Reducing nitrogen concentration with in-situ steam generation
View Patent ↗In-situ steam generation (ISSG) is used to reduce the nitrogen concentration in silicon and silicon oxide areas.
1. A method for fabricating an integrated circuit, the method comprising:
providing a first region containing silicon and/or silicon oxide and also containing nitrogen, the first region being part of the integrated circuit; and then
growing silicon oxide on the first region by in-situ steam generation (ISSG) while reducing nitrogen concentration in the first region during the ISSG;
wherein providing the first region comprises nitriding the first region and a second region of the integrated circuit;
wherein the method further comprises, after nitriding the first region and the second region, forming a third region over the second region;
wherein growing the silicon oxide comprises growing the silicon oxide on the first region while reducing the nitrogen concentration in the first region while the second region is protected by the third region.
2. The method of claim 1 wherein growing the silicon oxide comprises flowing hydrogen, oxygen, and one or more gases into a chamber containing the first region, wherein the one or more gases are flown at a flow rate equal to at least 2.5% of a flow rate of the hydrogen.
3. The method of claim 2 wherein the one or more gases are argon.
4. The method of claim 1 wherein providing the first region comprises providing a silicon region with a nitrogen concentration of at least 1 atomic percent and at most 10 atomic percent; and
growing the silicon oxide comprises growing the silicon oxide on the silicon region while reducing the nitrogen concentration in the silicon region down from the at least 1 atomic percent and at most 10 atomic percent.
5. The method of claim 1 wherein providing the first region comprises providing a silicon oxide region with a nitrogen concentration of at least 1 atomic percent and at most 10 atomic percent; and
growing the silicon oxide comprises growing the silicon oxide on the silicon oxide region while reducing the nitrogen concentration in the silicon oxide region down from the at least 1 atomic percent and at most 10 atomic percent.
6. The method of claim 1 wherein providing the first region comprises providing unbound nitrogen atoms in the first region; and
growing the silicon oxide comprises growing the silicon oxide on the first region provided with the unbound nitrogen atoms.
7. The method of claim 1 wherein the second region is a gate dielectric region of a transistor, the gate dielectric comprising silicon oxide.
8. The method of claim 7 wherein a gate of the transistor and/or a channel region of the transistor and/or a source/drain region of the transistor comprise boron and/or phosphorus.
9. The method of claim 1 wherein growing the silicon oxide comprises flowing hydrogen and oxygen but not any nitrogen nor any nitrogen compound into a chamber containing the first region.
10. The method of claim 9 wherein growing the silicon oxide comprises flowing only the hydrogen, the oxygen, and either argon or helium into the chamber.
11. The method of claim 9 wherein growing the silicon oxide comprises the oxygen reacting with the nitrogen in the first region to form a gaseous nitrogen compound.
12. The method of claim 1 wherein growing the silicon oxide comprises flowing hydrogen and oxygen into a chamber containing the first region and causing the oxygen to react with the nitrogen in the first region to form a gaseous nitrogen compound.
13. The method of claim 2 wherein the one or more gases are flown at the flow rate equal to at least 100% of the flow rate of the hydrogen.
14. The method of claim 1 wherein the peak nitrogen concentration in the first region is reduced by at least a factor of 2 during the ISSG.
15. The method of claim 1 wherein growing the silicon oxide comprises:
providing a chamber containing the first region ; and then
flowing hydrogen, oxygen, and one or more other diluent gases but not any nitrogen nor any nitrogen compound into the chamber containing the first region to grow the silicon oxide on the first region by in-situ steam generation (ISSG), the one or more diluent gases diluting one or more gaseous nitrogen compounds formed in the ISSG from nitrogen extracted from the first region.
16. The method of claim 15 wherein the one or more diluent gases have a flow rate of at least 2.5% of a flow rate of the hydrogen.
17. The method of claim 16 wherein the one or more diluent gases consist of argon.
18. The method of claim 17 wherein the one or more diluent gases' flow rate is at most 200% of the hydrogen flow rate.
19. The method of claim 17 wherein the argon flow rate is at least 10% of the hydrogen flow rate.
20. The method of claim 17 wherein the argon flow rate is at least 50% of the hydrogen flow rate.
21. The method of claim 16 wherein the one or more diluent gases' flow rate is at least 100% of the hydrogen flow rate.
22. The method of claim 16 wherein the one or more diluent gases' flow rate is at least 150% of the hydrogen flow rate.
23. The method of claim 17 wherein the argon flow rate is 200% of the hydrogen flow rate.
24. The method of claim 15 wherein the peak nitrogen concentration in the first region is reduced by at least a factor of 2 during the ISSG.