Ink-jet water-based ink, ink-jet recording method, ink cartridge and ink-jet recording apparatus
The invention provides an ink-jet water-based ink that can stably record images having high fastness properties and excellent quality over a long period of time even in any case, and further provides an ink-jet recording method, by which images having excellent fastness properties and quality can be recorded, and an ink cartridge and an ink-jet recording apparatus containing such an ink. The ink-jet water-based ink principally includes a water-insoluble coloring material, a water-soluble organic solvent, an auxiliary component and water, wherein at least polyoxyethylene castor oil or polyoxyethylene hardened castor oil is contained as the auxiliary component.
1. An ink-jet water-based ink principally comprising a water-insoluble coloring material, a water-soluble organic solvent, an auxiliary component and water,
wherein at least polyoxyethylene castor oil or polyoxyethylene hardened castor oil is contained as the auxiliary component,
wherein the water-insoluble coloring material is a pigment, and the pigment is dispersed by a polymer dispersant,
wherein the polymer dispersant is a polymeric compound composed of at least a monomer having an anionic hydrophilic group, a monomer having an oxyethylene group, and a monomer having a hydrophobic group, and
wherein the ratio (A)/(B) of the number (A) of oxyethylene units in the polyoxyethylene castor oil or polyoxyethylene hardened castor oil to the number (B) of oxyethylene units in the polymer dispersant falls within a range of from 0.1 to 5, (A) and (B) being average numbers per molecule.
2. The ink-jet water-based ink according to claim 1 , wherein polyethylene glycol or polypropylene glycol is further contained as another auxiliary component.
3. The ink-jet water-based ink according to claim 1 , wherein the polymer dispersant is a block copolymer comprising a hydrophobic block composed of at least one vinyl ether and a hydrophilic block composed of at least one vinyl ether.
4. The ink-jet water-based ink according to claim 3 , wherein the hydrophilic block of the polymer dispersant comprises a block composed of a vinyl ether having a nonionic hydrophilic group and a block composed of a vinyl ether having an anionic hydrophilic group.
5. The ink-jet water-based ink according to claim 3 , wherein the polymer dispersant comprises a block composed of a hydrophobic vinyl ether, a block composed of a hydrophilic vinyl ether having a nonionic hydrophilic group and a block composed of a hydrophilic vinyl ether having an anionic hydrophilic group in this order.
6. An ink-jet recording method comprising applying energy to an ink to eject the ink, thereby applying the ink to a recording material to conduct recording, wherein the ink is the ink-jet water-based ink according to any one of claims 1 and 2 to 5 .
7. The ink-jet recording method according to claim 6 , wherein the energy is thermal energy.
8. The ink-jet recording method according to claim 6 , wherein the recording material is a recording material having an ink-receptive coating layer on at least one surface thereof.
9. An ink cartridge comprising an ink-storing portion storing an ink, wherein the ink is the ink-jet water-based ink according to any one of claims 1 and 2 to 5 .
10. An ink-jet recording apparatus comprising an ink cartridge equipped with an ink-storing portion storing an ink and a head portion for ejecting the ink, wherein the ink is the ink-jet water-based ink according to any one of claims 1 and 2 to 5 .