Milled particle compositions and related methods and structures
Small particle compositions including nanoparticle compositions are provided. The particle compositions, in some cases, are characterized by having an extremely small average particle size (e.g., 150 nanometers or less). The small particles may comprise a semiconductor material and/or a light-emitting material. In some embodiments, the particles may be in the form a preferred shape including platelets, amongst others. The small particle compositions may be produced in a milling process. In some embodiments, the milling process uses preferred types of grinding media to form milled particles having desired characteristics (e.g., particle size, shape). The small (or nano) particle compositions may be used in a variety of different applications including light-emitting applications. In certain applications, it may be desirable to form thin films from the small particle compositions.
1. A particle composition comprising:
milled particles comprising a semiconductor material and having an average particle size of less than 150 nm, wherein the particles have a platelet shape, wherein the platelet shape particles are formed in a milling process and a majority of the particles have a (002) crystallographic orientation.
2. The particle composition of claim 1 , wherein the particles comprise a group III-V material.
3. The particle composition of claim 1 , wherein the particles comprise a gallium nitride material.
4. The particle composition of claim 1 , wherein the particles have an average particle size of less than 50 nm.
5. The particle composition of claim 1 , wherein the particles comprise a light-emitting material.
6. The particle composition of claim 1 , wherein the composition has a contamination level of less than 900 ppm.
7. A particle composition comprising:
milled particles comprising a light-emitting material and having an average particle size of less than 150 nm, wherein the particles have a platelet shape, wherein the platelet shape particles are formed in a milling process and a majority of the particles have a (002) crystallographic orientation.
8. A thin film comprising:
milled particles comprising a semiconductor material and having an average particle size of less than 150 nm, wherein the particles have a platelet shape, wherein the platelet shape particles are formed in a milling process and a majority of the particles have a (002) crystallographic orientation.
9. The thin film of claim 8 , wherein the thin film comprises a composite comprising the particle composition and a polymeric material.
10. The thin film of claim 8 , wherein the thin film includes a plurality of staggered grain boundaries.
11. The thin film of claim 8 , wherein the thin film has a preferred crystallographic orientation in the same direction as the crystallographic orientation of the particles.
12. The thin film of claim 8 , wherein the thin film has a (002) crystallographic orientation.