High-strength fiber of biodegradable aliphatic polyester and process for producing the same
An object of the present invention is to provide: a process for conveniently producing a fiber with high strength, regardless of molecular weight polymer composition, or the like of PHAs, which vary depending on origins such as a wild-type PHAs-producing microorganism product, a genetically modified strain product, and a chemical product; and the fiber with high strength produced through the process. The present invention provides: a process for producing a fiber, comprising: melt-extruding polyhydroxyalkanoic acid to form a melt-extruded fiber; rapidly quenching the melt-extruded fiber to the glass transition temperature of polyhydroxyalkanoic acid +15° C. or less, and solidifying the fiber to form an amorphous fiber; forming a crystalline fiber by leaving the amorphous fiber to stand at the glass transition temperature +15° C. or less; drawing the crystalline fiber; and further subjecting the crystalline fiber to stretch heat treatment.
1. A process for producing a fiber, comprising:
melt-extruding polyhydroxyalkanoic acid to form a melt-extruded fiber;
rapidly quenching the melt-extruded fiber to the glass transition temperature of polyhydroxyalkanoic acid +15° C. or less, and solidifying the fiber to form an amorphous fiber;
forming a crystalline fiber by leaving the amorphous fiber to stand at the glass transition temperature +15° C. or less for 24 to 72 hours;
drawing the crystalline fiber; and
further subjecting the crystalline fiber to stretch heat treatment.
2. The process for producing a fiber according to claim 1 , wherein the polyhydroxyalkanoic acid is a poly (3-hydroxybutyric acid) homopolymer or a poly (3-hydroxybutyric acid) copolymer.
3. A fiber of polyhydroxyalkanoic acid, which is produced by the process for producing a fiber according to claim 1 .