Lithium Ion Secondary Battery and Method for Producing the Same
A lithium ion secondary battery includes: a positive electrode including a positive electrode substrate, and a positive electrode material mixture layer carried on the positive electrode substrate; a negative electrode including a negative electrode substrate, and a negative electrode material mixture layer carried on the negative electrode substrate; a separator; a non-aqueous electrolyte including a non-aqueous solvent that contains a carbonic ester, and a solute dissolved in the non-aqueous solvent; and a porous film bonded to a surface of at least one of the positive electrode and the negative electrode. The porous film includes an inorganic filler and a film binder, and the solubility parameter of the film binder is different from the solubility parameter of the non-aqueous solvent by 1 or more.
1 . A lithium ion secondary battery comprising:
a positive electrode comprising a positive electrode substrate, and a positive electrode material mixture layer carried on said positive electrode substrate;
a negative electrode comprising a negative electrode substrate, and a negative electrode material mixture layer carried on said negative electrode substrate;
a separator;
a non-aqueous electrolyte comprising a non-aqueous solvent that contains a carbonic ester, and a solute dissolved in said non-aqueous solvent; and
a porous film bonded to a surface of at least one of said positive electrode and said negative electrode;
wherein said porous film comprises an inorganic filler and a film binder, and
the solubility parameter of said film binder is different from the solubility parameter of said non-aqueous solvent by 1 or more.
2 . The lithium ion secondary battery in accordance with claim 1 , wherein said film binder comprises a cured thermo-cross-linkable resin.
3 . The lithium ion secondary battery in accordance with claim 2 , wherein said thermo-cross-linkable resin is of single-liquid-type.
4 . The lithium ion secondary battery in accordance with claim 1 , wherein said non-aqueous solvent containing a carbonic ester has a solubility parameter from 11.5 to 14.
5 . A method for producing a lithium ion secondary battery, comprising the steps of:
mixing an electrode material that comprises an electrode active material and an electrode binder with an electrode formative dispersion medium, to prepare an electrode material mixture slurry;
applying said electrode material mixture slurry onto an electrode substrate, and drying said applied slurry, to form an electrode material mixture layer;
dissolving a solute into a non-aqueous solvent containing a carbonic ester to prepare a non-aqueous electrolyte;
mixing a film forming material that comprises an inorganic filler and a film binder with a film formative dispersion medium to prepare a porous film paste;
applying said porous film paste to a surface of said electrode material mixture layer, and drying said applied paste, to form a porous film; and
fabricating a battery by using the electrode with said porous film and said non-aqueous electrolyte;
wherein the solubility parameter of said film binder is different from the solubility parameter of said non-aqueous solvent by 1 or more.
6 . The method for producing the lithium ion secondary battery in accordance with claim 5 , wherein said film binder comprises a thermo-cross-linkable resin.
7 . The method for producing the lithium ion secondary battery in accordance with claim 6 , wherein said thermo-cross-linkable resin is of single-liquid-type.
8 . The method for producing the lithium ion secondary battery in accordance with claim 5 , wherein said non-aqueous solvent containing a carbonic ester has a solubility parameter from 11.5 to 14.
9 . The method for producing the lithium ion secondary battery in accordance with claim 5 , wherein the solubility parameter of said electrode formative dispersion medium is different from the solubility parameter of said non-aqueous solvent by 1 or more.
10 . The method for producing the lithium ion secondary battery in accordance with claim 5 , wherein the solubility parameter of said film formative dispersion medium is different from the solubility parameter of said non-aqueous solvent by 1 or more.