Nanoparticle coating process for fuel cell components
View Patent ↗A process including coating a fuel cell component using a coating solution including nanoparticles.
1. A process comprising:
applying an aqueous solution comprising a polyelectrolyte polymer to the fuel cell component so that at least a portion of the polyelectrolyte polymer adheres to at least a portion of the component the polyelectrolyte polymer comprising first functional groups;
submerging a fuel cell component in a bath comprising nanoparticles comprising second functional groups and a liquid phase comprising a nanoparticle dispersion agent;
removing the fuel cell component from the bath so that a coating of nanoparticles adheres to the polyelectrolyte polymer adhered to the fuel cell component and wherein the first functional group and second functional group form an ionic bond;
rinsing the fuel cell component to remove any nanoparticles not sufficiently adhered to the fuel cell component prior to drying the coating; and
drying the coating.
2. A process as set forth in claim 1 wherein the dispersion agent comprises an alcohol.
3. A process as set forth in claim 2 wherein the alcohol is present in at least 30 percent by volume of the liquid phase.
4. A process as set forth in claim 3 wherein the liquid phase further comprises water in an amount of 0.1-70 volume percent of the liquid phase.
5. A process as set forth in claim 2 wherein the alcohol comprises at least one of methanol, ethanol or propanol.
6. A process as set forth in claim 1 wherein the nanoparticle dispersion agent comprises an organic solvent capable of making a solution with water.
7. A process as set forth in claim 6 wherein the liquid phase further comprises water.
8. A process as set forth in claim 1 repeating the applying submerging, removing, rinsing and drying to process at least two layers of nanoparticles on the fuel cell component.
9. A process as set forth in claim 1 wherein the fuel cell component comprises a bipolar plate.
10. A process as set forth in claim 1 wherein the polyelectrolyte polymer includes positive cationic functional groups.
11. A process as set forth in claim 1 wherein the polyelectrolyte polymer includes anionic functional groups.
12. A process as set forth in claim 1 further comprising applying a second coating material to the polyelectrolyte polymer adhered to the component.
13. A process as set forth in claim 10 further comprising applying a second coating material including negative functional groups to the polyelectrolyte polymer adhered to the component and so that the negative functional groups and the positive functional groups form an ionic bond.
14. A process as set forth in claim 1 wherein the nanoparticles include negative functional groups.
15. A process as set forth in claim 1 wherein the nanoparticles comprising siloxane.
16. A process as set forth in claim 1 wherein the nanoparticles comprise silicon dioxide.
17. A process as set forth in claim 1 wherein the nanoparticles are present in an amount of 0.2 to 5 weight percent of the bath.
18. A process comprising:
(a) applying an aqueous polyelectrolyte polymer solution to a fuel cell component so that at least a portion of the polyelectrolyte polymer adheres to at least a portion of the component;
(b) removing any polyelectrolyte polymer not adhered to the fuel cell component;
(c) adhering a second coating material to the polyelectrolyte polymer adhered to the component;
(d) removing any of the second coating material not adhered to the polyelectrolyte polymer adhered to the component;
(e) submerging the fuel cell component in a bath comprising nanoparticles and a liquid phase comprising a dispersion agent;
(f) removing the fuel cell component from the bath so that a coating of nanoparticles adheres to the fuel cell component and;
(g) rinsing the fuel cell component to remove any nanoparticles not sufficiently adhered to the fuel cell component.
19. A process as set forth in claim 18 further comprising repeating (a-d) several times.
20. A process as set forth in claim 18 further comprising repeating (f-g) several times.
21. A process as set forth in claim 18 wherein the nanoparticles are present in an amount of 0.2 to 5 weight percent of the bath.
22. A process comprising:
(a) removing grease and contaminants from a fuel cell bipolar plate by immersing the plate in a pretreatment solution;
(b) rinsing the plate in a first bath of deionized water;
(c) rinsing the plate in a second bath of deionized water;
(d) immersing the plate in a first aqueous solution of a first polyelectrolyte polymer;
(e) rinsing the plate in a third bath of deionized water to remove any of the first polyelectrolyte polymer not adhered to the plate;
(f) rinsing the plate in a fourth bath of deionized water;
(g) immersing the plate in a second dispersion comprising a second coating material, wherein the second dispersion includes nanoparticles and an alcohol;
(h) rinsing the plate in a fourth bath of deionized water to remove any of the second coating material not adhered to the first polyelectrolyte polymer adhered to the plate;
(i) rinsing the plate in a fifth bath of deionized water;
(j) repeating (d-I) for at least three cycles;
(k) drying the plate.
23. A process as set forth in claim 22 wherein the first polyelectrolyte polymer adhered to the plate includes cationic functional groups.
24. A process as set forth in claim 23 wherein the nanoparticles having anionic functional groups.
25. A process as set forth in claim 22 wherein the first polyelectrolyte polymer comprises at least one of: a copolymer of acrylamide and quaternary ammonium salts; a polyamido-amine; a polyallylamine hydrochloride; an epoxy based azo polymer; or an acrylic acid based azo polymer.
26. A process as set forth in claim 22 wherein the nanoparticles are present in an amount of 0.2 to 5 weight percent of the dispersion.
27. A process comprising:
applying an aqueous solution comprising a polyelectrolyte polymer to a fuel cell component so that at least a portion of the polyelectrolyte polymer adheres to at least a portion of the component the polyelectrolyte polymer comprising a first ionic functional group;
removing any unadhered polyelectrolyte polymer from the fuel cell component; and
applying a second coating material to the polyelectrolyte polymer adhered to the fuel cell component, the second coating material comprising nanoparticles and a dispersion agent where the nanoparticles comprises a second ionic functional group having a charge opposite the first group so that the nanoparticles adhere to the polyelectrolyte polymer adhered to the fuel cell component.
28. A process as set forth in claim 27 wherein the fuel cell component comprises a bipolar plate.
29. A process as set forth in claim 27 wherein the polyelectrolyte polymer includes cationic functional groups.
30. A process as set forth in claim 27 wherein the polyelectrolyte polymer includes anionic functional groups.
31. A process as set forth in claim 27 wherein the nanoparticles having a size ranging from about 2 to about 100 nanometers.
32. A process as set forth in claim 27 wherein the nanoparticles comprise inorganic or organic materials.
33. A process as set forth in claim 27 wherein the nanoparticles comprising hydrophilic side chains.
34. A process as set forth in claim 27 wherein the nanoparticles comprise 10 to 90 weight percent inorganic structures, 5 to 70 weigh percent hydrophilic, and 0 to 50weight percent organic side chains having a functional group.
35. A process as set forth in claim 27 wherein the nanoparticles comprise at least one of an amino, sulfonate, sulfate, sulfite, sulfonamide, sulfoxide, carboxylate, polyol, polyether, phosphate, or phosphonate group.
36. A process as set forth in claim 27 wherein the nanoparticles comprise organic side chains having functional groups and wherein the functional groups of the organic side chains are epoxy, acryloxy, methacryloxy, glycidyloxy, allyl, vinyl, carboxyl, mercapto, hydroxyl, amide or amino, isocyano, hydroxy, or silanol groups.
37. A process as set forth in claim 27 wherein the fuel cell component comprise a substrate comprising at least one of a metal, polymeric material or electrically conductive composite material.
38. A process as set forth in claim 27 wherein the nanoparticles comprise at least one of SiO 2 , HfO 2 , ZrO 2 , Al 2 O 3 , SnO 2 , Ta 2 O 5 , Nb 2 O 5 , MoO 2 , IrO 2 , RuO 2 , metastable oxynitrides, nonstoichiometric metal oxides, oxynitrides, or derivatives thereof including carbon chains or including carbon, or mixtures thereof.
39. A process as set forth in claim 27 wherein the nanoparticles comprise at least one Si—O group, at least one polar group and at least one group including a saturated or unsaturated carbon chain.
40. A process as set forth in claim 27 wherein the nanoparticles comprise a polar group comprising at least one of a hydroxyl, halide, carboxyl, ketonic or aldehyde functional groups.
41. A process as set forth in claim 27 wherein the second coating material further comprises Au, Ag, Ru, Rh, Pd, Re, Os, Ir, Pt, rare earth metals, alloys thereof, polymeric carbon or graphite.
42. A process as set forth in claim 27 wherein each of the nanoparticles comprises a Si—O group and a Si—R group wherein R includes a saturated or unsaturated carbon chain, and wherein the molar ratio of Si—R groups to Si—O groups ranges from 1/8 to ½.
43. A process as set forth in claim 27 wherein the second coating material comprises a material derived from a siloxane.
44. A process as set forth in claim 27 wherein the nanoparticles are derived from a material having the formula:
wherein R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 , each may be H, O, Cl, or a saturated or unsaturated carbon chain having 1 to 4 carbon atoms, and wherein R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 , may be the same or different, and at least one of R 1 , R 2 , R 3 , R 4 , R 5 , or R 6 is a carbon chain with at least one carbon atom.
45. A process as set forth in claim 27 wherein the applying a second coating comprises submerging the fuel cell component in a bath comprising the nanoparticles and a dispersion agent.
46. A process as set forth in claim 45 further comprising removing the fuel cell component from the bath and drying the second coating.
47. A process as set forth in claim 46 further comprising repeating the submerging, removing the fuel cell component from the bath and the drying to produce multiple layers of nanoparticles on the fuel cell component, and wherein the multiple layers together are at least 100 nm thick.
48. A process as set forth in claim 46 wherein the nanoparticles comprise silicon, and further comprising repeating the submerging, removing the fuel cell component from the bath and the drying to produce multiple layers of nanoparticles on the fuel cell component, and wherein the multiple layers together have at least 1.5 atomic weight percent silicon.
49. A process as set forth in claim 45 wherein the nanoparticles are present in an amount of 0.2 to 5 weight percent of the bath.