IP Library Granted Patent US 7,294,908
Granted Patent B2
US 7,294,908 · App. 11/292,764 · Granted Nov 13, 2007

Method of forming a gate pattern in a semiconductor device

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Quick Facts
Patent No.
US 7,294,908
App. No.
11/292,764
Granted
Nov 13, 2007
Kind
B2
Abstract

A gate pattern having a critical dimension after an etching process of 60-70nm may be formed using an ArF photoresist as an etching mask by a method including sequentially forming a gate oxide layer, a gate electrode layer, an anti-reflection coating layer, and an ArF photoresist layer on a semiconductor wafer; forming a photoresist pattern by exposing and developing the ArF photoresist layer; etching the anti-reflection coating layer using the photoresist pattern as an etching mask; removing an oxide layer formed during etching of the anti-reflection coating layer; etching the gate electrode layer; and over-etching a remaining gate electrode layer.

Claims (33)

1. A gate pattern in a semiconductor device, comprising:

a semiconductor wafer;

a gate oxide layer on the semiconductor wafer;

an overetched gate electrode pattern on the gate oxide layer;

an anti-reflection coating pattern on the gate electrode layer; and

an ArF photoresist pattern on the anti-reflection coating pattern, coextensive with the anti-reflection coating pattern.

2. The gate pattern of claim 1 , wherein the gate pattern has a critical dimension of 60-70 nm.

3. The gate pattern of claim 2 , wherein the photoresist pattern has a critical dimension of 100-110 nm.

4. The gate pattern of claim 1 , wherein the gate oxide layer has a thickness of 10-20 Å, the gate electrode pattern has a thickness of 1500-1800 Å, the anti-reflection coating pattern has a thickness of 300-400 Å, and the ArF photoresist pattern has a thickness of 2000-2700 Å.

5. A method of forming a gate pattern in a semiconductor device, comprising:

sequentially forming a gate oxide layer, a gate electrode layer, an anti-reflection coating layer, and an ArF photoresist layer on a semiconductor wafer;

forming a photoresist pattern by exposing and developing the ArF photoresist layer;

etching the anti-reflection coating layer using the photoresist pattern as an etching mask;

removing an oxide layer formed during etching of the anti-reflection coating layer;

etching the gate electrode layer; and

over-etching a remaining gate electrode layer.

6. The method of claim 5 , wherein a critical dimension of the photoresist pattern before etching is 100-110 nm.

7. The method of claim 5 , wherein etching the anti-reflection coating layer, removing the oxide layer, etching the gate electrode layer, and over-etching a remaining gate electrode layer each comprise etching with an inductively coupled plasma (ICP).

8. The method of claim 5 , wherein the gate oxide layer has a thickness of 10-20 Å.

9. The method of claim 5 , wherein the gate electrode layer has a thickness of 1500-1800 Å.

10. The method of claim 5 , wherein the anti-reflection coating layer has a thickness of 300-400 Å.

11. The method of claim 5 , wherein the ArF photoresist layer has a thickness of 2000-2700 Å.

12. The method of claim 5 , wherein the gate oxide layer has a thickness of 10-20 Å, the gate electrode layer has a thickness of 1500-1800 Å, the anti-reflection coating layer has a thickness of 300-400 Å, and the ArF photoresist layer has a thickness of 2000-2700 Å.

13. The method of claim 7 , wherein etching the anti-reflection coating layer further comprises flowing an etching gas comprising a fluorocarbon and an oxygen source at a rate of 80-130 sccm, and maintaining a chamber pressure of 0.5-25 mTorr, a source power of 100-1000 W, and a bias power of 5-100 W; and the method further comprises:

detecting an end-point of etching the anti-reflection coating layer; and

over-etching the remaining anti-reflection coating layer.

14. The method of claim 7 , wherein etching the anti-reflection coating layer further comprises flowing an etching gas comprising CF 4 and O 2 at a rate of from 80 to 130 sccm, maintaining a pressure of an etching chamber at a level of 1-10 mTorr, maintaining a source power at 200-500 W, and maintaining a bias power at 10-70 W, and the method further comprises an additional over-etching process, performed after detecting an end-point of the etching.

15. The method of claim 7 , wherein removing the oxide layer further comprises etching with a gas comprising a fluorocarbon having a flow rate of 20-100 sccm, for a time of 2-20 sec, and at a pressure of 0.5-10 mTorr, a source power of 100-1000 W, and a bias power of 10-100 W.

16. The method of claim 7 , wherein removing the oxide layer comprises etching with a gas comprising CF 4 flowed at a rate of 40-60 sccm, for a process time of 5-10 sec, a pressure of 1-7 mTorr, a source power of 300-700 W, and a bias power of 20-70 W.

17. The method of claim 7 , wherein etching the gate electrode layer comprises etching with a gas comprising a chlorine source, a hydrogen halide and (optionally) an oxygen source having a total flow rate of 100-250 sccm, for a time of 10-100 sec, and at a chamber pressure of 0.5-10 mTorr, a source power of 200-1000 W, and a bias power of 20-200 W.

18. The method of claim 7 , wherein etching the gate electrode layer comprises etching with a gas comprising Cl 2 flowed at a rate of 10-50 sccm, HBr flowed at a rate of 100-180 sccm, and O 2 flowed at a rate of 0-5 sccm, for a process time of 30-50 sec, and at a chamber pressure of 1-7 mTorr, a source power of 300-800 W, and a bias power of 50-100 W.

19. The method of claim 7 , wherein over-etching the remaining gate electrode layer comprises etching with a gas comprising a nitrogen source, a hydrogen halide and an oxygen source having a flow rate of 100-250 sccm, for a time of 60-240 sec, and at a pressure of 10-150 mTorr, a source power of 500-2500 W, and a bias power of 20-500 W.

20. The method of claim 7 , wherein over-etching the remaining gate electrode layer comprises etching with a gas comprising N 2 flowed at a rate of 5-15 sccm, HBr flowed at a rate of 130-170 sccm, and O 2 flowed at a rate of 1-5 sccm, for a process time of 100-140 sec, and at an etching chamber pressure of 50-100 mTorr, a source power of 700-1500 W, and a bias power of 50-200 W.

Assignments (3)
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNOR PREVIOUSLY RECORDED ON REEL 017749 FRAME 0335. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNOR SHOULD BE "DONGBUANAM SEMICONDUCTOR INC.". Recorded Jun 21, 2006
From: DONGBUANAM SEMICONDUCTOR INC.
To: DONGBU ELECTRONICS CO., LTD.
Reel/Frame 017821/0670 →
CHANGE OF NAME Recorded Jun 8, 2006
From: DONGANAM SEMICONDUCTOR INC.
To: DONGBU ELECTRONICS CO., LTD.
Reel/Frame 017749/0335 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 2, 2005
From: JANG, JEONG-YEL; KWAK, SUNG-HO
To: DONGBUANAM SEMICONDUCTOR INC.
Reel/Frame 017328/0985 →