Sulfur-containing dispersant and sulfide phosphor paste composition comprising the same
A sulfide phosphor paste composition comprising a sulfur-containing dispersant, and a fluorescent film prepared therefrom, are provided. The sulfur-containing dispersant has a dual head structure containing both a carboxyl group and a thiol group or a structure containing a thiol or thiophene group as a head group. An oligomeric sulfur-containing dispersant is also provided. Adsorption of the dispersant on the surface of the sulfide phosphor prevents aggregation of the phosphor particles, and thereby improves the dispersibility of the sulfide phosphor paste composition, the homogeneity of the phosphor in the paste composition, and the density of a film produced from the paste composition. Fluorescent films and display devices produced from the phosphor paste composition exhibit improved luminescent properties and excellent processability.
1. A sulfide phosphor paste composition, comprising:
a sulfur-containing dispersant selected from the group consisting of:
a compound of Formula 1
wherein
X is substituted C 1˜200 alkyl, unsubstituted C 1˜200 alkyl, substituted aryl, unsubstituted aryl, substituted arylalkyl, or unsubstituted arylalkyl, R is H or methyl, and P is a number from 1 to 10;
a compound of Formula 2
wherein 1 is a number from 1 to 20;
and a combination comprising at least one of the foregoing compounds;
a binder solution of an organic binder in a solvent; and
a phosphor.
2. The phosphor paste composition according to claim 1 , wherein the composition comprises 40-70% by weight of the phosphor and 0.1-3% by weight of the dispersant with respect to the phosphor powder, based on the weight of sulfur-containing dispersant, phosphor, and binder solution.
3. The phosphor paste composition according to claim 2 , wherein the binder solution includes 1.5-5% by weight of the organic binder and the remainder of a mixed solvent.
4. The phosphor paste composition according to claim 1 , wherein the organic binder comprises acrylic polymers, styrenic polymers, cellulose polymers, methacrylic ester polymers, styrene-acrylic ester copolymers, carbonate polymers, or a combination comprising at least one of the foregoing organic binders.
5. The phosphor paste composition of claim 4 , wherein the organic binder comprises polystyrene, polyvinylbutyral, polyvinyl alcohol, polyethylene oxide, polypropylene carbonate, polymethyirnethacrylate, ethyl cellulose, or a combination comprising at least one of the foregoing organic binders.
6. The phosphor paste composition according to claim 1 ,
wherein the solvent is at least one compound selected from the group consisting of: aromatic hydrocarbon compounds; ether compounds; ketone compounds; ester compounds; alcohol compounds; and a combination comprising at least one of the foregoing solvents.
7. The phosphor paste composition of claim 6 , where the solvent comprises toluene, xylene, tetrahydrofuran, 1,2-butoxyethane, acetone, methyl ethyl ketone, ethyl acetate, butyl acetate, butyl carbitol acetate (BCA), isopropyl alcohol, diethylene glycol monobutyl ether, terpineol, 2-phenoxyethanol, or a combination comprising at least one of the foregoing solvents.
8. The phosphor paste composition according to claim 1 , wherein the organic binder is ethyl cellulose and the solvent is a mixed solvent consisting of terpineol and butyl carbitol acetate.
9. The phosphor paste composition according to claim 8 , wherein the mixed solvent consists of terpineol and butyl carbitol acetate in a mixing ratio of 1:1 (w/w) to 1:2.5.
10. The phosphor paste composition according to claim 1 , wherein the phosphor comprises SrS:Eu 2+ , SrGaS:Eu 2+ , SrGa 2 S 4 , SrCaS:Eu 2+ , ZnS:Ag + , CaS:Eu 2+ , ZnS:Cu + Al 3+ , ZnS:Ag + ,Cl 31 , La 2 O 2 S, La 2 O 2 S:Eu 3+ , Y 2 O 2 S:Eu 3+ , CaAl 2 S 4 , or BaAl 2 S 4 : Eu 2+ .
11. A fluorescent film for a display device produced from the phosphor paste composition according to claim 1 .
12. A display device comprising the fluorescent film according to claim 11 .
13. The display device according to claim 12 , wherein the display device is a cathodoluminescent display, a liquid crystal display, an electroluminescence display, a field emission display, or a vacuum fluorescent display.