IP Library Granted Patent US 7,535,462
Granted Patent B2
US 7,535,462 · App. 11/143,539 · Granted May 19, 2009

Touchscreen with one carbon nanotube conductive layer

Assignee: Eastman Kodak Company
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Quick Facts
Patent No.
US 7,535,462
App. No.
11/143,539
Filed
Jun 2, 2005
Granted
May 19, 2009
Kind
B2
Examiner
SHENG, TOM V
Art Unit
2629
USPC
345/174
Abstract

The present invention is directed to a touchscreen comprising touch side electrode and device side electrode wherein each electrode comprises an insulating substrate and an exposed electrically conductive layer, wherein said exposed electrically conductive layers are adjacent and separated by dielectric spacers, and wherein only one of the exposed electrically conductive layers comprises carbon nanotubes.

Claims (41)

1. A touchscreen comprising touch side electrode and device side electrode wherein each electrode comprises an insulating substrate and an exposed electrically conductive layer, wherein said exposed electrically conductive layers are adjacent and separated by dielectric spacers, wherein only one of the exposed electrically conductive layers comprises carbon nanotubes wherein said carbon nanotubes comprise single-wall carbon nanotubes and wherein said carbon nanotubes comprise covalently attached hydrophilic species.

2. The touchscreen of claim 1 wherein at least one of said electrodes comprises an electrically conductive layer comprising at least one material selected from the group consisting of electronically conductive polymers, transparent conducting oxides and transparent metal films.

3. The touchscreen of claim 2 wherein said electrically conductive layer comprises a mixture of a cationic polyethylenedioxythiophene and polyanion.

4. The touchscreen of claim 3 wherein said mixture of a cationic polyethylenedioxythiophene and polyanion has a figure of merit of less than 50.

5. The touchscreen of claim 2 wherein said electrically conductive layer comprises polypyrrole, polyaniline or polythiophene.

6. The touchscreen of claim 2 wherein said electrically conductive layer not comoprising carbon nanotubes comprises tin doped indium oxide, fluorine doped zinc oxide, aluminum doped zinc oxide, indium doped zinc oxide, antimony doped tin oxide, or fluorine doped tin oxide.

7. The touchscreen of claim 2 wherein said electrically conductive layer comprises a transparent metal film comprising silver, gold, copper, palladium, platinum or alloys of these materials.

8. The touchscreen of claim 2 wherein said electronically conductive polymer comprises a binder.

9. The touchscreen of claim 8 wherein said binder comprises polyvinylalcohol, polyvinylbutyral, polyacrylates, polyurethanes or epoxies.

10. The touchscreen of claim 1 wherein the hydrophilic species is present in an amount of between 0.5 and 5 atomic % of the single-wall carbon nanotubes.

11. The touchscreen of claim 1 wherein said hydrophilic species is selected from the group consisting of carboxylic acid, carboxylic acid salt mixtures thereof.

12. The touchscreen of claim 1 wherein said hydrophilic species comprises a sulfur containing group selected from:

SO x Z y

Wherein x may range from 1-3 and Z may be a Hydrogen atom or a metal cation selected from the metals Na, Mg, K, Ca, Zn, Mn, Ag, Au, Pd, Pt, Fe, Co and y may range from 0 or 1.

13. The touchscreen of claim 8 wherein said carbon nanotubes have an outer diameter of between 0.5 and 5 nanometers.

14. The touchscreen of claim 1 wherein said carbon nanotubes comprise bundles of a diameter of between 1 and 50 nanometers.

15. The touchscreen of claim 1 wherein said carbon nanotubes comprise bundles of a diameter of between 1 and 20 nanometers.

16. The touchscreen of claim 1 wherein said carbon nanotubes have a length of between 20 nanometers and 50 microns.

17. The touchscreen of claim 1 wherein said carbon nanotubes comprise bundles of a length of between 20 nanometers and 50 microns.

18. The touchscreen of claim 1 wherein said carbon nanotubes are metallic carbon nanotubes.

19. The touchscreen of claim 1 wherein said hydrophilic species comprises sulfonic acids or sulfonic acid salts or mixtures thereof.

20. The touchscreen of claim 1 wherein said carbon nanotubes are open end carbon nanotubes.

21. The touchscreen of claim 1 wherein said covalently attached hydrophilic species is present on the outside wall of said carbon nanotube.

22. The touchscreen of claim 1 wherein the electronically conductive layer comprising carbon nanotubes further comprises a binder.

23. The touchscreen of claim 1 wherein at least one of said electrodes further comprises an electronically conductive layer adjacent the substrate having a sheet resistance of between 10 and 10,000 Ohm per square.

24. The touchscreen of claim 1 wherein said electronically conductive layer comprising carbon nanotubes have a sheet resistance of between 10 2 to 10 6 Ohm per square.

25. The touchscreen of claim 1 wherein said screen is capable of greater than 500,000 single point actuations.

26. The touchscreen of claim 1 wherein said touchscreen has a visible light transparency of greater than 70 percent.

27. The touchscreen of claim 1 wherein said substrates have a visible light transparency of greater than 70 percent and comprise polyethyleneterephthalate, polyethylenenaphthalate, polycarbonate or glass.

28. The touchscreen of claim 1 wherein said touch side substrate further comprises an anti-glare coat.

29. The touchscreen of claim 1 wherein said touch side substrate further comprises an anti-reflection coat.

30. The touchscreen of claim 1 wherein said touch side substrate further comprises a hard coat having a pencil hardness greater than 2H.

31. The touchscreen of claim 1 wherein said touch side substrate further comprises a ultra violet light absorbing layer.

32. The touchscreen of claim 1 wherein the force required to actuate a point on the touchscreen does not change by more than 50 percent over 500,000 single point actuations.

33. The touchscreen of claim 1 wherein said the exposed layer comprising carbon nanotubes further comprises electrically conductive polymer, metal particles, or transparent conducting oxide particles.

34. The touchscreen of claim 1 wherein the electrode that does not comprise carbon nanotubes comprises a mixture of electrically conductive polymer, metal particles, or transparent conducting oxide particles.

35. The touchscreen of claim 1 wherein said exposed layer comprising carbon nanotubes is on the touch side of said touchscreen.

36. A device comprising a display device having attached thereto a touchscreen comprising touch side electrode and device side electrode wherein each electrode comprises an insulating substrate and an exposed electrically conductive layer, wherein said exposed electrically conductive layers are adjacent and separated by dielectric spacers, wherein only one of the exposed electrically conductive layers comprises carbon nanotubes wherein said carbon nanotubes comprise single-wall carbon nanotubes, and wherein said carbon nanotubes comprise covalently attached hydrophilic species.

37. The device of claim 36 wherein said display device comprises a LCD based display.

38. The device of claim 37 wherein said LCD comprises a polarizer plate and the touchscreen is adhesively attached to said polarizer plate.

39. The device of claim 36 wherein the exposed layer comprising carbon nanotubes is on the touch side of said touchscreen.

Assignments (9)
RELEASE OF SECURITY INTEREST Recorded Jan 24, 2020
From: BARCLAYS BANK PLC
To: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST) INC.; KODAK AMERICAS LTD.; KODAK REALTY INC.; LASER PACIFIC MEDIA CORPORATION; QUALEX INC.; KODAK PHILIPPINES LTD.; NPEC INC.
Reel/Frame 052773/0001 →
RELEASE OF SECURITY INTEREST Recorded Jul 22, 2019
From: JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
To: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC, INC.; KODAK (NEAR EAST), INC.; KODAK AMERICAS, LTD.; KODAK IMAGING NETWORK, INC.; KODAK PORTUGUESA LIMITED; KODAK REALTY, INC.; LASER PACIFIC MEDIA CORPORATION; PAKON, INC.; QUALEX, INC.; KODAK PHILIPPINES, LTD.; NPEC, INC.; CREO MANUFACTURING AMERICA LLC; KODAK AVIATION LEASING LLC
Reel/Frame 049814/0001 →
RELEASE OF SECURITY INTEREST IN PATENTS Recorded Sep 5, 2013
From: CITICORP NORTH AMERICA, INC., AS SENIOR DIP AGENT; WILMINGTON TRUST, NATIONAL ASSOCIATION, AS JUNIOR DIP AGENT
To: EASTMAN KODAK COMPANY; PAKON, INC.
Reel/Frame 031157/0451 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (FIRST LIEN) Recorded Sep 5, 2013
From: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST), INC.; KODAK IMAGING NETWORK, INC.; KODAK PORTUGUESA LIMITED; KODAK REALTY, INC.; LASER-PACIFIC MEDIA CORPORATION; PAKON, INC.; QUALEX INC.; KODAK PHILIPPINES, LTD.; NPEC INC.; CREO MANUFACTURING AMERICA LLC; KODAK AVIATION LEASING LLC; KODAK AMERICAS, LTD.
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE
Reel/Frame 031158/0001 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (ABL) Recorded Sep 5, 2013
From: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST), INC.; KODAK AMERICAS, LTD.; KODAK IMAGING NETWORK, INC.; KODAK PORTUGUESA LIMITED; KODAK REALTY, INC.; LASER-PACIFIC MEDIA CORPORATION; PAKON, INC.; QUALEX INC.; KODAK PHILIPPINES, LTD.; NPEC INC.; CREO MANUFACTURING AMERICA LLC; KODAK AVIATION LEASING LLC
To: BANK OF AMERICA N.A., AS AGENT
Reel/Frame 031162/0117 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (SECOND LIEN) Recorded Sep 5, 2013
From: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST), INC.; KODAK AMERICAS, LTD.; KODAK IMAGING NETWORK, INC.; KODAK PORTUGUESA LIMITED; KODAK REALTY, INC.; LASER-PACIFIC MEDIA CORPORATION; PAKON, INC.; QUALEX INC.; KODAK PHILIPPINES, LTD.; NPEC INC.; CREO MANUFACTURING AMERICA LLC; KODAK AVIATION LEASING LLC
To: BARCLAYS BANK PLC, AS ADMINISTRATIVE AGENT
Reel/Frame 031159/0001 →
PATENT SECURITY AGREEMENT Recorded Apr 1, 2013
From: EASTMAN KODAK COMPANY; PAKON, INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS AGENT
Reel/Frame 030122/0235 →
SECURITY INTEREST Recorded Feb 21, 2012
From: EASTMAN KODAK COMPANY; PAKON, INC.
To: CITICORP NORTH AMERICA, INC., AS AGENT
Reel/Frame 028201/0420 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 2, 2005
From: SPATH, TODD M.; IRVIN, GLEN C., JR.; MAJUMDAR, DEBASIS; ANDERSON, CHARLES C.
To: EASTMAN KODAK COMPANY
Reel/Frame 016656/0903 →
Continuity (1)
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