High power output non-aqueous electrolyte secondary battery
View Patent ↗In a high power output non-aqueous electrolyte secondary battery including a negative electrode including a graphitizable carbon material, the physical properties of the graphitizable carbon material is controlled. In a X-ray diffraction pattern of the graphitizable carbon material, a ratio of a peak intensity I(101) attributed to a (101) plane to a peak intensity I(100) attributed to a (100) plane satisfies 0<I(101)/I(100)<1.0. A ratio of a peak intensity I(110) attributed to a (110) plane to a peak intensity I(004) attributed to a (004) plane satisfies 0.7≦I(110)/I(004) ≦1.4. The graphitizable carbon material preferably has a specific surface area measured by BET method of 1 to 5 m 2 /g.
1. A high power output non-aqueous electrolyte secondary battery comprising: a positive electrode including a lithium-containing composite oxide; a negative electrode including a carbon material capable of absorbing and desorbing lithium ions; and a non-aqueous electrolyte,
wherein said carbon material comprises a graphitizable carbon material, and
said graphitizable carbon material has an average particle size of 5 μm to 15 μm, and
wherein in a diffraction pattern of said graphitizable carbon material measured by wide-angle powder X-ray diffractometry, a ratio: I(101)/I(100) of a peak intensity I(101) attributed to a (101) plane to a peak intensity I(100) attributed to a (100) plane satisfies 0<I(101)/I(100)<1.0, and
a ratio: I(110)/I(004) of a peak intensity I(110) attributed to a (110) plane to a peak intensity I(004) attributed to a (004) plane satisfies
0.7≦ I (110)/ I (004)≦1.4.
2. The high power output non-aqueous electrolyte secondary battery in accordance with claim 1 ,
wherein said negative electrode in a fully charged state has a capacity density of not less than 170 Ah/kg and not greater than 250 Ah/kg.
3. The high power output non-aqueous electrolyte secondary battery in accordance with claim 1 ,
wherein said graphitizable carbon material has a specific surface area measured by BET method of not less than 1 m 2 /g and not greater than 5 m 2 /g.