Heat-sensitive recording material and process for producing the same
The present invention relates to a heat-sensitive recording material having a high recording sensitivity, which is capable of providing excellent image quality even when recording is carried out at low energy, and causes reduced coating defects. The invention provides a heat-sensitive recording material obtained by forming, on a paper support, an undercoat layer and then a heat-sensitive recording layer, characterized in that: 1) the undercoat layer has at least two undercoat layers including a first undercoat layer and a second undercoat layer; and 2) the heat-sensitive recording layer has a thickness standard deviation of 0.30 or less, and also provides a method for producing the heat-sensitive recording material.
1. A heat-sensitive recording material comprising:
(i) a paper support,
(ii) an undercoat layer formed on the paper support, and
(iii) a heat-sensitive recording layer formed on the undercoat layer;
a) the undercoat layer having a multilayer structure comprising at least a first layer and a second layer formed on the first layer; and
b) the heat-sensitive recording layer having a thickness standard deviation of 0.30 or less.
2. A heat-sensitive recording material according to claim 1 , wherein the first undercoat layer and the second undercoat layer are formed from the same undercoat layer coating composition.
3. A heat-sensitive recording material according to claim 2 , wherein the undercoat layer coating composition has a viscosity as measured by a Hercules viscometer at 8800 rpm of 25 to 40 mPa·s, and a viscosity as measured by a BL viscometer at 60 rpm of 700 to 2000 mPa·s.
4. A heat-sensitive recording material according to claim 1 , wherein the ratio of the dry coating amount of the first undercoat layer to the dry coating amount of the second undercoat layer is 2:8 to 8:2.
5. A heat-sensitive recording material according to claim 1 , wherein the total dry coating amount of the first undercoat layer and the second undercoat layer is, 5 to 35 g/m 2 .
6. A heat-sensitive recording material according to claim 1 , wherein the fist undercoat layer is formed by blade coating followed by drying, and the second undercoat layer is formed by rod coating followed by drying.
7. A heat-sensitive recording material according to claim 6 , wherein, after the first undercoat layer is formed, the second undercoat layer is formed without winding the paper support provided with the first undercoat layer.
8. A heat-sensitive recording material according to claim 1 , wherein the heat-sensitive recording layer further comprises a pigment, and said pigment is in the form of secondary particles having an average particle diameter of 30 to 900 nm formed by an agglomeration of amorphous silica primary particles having a particle diameter of at least 3 and less than 30 nm.
9. A heat-sensitive recording material according to claim 1 or 8 , further comprising a protective layer formed on the heat-sensitive recording layer.
10. A heat-sensitive recording material according to claim 9 , wherein the protective layer comprises a pigment, and said pigment is in the form of secondary particles having an average particle diameter of 30 to 900 nm formed by agglomeration of amorphous silica primary particles having a particle diameter of 3 to 70 nm.
11. A heat-sensitive recording material according to claim 9 , wherein the protective layer has a thickness of 0.4 to 2.5 μm.
12. A method for producing a heat-sensitive recording material obtained by forming, on a paper support, an undercoat layer and then a heat-sensitive recording layer, the method comprising:
a first step of forming a first undercoat layer on the paper support by blade coating followed by drying, and
a second step of forming a second undercoat layer on the first undercoat layer by rod coating followed by drying.
13. A method according to claim 12 , wherein the second step is carried out after the first step without winding the paper support provided with the first undercoat layer.
14. A method according to claim 12 , wherein coating compositions for forming the first undercoat layer and the second undercoat layer each have a viscosity as measured by a Hercules viscometer at 8800 rpm of 25 to 40 mPa·s, and a viscosity as measured by a BL viscometer at 60 rpm of 700 to 2000 mPa·s.