Method of growing non-polar a-plane gallium nitride
View Patent ↗The invention provides a method of growing a non-polar a-plane gallium nitride. In the method, first, an r-plane substrate is prepared. Then, a low-temperature nitride-based nucleation layer is deposited on the substrate. Finally, the non-polar a-plane gallium nitride is grown on the nucleation layer. In growing the non-polar a-plane gallium nitride, a gallium source is supplied at a flow rate of about 190 to 390 μmol/min and the flow rate of a nitrogen source is set to produce a V/III ratio of about 770 to 2310.
1. A method of growing a non-polar a-plane gallium nitride comprising steps of:
(a) preparing an r-plane substrate;
(b) depositing a low-temperature nitride-based nucleation layer on the substrate; and
(c) growing the non-polar a-plane gallium nitride on the nucleation layer,
wherein the growing step (c) is carried out under the condition that a gallium source is supplied at a flow rate of about 190 μmol/min to about 390 μmol/min and the flow rate of a nitrogen source is set to produce a V/III ratio of about 770 to 2310,
wherein the pressure for growing the gallium nitride is about 0.5 atm or higher.
2. The method according to claim 1 , wherein the flow rate of the nitrogen source supplied in the growing step (c) is in the range of about 3.5 slm to about 20 slm.
3. The method according to claim 1 , wherein the V/III ratio in the growing step (c) is 1850 or less.
4. The method according to claim 1 , wherein the substrate comprises one selected from a group consisting of sapphire, silicon carbide, gallium nitride and zinc oxide.
5. The method according to claim 1 , wherein the substrate comprises an r-plate sapphire substrate.
6. The method according to claim 1 , wherein an in-plane orientation of the gallium nitride with respect to the r-plane substrate is [0001] GaN ∥[ 1 101] Sapphire and [ 1 101] GaN ∥[11 2 0] Sapphire .
7. The method according to claim 1 , wherein the nitride nucleation layer has a composition expressed by Al x Ga y In 1-x-y N, where 0≦x≦1 and 0≦y≦1.
8. The method according to claim 1 , wherein the depositing step (b) is carried out at a temperature of about 400° C. to about 900° C.
9. The method according to claim 1 , wherein the depositing step (b) is carried out at a temperature of about 900° C. to about 1200° C. and under a pressure of about 1.2 atm or less.
10. The method according to claim 9 , wherein the pressure for growing the gallium nitride is about 1 atm or less.
11. The method according to claim 9 , wherein the pressure for growing the gallium nitride is substantially identical to that for depositing the nitride nucleation layer.
12. The method according to claim 1 , wherein the gallium nitride is grown at a rate of at least 3.5 μm/hr.