners, dicyclopentadiene phenol type hardeners, limonene type hardeners, anhydrides, flexible hardeners, and combinations thereof.
5. The composition of claim 1 , further comprising an inorganic filler material.
6. The composition of claim 5 , wherein the polyphenylene oxide component comprises from about 0.8 percent to about 2.0 percent by weight of the total composition.
7. The composition of claim 5 , wherein the epoxy resin is selected from the group consisting of novolac type epoxy resins, bisphenol A type epoxy resins, alicyclic epoxy resins, glycidyl type epoxy resins, biphenyl epoxy resins, napthalene-ring containing epoxy resins, cyclopentadiene-containing epoxy resins, polyfunctional epoxy resins, hydroquinone epoxy resins, stilbene epoxy resins, and combinations thereof.
8. The composition of claim 5 , wherein the curing agent is selected from the group consisting of phenol novolac type hardeners, cresol novolac type hardeners, dicyclopentadiene phenol type hardeners, limonene type hardeners, anhydrides, flexible hardeners, and combinations thereof.
9. The composition of claim 5 , wherein the curing agent comprises a flexible hardener having a hydroxyl equivalent weight greater than about 150.
10. The composition of claim 5 , wherein said filler comprises materials selected from the group consisting of silica, alumina, aluminum oxide, aluminosilicate, silicon nitride, aluminum nitride, silica-coated aluminum nitride, born nitride, clay, talc, mica, kaolin, calcium carbonate, wollastonite, montmorillonite, smectite, rubber particles, nanoparticles, nanoclays, and combinations thereof.
11. The composition of claim 5 , further comprising one or more components selected from the group consisting of coupling agents, adhesion modifiers, mold release agents, colorants, rheology modifiers, catalysts, antioxidants, ion scavengers, flame retardants, and combinations thereof.
12. An encapsulant material comprising a reaction product of the composition of claim 5 .
13. An electronic device comprising an encapsulant material comprising a reaction product of the composition of claim 5 encapsulating an electronic substrate.
14. The curable composition of claim 1 , wherein the glass transition temperature of said first polyphenylene oxide compound is from 150 to 180° C., and the glass transition temperature of said second polyphenylene oxide compound is from 220 to 250° C.
15. The curable composition of claim 1 , wherein the ratio of the first polyphenylene oxide compound to the second polyphenylene oxide compound is selected from the group consisting of about 2.3:1 and about 1.5:1.
16. The curable composition of claim 1 , wherein the ratio of the first polyphenylene oxide compound to the second polyphenylene oxide compound is about 1.5:1.
17. A method of reducing staining of mold surfaces during a transfer molding operation comprising providing an epoxy-based molding composition comprising:
an epoxy resin;
a curing agent for promoting curing of the epoxy resin; and
a polyphenylene oxide component comprising a melt blended mixture of at least two different polyphenylene oxide compounds having different glass transition temperatures, wherein the at least two different polyphenylene oxide compounds are melt blended in the absence of the epoxy resin,
wherein the glass transition temperature of a first polyphenylene oxide compound is below about 200° C., and the glass transition temperature of a second polyphenylene oxide compound is above about 220° C.,
wherein the ratio of the first polyphenylene oxide compound to the second polyphenylene oxide compound is from about 3:1 to 1:1.
18. A method of coating an electrical or electronic device, comprising heating a molding composition to a temperature sufficient to cure the molding composition and form a polymer on the surface of the device, wherein the molding composition comprises:
an epoxy resin;
a curing agent for promoting curing of the epoxy resin; and
a polyphenylene oxide component comprising a melt blended mixture of at least two different polyphenylene oxide compounds having different glass transition temperatures, wherein the at least two different polyphenylene oxide compounds are melt blended in the absence of the epoxy resin,
wherein the glass transition temperature of a first polyphenylene oxide compound is below about 200° C., and the glass transition temperature of a second polyphenylene oxide compound is above about 220° C., and
wherein the ratio of the first polyphenylene oxide compound to the second polyphenylene oxide compound is from about 3:1 to 1:1.
19. The method of claim 18 , wherein the electrical or electronic device is selected from a semiconductor, a transistor, a diode, or an integrated circuit.
20. An electrical or electronic device formed by the method of claim 18 .