Polyolefin-based thermoplastic polymer composition
Disclosed herein is a polyolefin-based thermoplastic polymer composition, in which an acrylate copolymer phase obtained by absorbing an alkyl acrylate monomer, an alkyl methacrylate monomer, a polar group-containing acrylate monomer and a polymerization initiator into a polyolefin matrix and then polymerizing the monomers is dispersed in a polyolefin phase. The thermoplastic polymer composition has excellent surface polarity leading to excellent paint adhesion.
1. A polyolefin-based thermoplastic polymer composition comprising
an acrylate copolymer phase comprising an acrylate copolymer of an alkyl acrylate monomer, an alkyl methacrylate monomer, and a polar group-containing acrylate monomer; and
a polyolefin phase comprising a blend of a polyolefin and at least one polyethylene copolymer,
wherein the acrylate copolymer phase is dispersed in the polyolefin phase,
wherein the polyethylene copolymer comprises at least one selected from the group consisting of poly(ethylene-co-methylacrylate), poly(ethylene-co-ethylacrylate), poly(ethylene-co-butylacrylate), poly(ethylene-co-acrylic acid), poly(ethylene-co-methacrylic acid), poly(ethylene-co-glycidyl methacrylate), poly(ethylene-co-maleic acid), poly(ethylene-co-vinyl acetate), poly(ethylene-co-acrylamide), and poly(ethylene-co-acrylonitrile); and
wherein the amount of the alkyl acrylate monomer is 65-455 parts by weight based on 100 parts by weight of the polyolefin phase, the amount of the alkyl methacrylate monomer is 15-240 parts by weight based on 100 parts by weight of the polyolefin phase, and the amount of the polar group-containing acrylate monomer is 15-300 parts by weight based on 100 parts by weight of the polyolefin phase.
2. The thermoplastic polymer composition of claim 1 , wherein the amount of the acrylate copolymer phase is 95-995 parts by weight based on 100 parts by weight of the polyolefin phase.
3. The thermoplastic polymer composition of claim 1 , wherein the acrylate copolymer phase is obtained by the steps comprising:
absorbing an alkyl acrylate monomer, an alkyl methacrylate monomer, a polar group-containing acrylate monomer, and a polymerization initiator into a polyolefin matrix; and
polymerizing the monomers.
4. The thermoplastic polymer composition of claim 3 , wherein the amount of the alkyl acrylate monomer used in the polymerization is 90-350 parts by weight based on 100 parts by weight of the polyolefin phase.
5. The thermoplastic polymer composition of claim 3 , wherein the amount of the alkyl methacrylate monomer used in the polymerization is 45-150 parts by weight based on 100 parts by weight of the polyolefin phase.
6. The thermoplastic polymer composition of claim 3 , wherein the amount of the polar group-containing acrylate monomer used in the polymerization is 50-180 parts by weight based on 100 parts by weight of the polyolefin phase.
7. The thermoplastic polymer composition of claim 3 , wherein the amount of the polymerization initiator used in the polymerization is 0.5-2.0 mole % based on the sum of the mole of the monomers and the mole of the polymerization initiator.
8. The thermoplastic polymer composition of claim 3 , wherein the polyolefin matrix is prepared by the steps comprising:
absorbing an alkyl acrylate monomer and a polymerization initiator into a blend of a polyolefin and at least one polyethylene copolymer; and
polymerizing the monomer.
9. The thermoplastic polymer composition of claim 1 , further comprising a polymer of an alkyl acrylate monomer, wherein the polymer of an alkyl acrylate monomer is dispersed in the polyolefin phase.
10. The thermoplastic polymer composition of claim 1 , wherein the polyolefin included in the blend is a polypropylene.
11. The thermoplastic polymer composition of claim 1 , wherein the alkyl acrylate monomer is a methyl acrylate, an ethyl acrylate or a butyl acrylate.
12. The thermoplastic polymer composition of claim 1 , wherein the alkyl methacrylate monomer is a methyl methacrylate, an ethyl methacrylate or a butyl methacrylate.
13. The thermoplastic polymer composition of claim 1 , wherein the polar group-containing acrylate monomer is selected from the group consisting of a hydroxyalkyl acrylate, a hydroxyalkyl methacrylate, an acrylamide, an aminoalkyl acrylate, aminoalkyl methacrylate, acrylic acid, and methacrylic acid.
14. The thermoplastic polymer composition of claim 3 , wherein the polymerization initiator is selected from the group consisting of azobisisobutyronitrile, benzoyl peroxide, lauroyl peroxide, t-butyl peroxide, dicumyl peroxide, t-butyl peracetate, 2,2-bis(t-butylperoxy)butane, 2,5-bis(t-butylperoxy)-2,5-dimethyl-3-hexyne, and 2,5-bis(t-butylperoxy)-2,5-dimethylhexane.
15. A thermoplastic polymer composition of claim 1 , wherein the composition comprises:
(a) an acrylate phase comprising an acrylate copolymer of an alkyl acrylate monomer, an alkyl methacrylate monomer, and a polar group-containing acrylate monomer; and
(b) a polyolefin phase comprising a blend of a polypropylene and a polyethylene copolymer;
wherein
the acrylate copolymer phase is dispersed in the polyolefin phase;
the alkyl acrylate monomer is selected from the group consisting of a methyl acrylate, an ethyl acrylate and a butyl acrylate;
the alkyl methacrylate monomer is selected from the group consisting of a methyl methacrylate, an ethyl methacrylate and a butyl methacrylate;
the polar group-containing acrylate monomer is selected from the group consisting of a hydroxyalkyl acrylate, a hydroxyalkyl methacrylate, an acrylamide, an aminoalkyl acrylate, aminoalkyl methacrylate, acrylic acid, and methacrylic acid; and
the polyethylene copolymer is selected from the group consisting of poly(ethylene-co-methylacrylate), poly(ethylene-co-ethylacrylate), poly(ethylene-co-butylacrylate), poly(ethylene-co-acrylic acid), poly(ethylene-co-methacrylic acid), poly(ethylene-co-glycidyl methacrylate), poly(ethylene-co-maleic acid), poly(ethylene-co-vinyl acetate), poly(ethylene-co-acrylamide), and poly(ethylene-co-acrylonitrile).
16. A thermoplastic polymer composition of claim 1 , wherein the composition comprises:
(a) an acrylate phase comprising an acrylate copolymer of an alkyl monomer, an alkyl methacrylate monomer, and a polar group-containing acrylate monomer; and
(b) a polyolefin phase comprising a blend of a polypropylene and a poly(ethylene-co-butylacrylate),
wherein
the alkyl acrylate monomer is a methyl acrylate, an ethyl acrylate or a n-butyl acrylate;
the alkyl methacrylate monomer is a methyl methacrylate, or a butyl methacrylate;
the polar group-containing acrylate monomer is a hydroxyethyl methacrylate, a hydroxypropyl methacrylate, or a hydroxylbutyl methacrylate; and
the acrylate phase is dispersed in the polyolefin phase.
17. A polyolefin-based thermoplastic polymer coating composition comprising
an acrylate copolymer phase comprising an acrylate copolymer of an alkyl acrylate monomer, an alkyl methacrylate monomer, and a polar group-containing acrylate monomer; and
a polyolefin phase comprising a blend of a polyolefin and at least one polyethylene copolymer,
wherein the acrylate copolymer phase is dispersed in the polyolefin phase.