Frequency comb cavity enhanced spectroscopy
View Patent ↗Cavity enhanced spectroscopy efficiently couples a broadband optical frequency comb to a high finesse optical cavity inside which a sample test gas is placed. The output of the optical cavity is a multiplicity of channels of data resulting from the differential absorption of light at various of the comb frequencies. The device can operate in a ringdown mode or a non-ringdown enhanced absorption spectroscopy mode. Careful measurement and control of cavity dispersion and comb spacing are part of the coupling process. Several dispersive detection methods adapted to detecting the multiplicity of channels are provided.
1. A method of performing cavity enhanced spectroscopy on a test sample on many channels of data at once comprising the steps of:
(a) providing a high finesse, low-dispersion optical cavity within which the test sample is located;
(b) coupling a broadband optical frequency comb to the high finesse optical cavity;
(c) measuring cavity transmission of the high finesse optical cavity at a multiplicity of frequencies;
(d) determining absorption at the multiplicity of frequencies from the measured cavity transmission at the multiplicity of frequencies.
2. The method of claim 1 , further comprising the step of determining the composition of the test sample based upon the absorption at the multiplicity of frequencies.
3. The method of claim 1 wherein the coupling step includes the following steps:
(b1) measuring the wavelength dependent frequency spacing of cavity modes due to dispersion; and
(b2) making adjustments based on the wavelength dependent frequency spacing of cavity modes in order to match comb frequencies to cavity modes.
4. The method of claim 3 wherein step b1 includes the steps of detuning the frequency comb from the cavity modes, varying the repetition rate, and monitoring the spectrum of light transmitted from the cavity.
5. The method of claim 3 wherein the step of making adjustments includes the steps of varying the repetition rate and offset of the comb.
6. The method of claim 3 wherein the step of making adjustments includes the steps of adjusting the cavity length and varying at least one of either the sample composition or the sample pressure.
7. The method of claim 3 wherein the step of making adjustments includes the step of maintaining a match between the comb frequencies and the cavity modes using an electronic servo.
8. The method of claim 1 wherein the step of measuring cavity Transmission includes the steps of:
(c1) spatially separating wavelengths in the transmission; and
(c2) detecting the intensity at the wavelengths in parallel with a photodiode array and generating voltages based upon the detected intensities.
9. The method of claim 8 , wherein the method is performed in a ringdown mode such that the optical frequency comb is interrupted periodically and the cavity transmission is allowed to ring down, and wherein step c2 further includes the steps of comparing the generated voltages over time to a series of descending voltage thresholds, wherein the voltage thresholds are exponentially spaced in order to reduce computations needed to determine decay rate at the wavelengths.
10. The method of claim 1 wherein the step of measuring cavity transmission includes the steps of:
(c1) sweeping the comb frequencies over a preselected period of time such that a selected group of comb frequencies at a time couple to the cavity; and
(c2) measuring the intensity of each transmitted group of comb frequencies in turn.
11. The method of claim 10 wherein the selected group of comb frequencies comprises between 1 and 10,000 comb frequencies.
12. Apparatus for performing enhanced spectroscopy on a test sample on many channels of data at once comprising:
means for providing a broadband optical frequency comb;
a high finesse, low-dispersion optical cavity within which the test sample is stored;
means for coupling the optical frequency comb to the cavity, and
means for measuring cavity transmission at a multiplicity of frequencies.
13. The apparatus of claim 12 , further comprising a processor for determining absorption within the cavity at the multiplicity of frequencies from the measured cavity transmission and for determining the composition of the test sample based upon the determined absorption.
14. The apparatus of claim 12 wherein the means for coupling comprises:
means for measuring the wavelength dependent frequency spacing of cavity modes due to dispersion; and
means for making adjustments based on the wavelength dependent frequency spacing of cavity modes in order to match comb frequencies to cavity modes.
15. The apparatus of claim 14 wherein the means for measuring comprises means for detuning the frequency comb from the cavity modes, means for varying the repetition rate, and means for monitoring the spectrum of light transmitted from the cavity.
16. The apparatus of claim 14 wherein the means for making adjustments varies the repetition rate and offset of the comb.
17. The apparatus of claim 14 wherein the means for making adjustments adjusts the cavity length and varies at least one of either the sample composition or the sample pressure.
18. The apparatus of claim 14 wherein the means for making adjustments includes an electronic servo for maintaining the match between comb frequencies and cavity modes.
19. The apparatus of claim 12 wherein the means for measuring cavity transmission comprises:
an element for spatially separating wavelengths in the transmission; and
a photodiode array configured to detect the intensities of separated wavelengths and generate voltages based upon the detected intensities.
20. The apparatus of claim 19 configured to operate in ringdown mode and further comprising:
means for interrupting the optical frequency comb periodically; and
means for comparing the generated voltages over time to a series of descending voltage thresholds, wherein the voltage thresholds are exponentially spaced in order to reduce computations needed to determine decay rate at the wavelengths.
21. The apparatus of claim 12 wherein the means for measuring cavity transmission comprises:
means for sweeping the comb frequencies over a preselected period of time such that a selected group of comb frequencies at a time couples to the cavity; and
means for measuring the intensity of each transmitted selected group of comb frequencies in turn.
22. The apparatus of claim 21 wherein the selected group of comb frequencies comprises between 1 and 10,000 comb frequencies.
23. The apparatus of claim 12 wherein the means for measuring cavity transmission includes an optical detector.
24. The apparatus of claim 12 wherein the means for providing a broadband optical frequency comb is a mode locked laser.