Interpenetrating polymer network as coating for metal substrate and method therefor
A coated article and method therefor comprises a metal substrate comprising a layered coating composition on at least one surface thereof, the coating composition comprising a layer of epoxy on one or more of the surfaces of the substrate. The coating composition further comprises an overcoat layer comprising a combination of polyolefin and epoxy resins, the overcoat layer optionally being free of added epoxy curative. The article can be a pipe, vessel, conduit, rod, profile-shaped article, or tube. A preferred overcoat layer comprises a semi- or full-epoxy/polyolefin interpenetrating polymer network (IPN). In another embodiment, the coated article comprises a polyolefin/epoxy layer that is directly coated on at least one surface of a metal substrate, the polyolefin/epoxy coating being overcoated with a thermoplastic top coating, the coated article being free of added adhesive. The metal article preferably is a pipe, vessel, conduit, rod, profile shaped article or tube.
1. A coated article comprising a metal substrate including a multi-layered coating on at least one surface thereof, said multi-layered coating comprising:
a partially-cured or fully-cured layer of at least one of an epoxy resin and a fusion bonded epoxy, said partially-cured or fully-cured layer provided on at least one surface of said metal substrate, and
an overcoat layer of a semi-interpenetrating polymer network (IPN) or full-interpenetrating polymer network (IPN), said overcoat layer provided on said partially-cured or fully-cured layer;
wherein the semi-IPN comprises a cured epoxy resin and a polyolefin component that is linear and not crosslinked;
wherein the full-IPN comprises a cured epoxy resin and a polyolefin component that is crosslinked; and
wherein said metal substrate is selected from the group consisting of a pipe, a vessel, a conduit, a rod, a profile shaped article, and a tube.
2. The coated article according to claim 1 , wherein said semi-IPN or full-IPN is formed from a formulation comprising:
a) 0.1 to 50 weight percent, based on the total formulation, of a curable epoxy resin,
b) an effective amount of a photocatalyst or a thermal curing agent for curing the curable epoxy resin, and
c) 1 to 99.9 weight percent, based on the total formulation, of at least one fully pre-polymerized hydrocarbon polyolefin resin and 0 to 98.9 weight percent, based on the total formulation, of a fully pre-polymerized functionalized polyolefin resin, wherein the total of said at least one fully pre-polymerized hydrocarbon polyolefin resin and said optional fully pre-polymerized functionalized polyolefin resin account for 50 to 99.9 weight percent of the total formulation; and
wherein the formulation for forming the full-IPN further comprises a crosslinking agent for crosslinking component c).
3. The coated article according to claim 2 wherein said formulation further comprises an adjuvant selected from the group consisting of insulation materials, reinforcing materials, and fillers.
4. The coated article according to claim 3 , wherein said adjuvant is selected from the group consisting of feldspar, wollastonite, bentonite, titanium dioxide, bubbles, beads, fibers, and cloths.
5. The coated article according to claim 3 wherein said reinforcing materials are selected from the groups consisting of nets, cloths, fibers of organic or inorganic materials, plastic or steel mesh, and rods.
6. The coated article according to claim 2 , wherein said semi-IPN or full-IPN is formed from a formulation comprising:
a) 1 to 10 weight percent, based on the total formulation, of a curable epoxy resin,
b) an effective amount of a photocatalyst or a thermal curing agent for curing the curable epoxy resin, and
c) 80-98 weight percent, based on the total formulation, of rubber modified polypropylene and 1 to 10 weight percent, based on the total formulation, of functionalized polypropylene; and
wherein the formulation for forming the full-IPN further comprises a crosslinking agent for crosslinking component c).
7. The coated article according to claim 6 , wherein said multi-layered coating further comprises a topcoat layer comprising at least one hydrocarbon polyolefin, said topcoat layer provided on said overcoat layer.
8. The coated article according to claim 6 , wherein said metal substrate is a steel pipe.
9. The coated article according to claim 6 , wherein said formulation further comprises an adjuvant selected from the group consisting of insulation materials, reinforcing materials, and fillers.
10. The coated article according to claim 9 , wherein said adjuvant is selected from the group consisting of feldspar, wollastonite, bentonite, titanium dioxide, bubbles, beads, fibers, and cloths.
11. The coated article according to claim 9 , wherein said reinforcing materials are selected from the groups consisting of nets, cloths, fibers of organic or inorganic materials, plastic or steel mesh, and rods.
12. The coated article according to claim 1 wherein said polyolefin component of the semi-IPN or full-IPN comprises one or both of polypropylene and polyethylene.
13. The coated article according to claim 1 wherein said polyolefin component of the semi-IPN or full-IPN is selected from the group consisting of high density polyethylene, ultra-high molecular weight polyethylene, linear low density polyethylene, low density polyethylene, metallocene polyolefin, unsaturated polyolefin rubber, saturated polyolefin rubber, isotactic polypropylene, polymethylpentene, cyclic olefin, polybutylene, and combinations, blends, and mixtures thereof
14. The coated article according to claim 1 wherein said cured epoxy resin of the semi-IPN or full-IPN is a cured product of an epoxy resin selected from the group consisting of aromatic epoxy resins, cycloaliphatic epoxy resins, and heterocyclic epoxy resins.
15. The coated article according to claim 1 wherein said polyolefin component of the full-IPN is crosslinked by one or more of free radical generators, end of chain backbone unsaturation or functionality, radiation, and thermal energy.
16. The coated article according to claim 15 wherein said radiation comprises electron beam radiation.
17. The coated article according to claim 1 wherein said metal substrate is a steel pipe.
18. The coated article according to claim 1 , wherein said multi-layered coating further comprises a topcoat layer comprising at least one hydrocarbon polyolefin, said topcoat layer provided on said overcoat layer.