Platinum particles with varying morphology
View Patent ↗Nanometer to micrometer sized particles containing platinum and having selected morphologies are prepared by a sonochemical process. A compound of platinum is dissolved, suspended, or diluted in a suitable liquid medium at a predetermined concentration and the liquid is maintained at a predetermined temperature from sub-ambient temperatures to above ambient temperatures. A reducing gas is bubbled through the liquid as it is subjected to cavitation at a controlled power to affect the reductive decomposition of the platinum compound. The morphology of the precipitated platinum particles can be varied widely by varying the described concentration, temperature and power parameters.
1. A method of making platinum particles, the method comprising:
suspending or dissolving at least one precursor compound of platinum at a predetermined concentration level in a liquid medium of water, a water and alcohol mixture, or a hydrocarbon selected from the group consisting of decane, dodecane, tridecane, decalin, and tetralin;
heating the liquid to a temperature of about 60° C.;
bubbling a reducing gas consisting essentially of hydrogen gas through the liquid medium; and
subjecting the liquid medium to ultrasonic vibrations at a predetermined power level to reduce the precursor(s) to micrometer size, spherical platinum particles with surfaces containing spike-like protuberances.
2. A method of making platinum particles as recited in claim 1 in which the reducing gas is hydrogen.
3. A method of making platinum particles as recited in claim 1 in which the hydrogen gas is used in combination with at least one inert gas selected from the group consisting of argon, helium, neon, and nitrogen.
4. A method of making platinum particles as recited in claim 1 in which the liquid medium is water.
5. A method of making platinum particles as recited in claim 1 in which the liquid medium is a hydrocarbon selected from the group consisting of decane, dodecane, tridecane, decalin, and tetralin.
6. A method of making platinum particles as recited in claim 1 in which the precursor compound is a platinum halide or an organo-platinum compound.
7. A method of making platinum particles as recited in claim 1 in which the precursor compound comprises at least one compound selected from the group consisting of chloroplatinic acid, bis(ethylenediamine) platinum (II) dichloride, dimethyl (1 ,5-cyclooctadiene) platinum (II), and platinum (II) acetylacetonate.
8. A method of making platinum particles, the method comprising:
suspending or dissolving at least one precursor compound of platinum at a predetermined concentration level in a liquid medium of water or a water and alcohol mixture;
heating the liquid to a temperature of about 60° C.;
bubbling a reducing gas consisting essentially of hydrogen gas through the liquid medium to maintain anaerobic conditions; and
subjecting the liquid medium to ultrasonic vibrations at a predetermined power level to reduce the precursor(s) to micrometer size, spherical platinum particles with surfaces containing spike-like protuberances.
9. A method of making platinum particles as recited in claim 8 in which the reducing gas is hydrogen.
10. A method of making platinum particles as recited in claim 8 in which the hydrogen gas is used in combination with at least one inert gas selected from the group consisting of argon, helium, neon, and nitrogen.
11. A method of making platinum particles as recited in claim 8 in which the liquid medium is water.
12. A method of making platinum particles as recited in claim 1 in which the precursor compound is a platinum halide or an organo-platinum compound.