Flame-retardant molding compositions
View Patent ↗A flame-retardant molding composition that includes an epoxy resin, melamine cyanurate, and one or more hydrated metal salts capable of liberating water when heated. The hydrated metal salt may include one or more compounds selected from metal borate salts, Group IIB oxides, and polyhydroxides of one or more elements selected from Group IIA elements and Group IIIB elements. The molding composition may be used to coat an electrical or electronic device by heating the molding composition to a temperature sufficient to cure the molding composition and form a polymer on the surface of the device. Electrical and electronic devices formed by the method are also disclosed.
1. A flame-retardant molding composition substantially free of halogen, phosphorus, and antimony, comprising:
a) an epoxy resin; and
b) a flame retardant formulation consisting essentially of:
melamine cyanurate;
one or more metal borate salts; and
a compound selected from the group consisting of one or more polyhydroxides of one or more elements selected from Group IIA elements and Group IIIB elements, one or more Group IIB oxides, and mixtures thereof.
2. The molding composition of claim 1 , wherein the metal borate salt comprises zinc borate.
3. The molding composition of claim 1 , wherein the polyhydroxide is a metal polyhydroxide selected from the group consisting one or more aluminum trihydrate, magnesium hydroxide, and calcium hydroxide, and the Group IIB oxides comprise zinc oxide.
4. The molding composition of claim 3 , wherein the metal borate salt comprises zinc borate.
5. The molding composition of claim 1 , further comprising a phenolic novolac hardener.
6. The molding composition of claim 1 , wherein the molding composition comprises an epoxy cresol novolac resin.
7. The molding composition of claim 6 , wherein the molding composition further comprises a biphenyl epoxy resin.
8. The molding composition of claim 1 , wherein the one or more metal borate salts comprises zinc borate and one or more compounds selected from the group consisting of zinc oxide and a metal polyhydroxide comprising one or both of aluminum trihydrate and magnesium hydroxide.
9. A flame-retardant molding composition substantially free of halogen, phosphorus, and antimony, consisting essentially of:
about 4 wt. % to about 12 wt. % of an epoxy resin;
about 0.1 wt. % to about 3.5 wt. % of melamine cyanurate;
about 0.1 wt. % to about 2 wt. % of zinc borate;
about 0.01 wt. % to about 1 wt. % of one or more compounds selected from the group consisting of zinc oxide and metal polyhydroxides comprising one or both of aluminum trihydrate and magnesium hydroxide;
about 0.001 wt. % to about 10 wt. % of a phenolic novolac hardener;
about 0 wt. % to about 90 wt. % of one or more solvents; and
about 0.1 wt. % to about 10 wt. % each of one or more additives selected from the group consisting of colorants, mold release agents, coupling agents, catalysts, ion scavengers, metal oxides, metal hydroxides, pigments, adhesion promoters, toughening agents, UV absorbers, and antioxidants.
10. A method of coating an electrical or electronic device, comprising heating a molding composition to a temperature sufficient to cure the molding composition and form a polymer on the surface of the device; wherein the molding composition, which is substantially free of halogen, phosphorus, and antimony, comprises:
a) an epoxy resin;
b) a flame retardant formulation consisting essentially of:
a melamine cyanurate;
one or more metal borate salts; and
one or more compounds selected from the group consisting of zinc oxide and polyhydroxides of one or more elements selected from Group IIA elements and Group IIIB elements.
11. The method of claim 10 , wherein the temperature ranges from about 165° C. to 195° C.
12. The method of claim 10 , wherein the metal borate salt comprises zinc borate and wherein the polyhydroxide is a metal polyhydroxide selected from the group consisting of one or both of aluminum trihydrate and magnesium hydroxide.
13. The method of claim 10 , wherein the molding composition further comprises a phenolic novolac hardener.
14. The method of claim 10 , wherein the molding composition comprises an epoxy cresol novolac resin.
15. The method of claim 14 , wherein the molding composition further comprises a biphenyl epoxy resin.
16. The method of claim 10 , wherein the device is an electrical or electronic device.
17. The method of claim 16 , wherein the electrical or electronic device is selected from a semiconductor, a transistor, a diode, or an integrated circuit.
18. An electrical or electronic device formed by the method of claim 10 .
19. The molding composition of claim 1 , wherein the polyhydroxide comprises one or both of aluminum trihydrate and magnesium hydroxide.
20. The molding composition of claim 1 , wherein the Group IIB oxide comprises zinc oxide.
21. The molding composition of claim 1 , wherein the weight ratio of melamine cyanurate in the flame retardant formulation of b) to the combination of the one or more metal borate salts and the one or more polyhydroxides and one or more Group IIB oxides is from 2:1 to 4:1.
22. The molding composition of claim 9 , wherein the weight ratio of melamine cyanurate to the zinc oxide and metal polyhydroxides in combination is from 2:1 to 4:1.
23. The method of claim 10 , wherein the weight ratio of melamine cyanurate in the flame retardant formulation of b) to the combination of the one or more metal borate salts and the one or more polyhydroxides and one or more Group IIB oxides is from 2:1 to 4:1.