Silicon compound and a production process for silicon compound
The object of the present invention is to provide a new kind of silicon compound having an ester-type organic functional group and a new method for providing a T 8 -silsesquioxane compound having a hydroxyl group by using said silicon compound as the starting material. A silicon compound represented by formula (1) is obtained through the production process characterized by using a silicon compound represented by formula (2). wherein: in formula (1), each of seven R 1 group is independently selected from the group consisting of hydrogen, alkyl, substituted or unsubstituted aryl, and substituted or unsubstituted arylalkyl and A 2 is a hydroxyl-terminal organic functional group, and in formula (2), each of R 1 group is the same as R 1 in formula (1), and A 1 is an organic functional group containing an acyloxy group.
1. A silicon compound represented by formula (1), being prepared from a silicon compound represented by formula (2),
wherein: in formula (1), each of seven R 1 is independently selected from the group consisting of (a) hydrogen, (b) (ii) 2-methylpropyl, (iii) 2,4,4-trimethylpentyl, (iv) cyclopentyl, (v) cyclohexyl, (vi) trifluoropropyl, (vii) tridecafluoro-1,1,2,2,-tetrahydrooctyl and (viii) unsubstituted phenyl, (c) substituted or unsubstituted aryl and (d) substituted or unsubstituted arylalkyl wherein each hydrogen of the alkenylene may be optionally substituted with fluorine and each —CH 2 — group of said alkenylene may be optionally replaced with —O— or —CH═CH—; and A 2 is a hydroxyl-terminal organic group, and in formula (2), R 1 is the same as R 1 in formula (1) and A 1 is an organic compound having an acyloxy group.
2. The silicon compound according to claim 1 , wherein (a) in formula (1), all of seven R 1 are the same functional groups selected from the group consisting of (ii) 2-methylpropyl, (iii) 2,4,4-trimethylpentyl, (iv) cyclopentyl, (v) cyclohexyl, (vi) trifluoropropyl, (vii) tridecafluoro-1,1,2,2,-tetrahydrooctyl and (viii) unsubstituted phenyl; (b) A 2 is a group represented by formula (3) and (c) A 1 in formula (2) is a group represented by formula (4),
wherein: in formula (3), Z 1 is either C 1 -C 22 alkylene where each —CH 2 — group may be optionally replaced with —O—, or C 3 -C 8 alkenylene where each —CH 2 — group may be optionally replaced with —O—; in formula (4), R 2 is selected from the group consisting of C 1 -C 17 alkyl where each hydrogen may be optionally substituted with fluorine, C 2 -C 3 alkenyl, substituted or unsubstituted phenyl and unsubstituted phenylalkyl, and Z 1 is the same as Z 1 in formula (3).
3. The silicon compound according to claim 1 , wherein (a) in formula (1), all of seven R 1 are the same functional groups selected from the group consisting of (ii) 2-methylpropyl, (iii) 2,4,4-trimethylpentyl, (iv) cyclopentyl, (v) cyclohexyl, (vi) trifluoropropyl, (vii) tridecafluoro-1,1,2,2,-tetrahydrooctyl and (viii) unsubstituted phenyl; (b) A 2 is a group represented by formula (5) and (c) A 1 in formula (2) is a group represented by formula (6),
wherein: in formula (5), (A) Z 2 represents a single bond or C 1 -C 3 alkylene and may be bound to the benzene ring at any carbon position, (B) Z 3 is either C 1 -C 22 alkylene where each —CH 2 — may be optionally replaced with —O—, or C 3 -C 8 alkenylene where each —CH 2 — may be optionally replaced with —O—, in formula (6), R 2 is selected from the group consisting of C 1 -C 17 alkyl, C 2 -C 3 alkenyl, substituted or unsubstituted phenyl and unsubstituted phenylalkyl, and Z 2 and Z 3 are the same as Z 2 and Z 3 in formula (5).
4. The silicon compound according to claim 2 , wherein all of seven R 1 are either unsubstituted phenyl or trifluoropropyl.
5. The silicon compound according to claim 3 , wherein all of seven R 1 are either unsubstituted phenyl or trifluoropropyl.
6. A silicon compound represented by formula (1),
wherein: in formula (1), each of seven R 1 is independently selected from the group consisting of (a) hydrogen, (b) (ii) 2-methylpropyl, (iii) 2,4,4-trimethylpentyl, (iv) cyclopentyl,(v) cyclohexyl, (vi) trifluoropropyl, (vii) tridecafluoro-1,1,2,2,-tetrahydrooctyl and (viii) unsubstituted phenyl, (c) substituted or unsubstituted aryl and (d) substituted or unsubstituted arylalkyl wherein each hydrogen of the alkenylene may be optionally substituted with fluorine and each —CH 2 — group of said alkenylene may be optionally replaced with —O— or —CH═CH—; and A 2 is a hydroxyl-terminal organic group.
7. The silicon compound according to claim 6 , wherein (a) in formula (1), all of seven R 1 are the same functional groups selected from the group consisting of (ii) 2-methylpropyl, (iii) 2,4,4-trimethylpentyl, (iv) cyclopentyl, (v) cyclohexyl, (vi) trifluoropropyl, (vii) tridecafluoro-1,1,2,2,-tetrahydrooctyl and (viii) unsubstituted phenyl; and (b) A 2 is a group represented by formula (3),
wherein: in formula (3), Z 1 is either C 1 -C 22 alkylene where each —CH 2 — group may be optionally replaced with —O—, or C 3 -C 8 alkenylene where each —CH 2 — group may be optionally replaced with —O—.
8. The silicon compound according to claim 6 , wherein (a) in formula (1), all of seven are the same functional groups selected from the group consisting of (ii) 2-methylpropyl, (iii) 2,4,4-trimethylpentyl, (iv) cyclopentyl, (v) cyclohexyl, (vi) trifluoropropyl, (vii) tridecafluoro-1,1,2,2,-tetrahydrooctyl and (viii) unsubstituted phenyl; and (b) A 2 is a group represented by formula (5),
wherein: in formula (5), (A) Z 2 represents a single bond or C 1 -C 3 alkylene and may be bound to the benzene ring at any carbon position, and (B) Z 3 is either C 1 -C 22 alkylene where each —CH 2 — may be optionally replaced with —O—, or C 3 -C 8 alkenylene where each —CH 2 — may be optionally replaced with —O—.
9. The silicon compound according to claim 7 , wherein all, of seven R 1 are either unsubstituted phenyl or trifluoropropyl.
10. The silicon compound according to claim 8 , wherein all of seven R 1 are either unsubstituted phenyl or trifluoropropyl.