Nonmagnetic powder comprising acicular iron and having specific porosity for a magnetic recording medium, method of manufacturing same, and magnetic recording medium using same
View Patent ↗A nonmagnetic powder, used for the nonmagnetic layer of a coated type magnetic recording medium having a multilayer structure, has good dispersibility in the binder in which it is dispersed to prepare a coating material that is applied to the nonmagnetic layer. The nonmagnetic powder has an iron compound as its principal component and exhibits a maximum pore volume value in a pore diameter range of 0.01 μm to 0.05 μm within a pore diameter range of 0.0018 μm to 0.1 μm in which the relationship between pore diameter and pore volume is calculated by a mercury injection method. The nonmagnetic powder exhibits a cumulative pore volume value in a pore diameter range of 0.0018 μm to 0.01 μm that is not more than 30% of the cumulative pore volume value in the pore diameter range of 0.0018 μm to 0.1 μm.
1. Nonmagnetic powder for a magnetic recording medium that has an acicular iron compound as its principal component and exhibits a maximum pore volume value within a pore diameter range of 0.01 μm to 0.05 μm, with respect to a pore diameter within the range 0.0018 μm to 0.1 μm, in which the relationship between pore diameter and pore volume is calculated by a mercury injection method.
2. The nonmagnetic powder according to claim 1 which exhibits a cumulative pore volume value in a pore diameter range of 0.0018 μm to 0.01 μm that is not more than 30% of the cumulative pore volume value in the pore diameter range of 0.0018 μm to 0.1 μm.
3. The nonmagnetic powder according to claim 1 , in which the powder contains 0.1 to 5 wt % P.
4. The nonmagnetic powder according to claim 1 , in which the powder contains a total of 0.1 to 10 wt % of at least one of Al and Si.
5. The nonmagnetic powder according to claim 1 , in which the powder contains 0.1 to 10 wt % of rare earth elements including Y.
6. A magnetic recording medium comprising the nonmagnetic powder of claim 1 .
7. A method of manufacturing the nonmagnetic powder of claim 1 , comprising baking iron oxy hydroxide in an atmosphere and introducing steam into the baking atmosphere wherein during a step of elevating the temperature to bake the iron oxy hydroxide and transform it to the acicular iron compound, the temperature is elevated at a rate of at least 50° C./min.
8. The method of claim 7 , wherein the baking and transforming steps produce α-ferric oxide.