All-solid-state lithium secondary cell and method of manufacturing the same

1. An all-solid-state lithium secondary cell comprising:

a laminate shaped into substantially a rectangular parallelepiped having one of a chamfered shape or an R-chamfered shape at four corners and four side lines of the laminate, the laminate comprising:

a positive electrode containing a positive electrode active material; a negative electrode containing a negative electrode active material; and a solid electrolyte between the positive electrode and the negative electrode; and

a pair of external current collectors disposed at both ends of the laminate to support side faces of the laminate, one of the current collectors being coupled to the positive electrode and another of the current collectors being connected to the negative electrode, wherein

in a cross section of the laminate along a stacked direction of the positive electrode, the negative electrode and the solid electrolyte, four corners of the cross section of laminate has one of a chamfered shape or an R-chamfered shape.

2. The all-solid-state lithium secondary cell of claim 1 , wherein the positive electrode includes a positive electrode current collector and the positive electrode active material provided on the positive electrode current collector, and the negative electrode includes a negative electrode current collector and the negative electrode active material provided on the negative electrode current collector.

3. The all-solid-state lithium secondary cell of claim 2 , wherein the positive electrode is one of a plurality of positive electrodes, the negative electrode is one of a plurality of negative electrodes, the solid electrolyte is one of a plurality of solid electrolytes, and the laminate includes a plurality of elemental units, each comprising one of the plurality of positive electrodes, one of the plurality of negative electrodes, and one of the plurality of solid electrolytes.

4. The all-solid-state lithium secondary cell of claim 3 , wherein a layer made of a material same as the solid electrolyte is in an outermost layer of the laminate.

5. The all-solid-state lithium secondary cell of claim 1 , wherein a curvature radius of the R-chamfered shape is smaller than ⅕ a length of the laminate in a laminated direction and is at least 30 μm.

6. The all-solid-state lithium secondary cell of claim 1 , further comprising a seal including at least one of a glass and a resin mold for sealing a portion exposed from the external current collectors of the laminate.

7. A method of manufacturing an all-solid-state lithium secondary cell, the method comprising:

(A) producing a laminate that has substantially a rectangular parallelepiped shape and one of a chamfered shape or an R-chamfered shape at four corners and four side lines of the laminate, by stacking a positive electrode, a negative electrode, and a solid electrolyte; and

(B) disposing external electrodes at both ends of the laminate to support side faces thereof, wherein

the laminate is produced so that in a cross section of the laminate along a stacked direction of the positive electrode, the negative electrode and the solid electrolyte, four corners of the cross section of laminate has one of a chamfered shape or an R-chamfered shape.

8. The method of producing the all-solid-state lithium secondary cell of claim 7 , wherein step (A) includes sub-steps:

(1) producing green sheets of the positive electrode active material, positive electrode current collector, negative electrode active material, negative electrode current collector, and solid electrolyte separately;

(2) sequentially laminating each of the green sheets of the positive electrode current collector, positive electrode active material, solid electrolyte, negative electrode active material, and negative electrode current collector in this order, to produce a laminated sheet;

(3) cutting the laminated sheet to provide a green chip;

(4) forming four corners and four side lines of the green chip into one of the chamfered or R chamfered shapes; and

(5) sintering the green chip after sub-step (4) to provide the laminate.

9. The method of producing the all-solid-state lithium secondary cell of claim 8 , further including, after sub-step (3), drying the green chip so that an amount of a plasticizer remained in the green chip is at least 25 weight % and at most 99 weight % based on an amount of the plasticizer before drying.

10. The method of producing the all-solid-state lithium secondary cell of claim 8 , wherein the four corners and the four side lines of the green chip are ground in sub-step (4).

11. The method of producing the all-solid-state lithium secondary cell of claim 10 , wherein a powder made of a material same as the solid electrolyte is used as an abrasive in sub-step (4).

12. The method of manufacturing the all-solid-state lithium secondary cell of claim 8 , wherein the laminated sheet is produced by repeating laminating operations a plurality of times in sub-step (2), and in each laminating operation, green sheets of the solid electrolyte, the negative electrode active material, the negative electrode current collector, the negative electrode active material, the solid electrolyte, the positive electrode active material, the positive electrode current collector, and the positive electrode active material are each sequentially laminated in this order.