IP Library Granted Patent US 7,442,598
Granted Patent B2
US 7,442,598 · App. 11/148,455 · Granted Oct 28, 2008

Method of forming an interlayer dielectric

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 7,442,598
App. No.
11/148,455
Granted
Oct 28, 2008
Kind
B2
Abstract

A method for forming a semiconductor device comprises providing a semiconductor substrate; forming a first stressor layer over a surface of the semiconductor substrate; selectively removing portions of the first stressor layer; forming a second stressor layer over the surface of the semiconductor substrate and the first stressor layer; and selectively removing portions of the second stressor layer using an isotropic etch. In one embodiment, the isotropic etch is a wet etch that selectively removes the second stressor layer without removing a significant amount of the first stressor layer and also planarizing a boundary between the first stressor layer and the second stressor layer.

Claims (39)

1. A method for forming a semiconductor device comprising:

providing a semiconductor substrate;

forming a first stressor layer of silicon-lean silicon nitride over a surface of the semiconductor substrate, wherein the first stressor has compressive stress;

selectively removing portions of the first stressor layer to leave a remaining portion;

forming a second stressor layer of silicon-lean silicon nitride over the surface of the semiconductor substrate and the remaining portion of the first stressor layer, wherein the second stressor layer has tensile stress;

forming a photoresist layer over the second stressor layer;

patterning the photoresist layer to leave a portion of the photoresist layer that overlaps the remaining portion of the first stressor layer and exposes a first portion of the second stressor layer; and

applying a wet chemistry comprising hydrofluoric acid to the portion of the photoresist layer and the first portion of the second stressor layer, wherein wet chemistry comprising hydrofluoric acid is characterized by etching the second stressor layer at a greater rate than the first stressor layer.

2. The method of claim 1 , wherein the step of applying is further characterized by the greater rate being about 12 to 1.

3. The method of claim 1 , wherein the step of applying is further characterized by continuing after the first portion of the second stressor layer has been removed until all of the second stressor layer that is over the remaining portion of the first stressor layer is removed.

4. The method of claim 1 , wherein the semiconductor substrate is characterized as being a silicon-on-insulator (SOI) substrate.

5. The method of claim 1 , wherein the first and second stressor layers are both formed using plasma enhanced chemical vapor deposition (PECVD).

6. A method for forming a semiconductor device comprising:

providing a semiconductor substrate;

forming a first plurality of transistors on a first portion of the semiconductor substrate;

forming a second plurality of transistors on a second portion of the semiconductor substrate;

forming a first stressor layer of silicon-lean silicon nitride over the first and second pluralities of transistors having compressive stress;

selectively removing the first stressor layer from over the first plurality of transistors to leave a remaining portion of the first stressor layer;

forming a second stressor layer of silicon-lean silicon nitride over remaining portion of the first stressor layer and the first and second pluralities of transistors, wherein the second stressor layer has tensile stress;

forming a photoresist layer over the second stressor layer;

patterning the photoresist layer to leave a portion of the photoresist layer that overlaps the remaining portion of the first stressor layer and exposes a first portion of the second stressor layer; and applying a wet chemistry comprising hydrofluoric acid to the portion of the of the photoresist layer and the first portion of the second stressor layer, wherein wet chemistry comprising hydrofluoric acid is characterized by etching the second stressor layer at a greater rate than the first stressor layer.

7. The method of claim 6 , wherein channel regions of the first and second pluralities of transistors are oriented in a direction in a semiconductor wafer.

8. The method of claim 6 , wherein the first plurality of transistors has an N conductivity type and the second plurality of transistors has a P conductivity type.

9. The method of claim 6 , wherein the step of applying is further characterized by the greater rate being about 12 to 1.

10. The method of claim 6 , wherein portions of the second stressor layer further comprises selectively removing the step of applying is further characterized by continuing after the first portion of the second stressor layer has been removed until all of the second stressor layer that is over the remaining portion of the first stressor layer is removed.

11. The method of claim 6 , further comprising forming an electrical contact with at least one transistor of the first or second pluralities of transistors at a boundary between the first stressor layer and the second stressor layer.

12. The method of claim 6 , wherein forming the first and second stressor layers comprises forming the first and second stressor layers to be between about 30 and 100 nanometers thick.

13. A method for forming a semiconductor device comprising:

providing a semiconductor substrate;

forming a plurality of N-channel transistors on a first portion of the semiconductor substrate;

forming a plurality of P-channel transistors on a second portion of the semiconductor substrate, wherein the second portion is adjacent to the first portion;

forming a compressive stressor layer of silicon-lean silicon nitride over the plurality of N-channel transistors and over the plurality of P-channel transistors;

selectively removing the compressive stressor layer from over the plurality N-channel of transistors to leave a remaining portion of the compressive stressor layer;

forming a tensile stressor layer of silicon-lean silicon nitride over the remaining portion of the compressive stressor layer and the plurality of P-channel transistors; and

forming a photoresist layer over the compressive stressor layer;

patterning the photoresist layer to leave a portion of the photoresist layer that overlaps the remaining portion of the compressive stressor layer and exposes a first portion of the tensile stressor layer; and

applying a wet chemistry comprising hydrofluoric acid to the portion of the of the photoresist layer and the first portion of the second stressor layer, wherein wet chemistry comprising hydrofluoric acid is characterized by etching the second stressor layer at a greater rate than the first stressor layer.

14. The method of claim 13 , wherein the first portion is isolated from the second portion using shallow trench isolation, and wherein an electrical contact to at least one transistor of the plurality of N-channel transistors or the plurality of P-channel transistors is formed at a boundary between the first and second portions.

15. The method of claim 13 wherein the compressive stressor layer and the tensile stressor layer are both formed using plasma enhanced chemical vapor deposition (PECVD).

Assignments (22)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 037486 FRAME 0517. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Dec 10, 2019
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 053547/0421 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TO CORRECT THE APPLICATION NO. FROM 13,883,290 TO 13,833,290 PREVIOUSLY RECORDED ON REEL 041703 FRAME 0536. ASSIGNOR(S) HEREBY CONFIRMS THE THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS.. Recorded Feb 20, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: SHENZHEN XINGUODU TECHNOLOGY CO., LTD.
Reel/Frame 048734/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENTS 8108266 AND 8062324 AND REPLACE THEM WITH 6108266 AND 8060324 PREVIOUSLY RECORDED ON REEL 037518 FRAME 0292. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Feb 1, 2017
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 041703/0536 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 040925/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 4, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: NORTH STAR INNOVATIONS INC.
Reel/Frame 037694/0264 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 13, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037518/0292 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 12, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037486/0517 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037354/0225 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037354/0807 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037356/0143 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037356/0553 →
SECURITY AGREEMENT Recorded Nov 6, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 031591/0266 →
SECURITY AGREEMENT Recorded Jun 18, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 030633/0424 →
SECURITY AGREEMENT Recorded May 13, 2010
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 024397/0001 →
SECURITY AGREEMENT Recorded Mar 12, 2009
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A.
Reel/Frame 022380/0409 →
SECURITY AGREEMENT Recorded Feb 2, 2007
From: FREESCALE SEMICONDUCTOR, INC.; FREESCALE ACQUISITION CORPORATION; FREESCALE ACQUISITION HOLDINGS CORP.; FREESCALE HOLDINGS (BERMUDA) III, LTD.
To: CITIBANK, N.A. AS COLLATERAL AGENT
Reel/Frame 018855/0129 →
RECORD TO CORRECT 3RD ASSIGNEE'S NAME ON ASSIGNMENT DOCUMENTS PREVIOUSLY RECORDED ON REEL 016679, FRAME 0306 Recorded May 15, 2006
From: GRUDOWSKI, PAUL A.; FILIPIAK, STANLEY M.; JEON, YONGJOO; WEINTRAUB, CHAD E.
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 017627/0360 →
CORRECTED COVER SHEET TO CORRECT THE 3RD ASSIGNEE'S NAME, PREVIOUSLY RECORDED AT REEL/FRAME 016679/0306 (ASSIGNMENT OF ASSIGNOR'S INTEREST) Recorded May 15, 2006
From: GRUDOWSKI, PAUL A.; FILIPIAK, STANLEY M.; JEON, YONGJOO; WEINTRAUB, CHAD E.
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 017633/0225 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 9, 2005
From: GRUDOWSKI, PAUL A.; FILIPIAK, STANLEY M.; JEON, YONGLOO; WEINTRAUB, CHAD E.
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 016679/0306 →