High-weatherability iron nitride-based magnetic powder and method of manufacturing the powder
View Patent ↗A high-reliability iron nitride-based magnetic powder with markedly improved weatherability with respect to deterioration over time of the magnetic properties in fine particles smaller than 25 nm is formed by adhering one or more of the elements Si and P to the surface of an iron nitride-based magnetic powder constituted primarily of Fe 16 N 2 with an average grain size of 25 nm or less, where the total content of Si and P in the magnetic powder may be 0.1% or greater as an atomic ratio with respect to Fe. In particular, the invention provides an iron nitride-based magnetic powder such that the value ΔH c as defined by Equation (1) below is 5% or less and the value Δσ s as defined by Equation (2) below is 20% or less. Δ H c =( H c0 −H c1 )/ H c0 100 (1) Δσ s =(σ s0 −σ s1 )/σ s0 100 (2) Here, H c1 and σ s1 are the coercivity and saturation magnetization, respectively, of the magnetic powder after being kept for one week at a constant temperature and constant humidity of 60° C. and 90% RH. H c0 and σ s0 are the coercivity and saturation magnetization of the magnetic powder before being kept at constant temperature and constant humidity.
1. A high-weatherability iron nitride-based magnetic powder comprising iron nitride-based magnetic particles constituted primarily of Fe 16 N 2 with an average grain size of 20 nm or less, wherein a substance containing one or more of the elements Si and P are adhered to the surface of the Fe 16 N 2 particles after the particles have been formed, the total content of Si and P in the magnetic powder after adhesion is 0.1% or greater as an atomic ratio with respect to Fe, and
the value ΔH c as defined by Equation (1) below is 5% or less:
Δ H c =( H c0 —H c1 )/ H c0 ×100 (1)
where,
H c0 is the coercivity (kA/m) of the iron nitride-based magnetic powder after adhesion, and
H c1 is the coercivity (kA/m) of the iron nitride-based magnetic powder after adhesion and after being kept for one week in a constant-temperature, constant-humidity vessel at 60° C. and 90% RH.
2. The high-weatherability iron nitride-based magnetic powder according to claim 1 , wherein the value Δσ s as defined by Equation (2) below is 20% or less:
Δσ s =(σ s0 −σ s1 )σ s0 ×100 (2)
where, σ s0 is the saturation magnetization (Am 2 /kg) of the iron nitride-based magnetic powder after adhesion, and σ s1 is the saturation magnetization (Am 2 /kg) of the iron nitride-based magnetic powder after adhesion and after being kept for one week in a constant-temperature, constant-humidity vessel at 60° C. and 90% RH.
3. A method of manufacturing a high-weatherability iron nitride-based magnetic powder comprising a step of taking an iron nitride-based magnetic powder constituted primarily of Fe 16 N 2 with an average grain size of 20 nm or less and adhering one or more of the elements Si and P to the surface of the powder such that the total content of Si and P in the magnetic powder after adhesion is 0.1% or greater as an atomic ratio with respect to Fe, wherein the adhering step further comprises dispersing the iron nitride-based magnetic nowder in water, and adding to the dispersion one or more of a Si-containing substance and a P-containing substance so that one or more of the elements Si and P adhere to the surface of the powder, wherein a pH adjusting agent is added either to the water prior to the adding step, is added to the dispersion after the adding step, or is added to the dispersion with the one or more of the Si-containing substance and the P-containing substance, and further drying the particles obtained at a temperature less than 80° C.
4. A method of manufacturing a high-weatherability iron nitride-based magnetic powder according to claim 3 , wherein a step of heat treating the powder obtained in the adhering step at 80-200° C. in an inert-gas atmosphere follows the drying step.