Thermally conductive polymer compositions having moderate tensile and flexural properties
View Patent ↗A thermally conductive polymer composition having enhanced mechanical properties is provided. The polymer composition consists of a base polymer matrix loaded with fillers that results in a thermal conductivity that is greater than 1.5 W/m° K and a tensile modulus within an acceptable range making the composition suitable for structural plastic applications, such as between 1,700 to 12,000 Mpa and more preferably between approximately 2,700 to 10,000 Mpa and even more preferably in the range of between approximately 4,000 to 9,000 Mpa. In addition to a tensile modulus within the identified range the composition also includes an elongation to break value that is at least above 1.0% and more preferably in the range of about 1.2% to 10%.
1. A thermally conductive polymer composition having reduced brittleness comprising:
about 40% to about 70% base thermoplastic elastomer matrix having a tensile modulus in the range of between 30 Mpa and 1200 Mpa; and
about 30% to about 60% thermally conductive filler uniformly dispersed throughout said base matrix,
wherein said thermally conductive polymer composition has a thermal conductivity of as least 1.5 w/m° K, and is a structural composition having a tensile modulus of between 4,000 Mpa and 9,000 Mpa and an elongation to break that is between 1.2% and 10%.
2. The thermally conductive polymer composition of claim 1 , wherein said thermoplastic elastomer is selected from the group consisting of: polyether esters and polyether amides.
3. The thermally conductive polymer composition of claim 1 , wherein said thermoplastic elastomer is selected from the group consisting of: thermoplastic olefin elastomers (TPO), styrenic elastomers, polyurethane elastomers, fluoropolymers, polyester elastomers and thermoplastic vulcanizates (TPVs).
4. A thermally conductive polymer composition having reduced brittleness comprising:
about 40% to about 70% base thermoplastic co-poylmer including a thermoplastic elastomer and a thermoplastic;
about 30% to about 60% thermally conductive filler uniformly dispersed throughout said base matrix,
wherein said thermally conductive polymer composition has a thermal conductivity of as least 1.5 w/m° K, and is a structural composition having a tensile modulus of between 4,000 Mpa and 9,000 Mpa and an elongation to break that is between 1.2% and 10%.
5. The thermally conductive polymer composition of claim 4 , wherein said thermoplastic co-polymer is selected from the group consisting of: polybutyleneterephthalate in combination with polyether ester elastomer, polyamide in combination with polyether amide elastomer and polypropylene in combination with thermoplastic olefinic elastomer.
6. A method of forming a thermally conductive polymer composition having reduced brittleness comprising the steps of:
providing about 40% to about 70% base matrix of thermoplastic co-poylmer including a thermoplastic elastomer and a thermoplastic polymer having a tensile modulus in the range of between 30 Mpa and 1200 Mpa;
providing about 30% to about 60% thermally conductive filler; and
mixing said thermally conductive filler uniformly throughout said base matrix, wherein said thermally conductive polymer composition has a thermal conductivity of as least 1.5 w/m° K, a tensile modulus of between 4,000 Mpa and 9,000 Mpa and an elongation to break that is between 1.0% and 10%.
7. The method of forming a thermally conductive polymer composition of claim 6 , wherein said thermoplastic co-polymer is selected from the group consisting of: polybutyleneterephthalate in combination with polyether ester elastomer, polyamide in combination with polyether amide elastomer and polypropylene in combination with thermoplastic olefinic elastomer.