Method for Controlling Fluidity of Phosphor, Phosphor and Phosphor Paste
Disclosed herein is a method for controlling the fluidity of a phosphor, a phosphor and a phosphor paste, the method comprising the steps of: treating the surface of a phosphor with a silane compound comprising a double bond; and polymerizing the monomer on the surface of the phosphor to form a polymer membrane thereon. The phosphor having the polymer membrane formed thereon exhibits significantly stabilized fluidity within a polymer encapsulant.
1 . A method for controlling fluidity of a phosphor, comprising the steps of:
treating a surface of a phosphor with a silane compound that comprises a double bond to form a surface-treated phosphor; and
mixing the surface-treated phosphor, a monomer and a polymerization initiator and initiating polymerization of the monomer on the surface of the phosphor to form a polymer film on the surface of the phosphor.
2 . The method according to claim 1 , wherein the silane compound comprises an alkoxy group and an alkenyl group.
3 . The method according to claim 2 , wherein the alkenlyl group comprises an allyl group or a vinyl group.
4 . The method according to claim 2 , wherein the silane compound has a structure represented by the following Formula 1:
wherein R 1 is C 1-6 alkoxy; R 2 , R 3 and R 4 are independently hydrogen, C 1-20 linear, branched or circular alkyl, C 1-6 alkoxy, C 2-20 alkenyl, at least one of R 2 , R 3 and R 4 being C 2-20 alkenyl.
5 . The method according to claim 4 , wherein the silane compound is selected from the group consisting of allyltrimethoxysilane, diallyldimethoxysilane, allyltrietoxysilane, allyltripropoxysilane, allyltripthoxysilane, allyltripentyloxysilane, allyltrihexyloxysilane, allylmethoxysilane, vinyltrimethoxysilane, 1-butenyltrimethoxysilane, styryltrimethoxysilane, and a combination comprising at least one of the foregoing silane compounds.
6 . The method according to claim 1 , wherein the monomer is one or more selected from the group consisting of styrene, propylene, vinylchloride, isobutylene, acrylonitrile, methylmetacrylate, 2-vinylpyrridine, isoprene, and a combination comprising at least one of the foregoing monomers.
7 . The method according to claim 1 , wherein the phosphor is an inorganic phosphor or an organic phosphor.
8 . The method according to claim 7 , wherein the inorganic phosphor is one or more selected from the group consisting of Y 3 Al 5 O 12 :Ce, (Y,Gd)BO 3 :Eu, Y(V,P)O 4 :Eu, (Y,Gd)O 3 :Eu, La 2 O 2 S:Eu 3+ , BaMgAl 10 O 17 :Eu,Mn, Zn 2 SiO 4 :Mn, (Zn,A) 2 SiO 4 :Mn, where A is an alkaline earth metal, MgAl x O y :Mn, where x is an integer in the range of 1 to 10 and y is an integer in the range of 1 to 30, LaMgAl x O y :Tb, where x is an integer in the range of 1 to 14 and y is an integer in the range of 8 to 47, ReBO 3 :Tb where Re is one or more rare-earth element selected from the group consisting of Sc, Y, La, Ce, and Gd, (Y,Gd)BO 3 :Tb, Sr(PO 4 ) 3 Cl:Eu 2+ , ZnS:Ag, Cl, CaMgSi 2 O 6 :Eu, CaWO 4 :Pb, and Y 2 SiO 5 :Eu.
9 . The method according to claim 1 , wherein the step of treating the surface of the phosphor is conducted by dispersing the phosphor in a solvent, adding the saline compound thereto, filtering the mixture, and washing and drying a filtrate.
10 . The method according to claim 1 , wherein the initiator is one or more selected from the group consisting of potassium persulfate, hydrogen peroxide, cumyl hydroperoxide, di-tertiary butyl peroxide, dilaurylperoxide, acetylperoxide, benzoylperoxide, and a combination comprising at least one of the foregoing initiators.
11 . The method according to claim 1 , wherein the step of forming the polymer membrane is conducted by mixing the surface-treated phosphor with the monomer and performing emulsion polymerization or suspension polymerization of the mixture.
12 . A phosphor showing improved fluidity prepared by the method according to claim 1 .
13 . The phosphor according to claim 12 , wherein the phosphor exhibits a reduced settling speed within a polymer encapsulant, when compared with a phosphor that is not coated with a polymeric coating.
14 . The phosphor according to claim 12 , wherein the phosphor inhibits the occurrence of microturbulence within the polymer encapsulant by its hydrophobic surface, when compared with a phosphor that is not coated with a polymeric coating.
15 . The phosphor according to claim 12 , wherein the phosphor has reduced density, when compared with a phosphor that is not coated with a polymeric coating.
16 . A phosphor paste comprising the phosphor according to claim 12 and a polymer encapsulant.
17 . The phosphor paste according to claim 16 , wherein the polymer encapsulant is selected from the group consisting of acryl, epoxy, polyimide, silicone, silicone-epoxy hybrid resin, poly dimethyl siloxane resin, phenol resin, polyurethan resin, amino resin, polyester resin, and a combination comprising at least one of the foregoing polymer encapsulants.
18 . A light emitting diode prepared by using the phosphor paste according to claim 16 .