Storage stable formulation and a process for its preparation
The present invention is directed to a storage stable insecticidal composition comprising one or more Chloronicotynyle compound, in an amount ranging from 0.1 to 5% by weight of the composition, one or more compounds falling within the group of Organophosphorus compounds in an amount ranging from 30 to 75% by weight of the composition and 69.9 to 20% by weight of conventional agriculturally acceptable carrier(s) and excepient(s) along with the process for obtaining the storage stable composition. At least one of the active ingredients is provided with a coating of a water soluble polymer.
1. An improved storage stable formulation for the protection of crops comprising as active ingredients imidacloprid and acephate, wherein imidacloprid is provided with a coating of a water soluble polymer in melt form and said formulation further includes a pH stabilizer that provides an overall pH of the formulation between 3-4.
2. The improved storage stable formulation as claimed in claims 1 further comprising wetting agents, dispersing agents, and inert fillers.
3. The improved storage stable formulation as claimed in claim 1 comprising (i) imidacloprid in an amount in the range of 0.1-25 wt % of the total weight of the formulation, (ii) acephate in an amount in the range of 5-97 wt % of the total weight of the formulation and (iii) a coating of a water soluble polymer in an amount in the range of 0.08-50 wt % of the total weight of the formulation.
4. The improved storage stable formulation as claimed in claim 3 further comprising (iv) a wetting agent in an amount in the range of 0.1-2.0 wt % of the total weight of the formulation, (v) a dispersing agent in an amount in the range of 0.5-7.0 wt % of the total weight of the formulation, and (vi) inert fillers in an amount in the range of 10-50 wt % of the total weight of the formulation.
5. The improved storage stable formulation as claimed in claim 1 wherein the water soluble polymer is selected from the group consisting of PEG 4000, PEG 6000, PEG 8000, PEG 10000, polyacrylamide, sodium polyacrylate, and copolymer of methyl methacrylate, butyl methacrylate and dimethylaminoethyl methacrylate.
6. The improved storage stable formulation as claimed in claim 3 wherein the water soluble polymer is selected from the group consisting of PEG 4000, PEG 6000, PEG 8000, PEG 10000, polyacrylamide, sodium polyacrylate, and copolymer of methyl methacrylate, butyl methacrylate and dimethylaminoethyl methacrylate.
7. The improved storage stable formulation as claimed in claim 4 wherein the water soluble polymer is selected from the group consisting of PEG 4000, PEG 6000, PEG 8000, PEG 10000, polyacrylamide, sodium polyacrylate, and copolymer of methyl methacrylate, butyl methacrylate and dimethylaminoethyl methacrylate.
8. A process for the preparation of an improved storage stable formulation for the protection of crops comprising,
a) providing as active ingredients imidacloprid and acephate;
b) coating imidacloprid with a water soluble polymer in melt form;
c) providing a pH stabilizer that imparts an overall pH of the formulation between 3-4;
d) blending the ingredients to form a homogenous mixture in powder form; and
e) optionally, converting the powder into granules or pellets.
9. The process of claim 8 , wherein the water soluble polymer is selected from the group consisting of PEG 4000, PEG 6000, PEG 8000, PEG 10000, polyacrylamide, sodium polyacrylate, and copolymer of methyl methacrylate, butyl methacrylate and dimethylaminoethyl methacrylate.
10. The process of claim 8 , wherein imidacloprid is present in an amount in the range of 0.1-25 wt % of the total weight of the formulation, acephate is present in an amount in the range of 5-97 wt % of the total weight of the formulation and the water soluble polymer is present in an amount in the range of 0.08-50 wt % of the total weight of the formulation.
11. The improved storage stable formulation of claim 1 , wherein said pH stabilizer is citric acid.
12. The process of claim 8 , wherein said pH stabilizer is citric acid.