Coated steel bipolar plates
View Patent ↗In accordance with one embodiment of the present invention, an electrochemical conversion assembly comprises a plurality of electrochemical conversion cells and a plurality of electrically conductive bipolar plates. The electrochemical conversion cells are configured to communicate with first and second reactant supplies. Adjacent ones of the electrochemical conversion cells are separated by respective ones of the plurality of bipolar plates. The bipolar plates comprise an alloy comprising Fe and Cr. Respective surface portions of the bipolar plates are provided with electrically conductive, corrosion resistant layers that are placed in contact with portions of the electrochemical conversion cells. The corrosion resistant electrically conductive layers may comprise graphitic layers characterized predominantly by sp2 hybridized carbon-carbon bonding, molybdenum doped indium oxide layers, an electrically conductive Cr+N layer, or an electrically conductive MoSi 2 layer.
1. A device comprising an electrochemical conversion assembly, said electrochemical conversion assembly comprising a plurality of electrochemical conversion cells and a plurality of electrically conductive bipolar plates, wherein:
said electrochemical conversion cells are configured to communicate with first and second reactant supplies;
adjacent ones of said electrochemical conversion cells are separated by respective ones of said plurality of bipolar plates;
said bipolar plates comprise an alloy comprising Fe and Cr;
respective surface portions of said bipolar plates comprise graphitic layers characterized predominantly by sp 2 hybridized carbon-carbon bonding, wherein a thickness of said graphitic layers is less than about 10 μm;
an underlayer formed on said bi-polar plate alloy between said bi-polar plate alloy and said graphitic layers, said underlayer comprising a metal and carbon, wherein a thickness of said underlayer is between 50 and 200 nm; and
respective graphite layers of said bipolar plates are in contact with portions of said electrochemical conversion cells.
2. A device as claimed in claim 1 wherein said graphitic layers are characterized substantially entirely by sp 2 hybridized carbon-carbon bonding.
3. A device as claimed in claim 1 wherein said graphitic layers are characterized by an interfacial contact resistance less than about 10 mΩ-cm 2 under compression of at least about 100 psi (690 kPa).
4. A device as claimed in claim 1 wherein said graphitic layers are defined on opposite sides of a selected bipolar plate so as to contact one of a pair of electrochemical conversion cells separated by said selected bipolar plate.
5. A device as claimed in claim 1 wherein respective ones of said graphitic layers define a plurality of component graphitic layers collectively defining a single graphitic layer.
6. A device as claimed in claim 1 wherein said graphitic layers define between about 0.1% and about 10.0% of a thickness of respective ones of said bipolar plates.
7. A device as claimed in claim 1 wherein said alloy further comprises Ni, Mo, Mn, Si, C, N and combinations thereof.
8. A device as claimed in claim 1 wherein said alloy comprises Fe, Cr, Ni, Mn, Si, and C.
9. A device as claimed in claim 1 wherein said alloy comprises an austenitic stainless steel.
10. A device as claimed in claim 1 wherein said first reactant supply comprises a source of hydrogenous gas and said second reactant supply comprises a source of air.
11. A device as claimed in claim 1 wherein said bipolar plates comprise a flowfield defined between opposite, electrically conductive sides of said bipolar plate.
12. A device as claimed in claim 1 wherein said electrochemical conversion cells comprise respective membrane electrode assemblies.
13. A device as claimed in claim 1 wherein said electrochemical conversion cells comprise respective electrolytic membranes, gaseous diffusion layers, catalytic components, carbonaceous components, electrically conductive components, and combinations thereof.
14. A device as claimed in claim 1 wherein said device further comprises a fuel processing system or fuel source for providing a hydrogenous gas to said electrochemical conversion assembly.
15. A device as claimed in claim 1 wherein:
said device further comprises a vehicle; and
said electrochemical conversion assembly is configured to at least partially provide said vehicle with motive power.