Method of forming phosphor film and method of manufacturing light emitting diode package incorporating the same
View Patent ↗The invention relates to a method of forming a phosphor film and a method of manufacturing an LED package incorporating the same. The method of forming a phosphor film includes mixing phosphor and light-transmitting beads in an aqueous solvent such that the nano-sized light-transmitting beads having a first charge are adsorbed onto surfaces of phosphor particles having a second charge. The method also includes coating a phosphor mixture obtained from the mixing step on an area where the phosphor film is to be formed, and drying the coated phosphor mixture to form the phosphor film. The invention further provides a method of manufacturing an LED package incorporating the method of forming the phosphor film.
1. A method of forming a phosphor film comprising steps of:
mixing phosphor and nano-sized light-transmitting beads in an aqueous solvent such that the nano-sized light-transmitting beads having a first charge are adsorbed onto surfaces of phosphor particles having a second charge;
coating a phosphor mixture obtained from the mixing step on an area where the phosphor film is to be formed; and
drying the coated phosphor mixture to form the phosphor film,
wherein the phosphor particles have a positive polarity, and each of the light-transmitting nano-beads has a functional group having a negative polarity on a surface thereof, selected from the group consisting of sulfonates, phosphates and carboxylates.
2. The method according to claim 1 , wherein the mixing step comprises adding and mixing a dispersing agent having a negative polarity together with the phosphor and the light-transmitting beads.
3. The method according to claim 1 , wherein each of the light-transmitting nano-beads has a mean diameter of 50 nm to 500 nm.
4. The method according to claim 1 , wherein the light-transmitting nano-beads have a glass transition temperature of at least 100° C.
5. The method according to claim 1 , wherein each of the light-transmitting nano-beads comprises one selected from the group consisting of polyethylene (PE), polypropylene (PP), polystyrene (PS), polyethylene terephthalate (PET), polyethylene naphthalate (PEN), polybutelene terephtalate (PBT), polyethersulfone (PES), polyetherketone (PEEK), polycarbonate (PC), polyimide (PI), polyetherimide and polyacrylate.
6. The method according to claim 1 , wherein the phosphor comprises 2 wt % to 10 wt % of the aqueous solvent.
7. The method according to claim 1 or 6 , wherein the light-transmitting nano-beads comprise 5 wt % to 10 wt % with respect to the weight of the phosphor in the phosphor mixture.
8. The method according to claim 1 , wherein the aqueous solvent comprises deionized water or alcohol.
9. A method of manufacturing a light emitting diode package, comprising steps of
mixing phosphor and nano-sized light-transmitting beads in an aqueous solvent such that the nano-sized light-transmitting beads having a first charge are adsorbed onto surfaces of the phosphor particles having a second charge;
coating a phosphor mixture obtained from the mixing step on at least a light emitting surface portion of a light emitting diode chip;
drying the coated phosphor mixture to form a phosphor film; and
forming a resin part on the light emitting diode chip with the phosphor film formed thereon,
wherein the phosphor particles have a positive polarity, and the each of the light-transmitting nano-beads has a functional group having a negative polarity selected from the group consisting of sulfonates, phosphates and carboxylates on a surface thereof.
10. The method according to claim 9 , wherein the mixing step comprises adding and mixing a dispersing agent having a negative polarity together with the phosphor and the light-transmitting beads.
11. The method according to claim 9 , wherein each of the light-transmitting nano-beads has a mean diameter of 50 to 50 nm.
12. The method according to claim 9 , wherein each of the light-transmitting nano-beads has a glass transition temperature of at least 100° C.
13. The method according to claim 9 , wherein the light-transmitting nano-beads has a refractive index higher than that of the light emitting diode and lower than that of the resin part.
14. The method according to claim 9 , wherein each of the light-transmitting nano-beads comprises one selected from the group consisting of polyethylene (PE), polypropylene (PP), polystyrene (PS), polyethylene terephthalate (PET), polyethylene naphthalate (PEN), polybutelene terephtalate (PBT), polyethersulfone (PES), polyetherketone (PEEK), polycarbonate (PC), polyimide (PI), polyetherimide and polyacrylate.
15. The method according to claim 9 , wherein the phosphor is mixed in the amount of 2 wt % to 20 wt % of the aqueous solvent.
16. The method according to claim 9 or 15 , wherein the light-transmitting nano-beads are mixed in the amount of 5 wt % to 40 wt % with respect to the weight of the phosphor in the phosphor mixture.
17. The method according to claim 9 , wherein the aqueous solvent comprises deionized water or alcohol.