BATTERY
A battery capable of improving the energy density and improving the cycle characteristics is provided. The battery includes a spirally wound electrode body, in which a cathode and an anode are wound with a separator and an electrolyte in between. The open circuit voltage in full charge is in the range from 4.25 V to 6.00 V. The electrolyte contains an electrolytic solution and a polymer containing vinylidene fluoride as a component. The polymer containing vinylidene fluoride as a component has high oxidation stability. Therefore, even when the battery voltage is raised, oxidation and decomposition of the electrolyte and the separator can be inhibited.
1 . A battery in which a cathode and an anode are oppositely arranged with an electrolyte in between,
wherein an open circuit voltage in a full charge state per a pair of the cathode and the anode is in the range from 4.25 V to 6.00 V, and
the electrolyte contains an electrolytic solution and a polymer containing vinylidene fluoride as a component.
2 . The battery according to claim 1 , wherein the polymer contains a copolymer containing vinylidene fluoride and hexafluoropropylene as a component.
3 . The battery according to claim 2 , wherein the copolymerization amount of hexafluoropropylene in the copolymer is 7 wt % or less.
4 . The battery according to claim 1 , wherein the cathode contains at least one from the group consisting of lithium complex oxides shown in Chemical formula 1, Chemical formula 2, or Chemical formula 3.
Li f Mn (1-g-h) Ni g M1 h O (2-j) F k (Chemical formula 1)
wherein M1 represents at least one from the group consisting of cobalt (Co), magnesium (Mg), aluminum (Al), boron (B), titanium (Ti), vanadium (V), chromium (Cr), iron (Fe), copper (Cu), zinc (Zn), zirconium (Zr), molybdenum (Mo), tin (Sn), calcium (Ca), strontium (Sr), and tungsten (W); and f, g, h, j, and k are values in the range of 0.8≦f≦1.2, 0≦g≦0.5, 0≦h≦0.5, g+h<1, −0.1≦j≦0.2, and 0≦k≦0.1.
Li m Ni (1-n) M2 n O (2-p) F q (Chemical formula 2)
wherein M2 represents at least one from the group consisting of cobalt, manganese, magnesium, aluminum, boron, titanium, vanadium, chromium, iron, copper, zinc, molybdenum, tin, calcium, strontium, and tungsten; and m, n, p, and q are values in the range of 0.8≦m≦1.2, 0.005≦n≦0.5, −0.1≦p≦0.2, and 0≦q≦0.1.
Li r Co (1-s) M3 s O (2-t) F u (Chemical formula 3)
wherein M3 represents at least one from the group consisting of nickel, manganese, magnesium, aluminum, boron, titanium, vanadium, chromium, iron, copper, zinc, molybdenum, tin, calcium, strontium, and tungsten; and r, s, t, and u are values in the range of 0.8≦r≦1.2, 0≦s<0.5, −0.1≦t≦0.2, and 0≦u≦0.1.