Dual cure adhesives
View Patent ↗Adhesive compositions useful for laminating cellulosic substrates are formulated using an aqueous emulsion of a vinyl ester polymer such as polyvinyl acetate, one or more monomers or oligomers functionalized with (meth)acrylate groups, and a photoinitiator. The adhesive is cured by drying and exposing the adhesive to UV or visible light and is particularly useful for attaching clear films to cellulosic substrates such as paper and boxboard (e.g., in the manufacture of envelopes or folding cartons having windows).
1. A dual cure adhesive comprising:
a) a water-based emulsion of at least one of i) a vinyl ester homopolymer, ii) a copolymer consisting of two or more vinyl ester monomers or ii) a copolymer consisting of at least one vinyl ester monomer and at least one comonomer selected from the group consisting of alpha olefins, C1-C9 esters of mono- and dicarboxylic acids containing at least one carbon-carbon double bond, N-methylolacrylamide, N-vinyl formamide, and N-vinyl pyrrolidone;
b) at least one (meth)acrylate-functionalized monomer and/or oligomer capable of being polymerized and/or crosslinked by exposure to ultraviolet or visible light; and
c) at least one photoinitiatord
wherein said water-based emulsion is cured by evaporation/coalescence.
2. The dual cure adhesive of claim 1 , wherein component a) comprises from about 70 to about 95 percent by weight of the dual cure adhesive.
3. The dual cure adhesive of claim 1 , comprising at least one (meth)acrylate-functionalized urethane oligomer.
4. The dual cure adhesive of claim 1 , comprising at least one ethoxylated polyol poly(meth)acrylate containing at least three (meth)acrylate groups per molecule.
5. The dual cure adhesive of claim 1 , comprising at least one vinyl acetate homopolymer.
6. The dual cure adhesive of claim 1 , wherein component a) has a solids content of from about 50 to about 80% by weight.
7. The dual cure adhesive of claim 1 , wherein component b) comprises from about 5 to about 20% by weight of said dual cure adhesive.
8. The dual cure adhesive of claim 1 , wherein said dual cure adhesive has a viscosity of from about 900 to about 3000 cps at 25 degrees C.
9. The dual cure adhesive of claim 1 , additionally comprising at least one additive selected from the group consisting of plasticizers, fillers, thickeners, thixotropic agents, surfactants, emulsifiers, protective colloids, humectants, stabilizers, tackifiers, and dispersants.
10. The dual cure adhesive of claim 1 , wherein component c) comprises from about 0.1 to about 5 percent by weight of said dual cure adhesive.
11. The dual cure adhesive of claim 1 , wherein said at least one (methlacrylate-functionalized monomer and/or oligomer is water-soluble.
12. A method of bonding a first substrate to a second substrate, said method comprising forming a laminate of said first substrate and said second substrate with a layer of the dual cure adhesive of claim 1 therebetween and then exposing said layer of the dual cure adhesive to at least one of ultraviolet or visible light.
13. The method of claim 12 , wherein said first substrate is cellulosic and said second substrate is a film which is transparent to at least one of ultraviolet or visible light.
14. The method of claim 12 , wherein visible light is used to cure the layer of the dual cure adhesive and a light-emitting diode or array of light-emitting diodes is used as a source of the visible light.
15. The method of claim 12 , additionally comprising a step of drying said layer of said dual cure adhesive.
16. A method of making an article comprised of a cellulosic substrate having an opening therein and a film covering said opening, said method comprising forming a laminate of said cellulosic substrate and said substrate with a layer of the dual cure adhesive of claim 1 therebetween around at least a portion of the perimeter of said opening and then exposing said layer of said dual cure adhesive to at least one of ultraviolet or visible light.